Skip to main content
Erschienen in: Journal of Materials Science 5/2020

01.10.2019 | Chemical routes to materials

Highly efficient MnO2/reduced graphene oxide hydrogel motors for organic pollutants removal

verfasst von: Laibo Song, Chaoqing Li, Wei Chen, Bo Liu, Yuandi Zhao

Erschienen in: Journal of Materials Science | Ausgabe 5/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Self-propelled milli/micro/nanomotors have shown promising potential for achieving various on-demand tasks of biomedical and environmental applications. In order to increase motor propellant and/or cargo-loading capability, it is critical to design and fabricate novel multifunctional materials. Here, high surface area reduced graphene oxide hydrogel (rGH)-based motor incorporated with richly porous manganese oxide (MnO2) as nanocatalysts was developed for efficient organic dyes removal through the adsorption–oxidation–desorption mechanism enhanced with bubble-propelling-induced mixing which led to a more than 90% removal of organic dyes in just 30 min, without the need for external stirring. After each usage, the MnO2/rGH motor can be easily manipulated and separated, as well as lowering the risk of graphene nanosheets release to the environment. Due to its fabrication simplicity and flexibility, high efficiency and reusability, this rGH-based motor can be further customized with more functions for practical environmental applications.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat Safdar M, Khan SU, Janis J (2018) Progress toward catalytic micro- and nanomotors for biomedical and environmental applications. Adv Mater 30:1703660 Safdar M, Khan SU, Janis J (2018) Progress toward catalytic micro- and nanomotors for biomedical and environmental applications. Adv Mater 30:1703660
2.
Zurück zum Zitat Karshalev E, Esteban-Fernandez de Avila B, Wang J (2018) Micromotors for “chemistry-on-the-fly”. J Am Chem Soc 140(11):3810–3820 Karshalev E, Esteban-Fernandez de Avila B, Wang J (2018) Micromotors for “chemistry-on-the-fly”. J Am Chem Soc 140(11):3810–3820
3.
Zurück zum Zitat Parmar J, Vilela D, Villa K, Wang J, Sanchez S (2018) Micro- and nanomotors as active environmental microcleaners and sensors. J Am Chem Soc 140:9317–9331 Parmar J, Vilela D, Villa K, Wang J, Sanchez S (2018) Micro- and nanomotors as active environmental microcleaners and sensors. J Am Chem Soc 140:9317–9331
4.
Zurück zum Zitat Villa K, Parmar J, Vilela D, Sanchez S (2018) Metal-oxide-based microjets for the simultaneous removal of organic pollutants and heavy metals. ACS Appl Mater Interfaces 10:20478–20486 Villa K, Parmar J, Vilela D, Sanchez S (2018) Metal-oxide-based microjets for the simultaneous removal of organic pollutants and heavy metals. ACS Appl Mater Interfaces 10:20478–20486
5.
Zurück zum Zitat Magdanz V, Guix M, Hebenstreit F, Schmidt OG (2016) Dynamic polymeric microtubes for the remote-controlled capture, guidance, and release of sperm cells. Adv Mater 28:4084–4089 Magdanz V, Guix M, Hebenstreit F, Schmidt OG (2016) Dynamic polymeric microtubes for the remote-controlled capture, guidance, and release of sperm cells. Adv Mater 28:4084–4089
6.
Zurück zum Zitat Mou FZ, Chen CR, Zhong Q, Yin YX, Ma HR, Guan JG (2014) Autonomous motion and temperature-controlled drug delivery of Mg/Pt-poly(N-isopropylacrylamide) Janus micromotors driven by simulated body fluid and blood plasma. ACS Appl Mater Interfaces 6:9897–9903 Mou FZ, Chen CR, Zhong Q, Yin YX, Ma HR, Guan JG (2014) Autonomous motion and temperature-controlled drug delivery of Mg/Pt-poly(N-isopropylacrylamide) Janus micromotors driven by simulated body fluid and blood plasma. ACS Appl Mater Interfaces 6:9897–9903
7.
Zurück zum Zitat Singh VV, Kaufmann K, de Ávila BEF, Karshalev E, Wang J (2016) Molybdenum disulfide-based tubular microengines: toward biomedical applications. Adv Funct Mater 26:6270–6278 Singh VV, Kaufmann K, de Ávila BEF, Karshalev E, Wang J (2016) Molybdenum disulfide-based tubular microengines: toward biomedical applications. Adv Funct Mater 26:6270–6278
8.
Zurück zum Zitat Xuan MJ, Wu ZG, Shao JX, Dai LR, Si TY, He Q (2016) Near infrared light-powered Janus mesoporous silica nanoparticle motors. J Am Chem Soc 138:6492–6497 Xuan MJ, Wu ZG, Shao JX, Dai LR, Si TY, He Q (2016) Near infrared light-powered Janus mesoporous silica nanoparticle motors. J Am Chem Soc 138:6492–6497
9.
Zurück zum Zitat Wang H, Gu XY, Wang CY (2016) Self-propelling hydrogel/emulsion-hydrogel soft motors for water purification. ACS Appl Mater Interfaces 8:9413–9422 Wang H, Gu XY, Wang CY (2016) Self-propelling hydrogel/emulsion-hydrogel soft motors for water purification. ACS Appl Mater Interfaces 8:9413–9422
10.
Zurück zum Zitat Hermanova S, Pumera M (2018) Polymer platforms for micro- and nanomotor fabrication. Nanoscale 10:7332–7342 Hermanova S, Pumera M (2018) Polymer platforms for micro- and nanomotor fabrication. Nanoscale 10:7332–7342
11.
Zurück zum Zitat Jurado-Sanchez B, Sattayasamitsathit S, Gao W, Santos L, Fedorak Y, Singh VV, Orozco J, Galarnyk M, Wang J (2015) Self-propelled activated carbon Janus micromotors for efficient water purification. Small 11:499–506 Jurado-Sanchez B, Sattayasamitsathit S, Gao W, Santos L, Fedorak Y, Singh VV, Orozco J, Galarnyk M, Wang J (2015) Self-propelled activated carbon Janus micromotors for efficient water purification. Small 11:499–506
12.
Zurück zum Zitat Huang Y, Liang JJ, Chen YS (2012) An overview of the applications of graphene-based materials in supercapacitors. Small 8:1805–1834 Huang Y, Liang JJ, Chen YS (2012) An overview of the applications of graphene-based materials in supercapacitors. Small 8:1805–1834
13.
Zurück zum Zitat Justino CIL, Gomes AR, Freitas AC, Duarte AC, Rocha-Santos TAP (2017) Graphene based sensors and biosensors. TrAC Trends in Anal Chem 91:53–66 Justino CIL, Gomes AR, Freitas AC, Duarte AC, Rocha-Santos TAP (2017) Graphene based sensors and biosensors. TrAC Trends in Anal Chem 91:53–66
14.
Zurück zum Zitat Cong HP, Chen JF, Yu SH (2014) Graphene-based macroscopic assemblies and architectures: an emerging material system. Chem Soc Rev 43:7295–7325 Cong HP, Chen JF, Yu SH (2014) Graphene-based macroscopic assemblies and architectures: an emerging material system. Chem Soc Rev 43:7295–7325
15.
Zurück zum Zitat Ma X, Katuri J, Zeng YF, Zhao YL, Sanchez S (2015) Surface conductive graphene-wrapped micromotors exhibiting enhanced motion. Small 11:5023–5027 Ma X, Katuri J, Zeng YF, Zhao YL, Sanchez S (2015) Surface conductive graphene-wrapped micromotors exhibiting enhanced motion. Small 11:5023–5027
16.
Zurück zum Zitat Vilela D, Parmar J, Zeng YF, Zhao YL, Sanchez S (2016) Graphene-based microbots for toxic heavy metal removal and recovery from water. Nano Lett 16:2860–2866 Vilela D, Parmar J, Zeng YF, Zhao YL, Sanchez S (2016) Graphene-based microbots for toxic heavy metal removal and recovery from water. Nano Lett 16:2860–2866
17.
Zurück zum Zitat Chen ZP, Ren WC, Gao LB, Liu BL, Pei SF, Cheng HM (2011) Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nat Mater 10:424–428 Chen ZP, Ren WC, Gao LB, Liu BL, Pei SF, Cheng HM (2011) Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nat Mater 10:424–428
18.
Zurück zum Zitat Wang H, Yuan XZ, Zeng GM, Wu Y, Liu Y, Jiang Q, Gu SS (2015) Three dimensional graphene based materials: synthesis and applications from energy storage and conversion to electrochemical sensor and environmental remediation. Adv Colloid Interface Sci 221:41–59 Wang H, Yuan XZ, Zeng GM, Wu Y, Liu Y, Jiang Q, Gu SS (2015) Three dimensional graphene based materials: synthesis and applications from energy storage and conversion to electrochemical sensor and environmental remediation. Adv Colloid Interface Sci 221:41–59
19.
Zurück zum Zitat He K, Chen GQ, Zeng GM, Chen AW, Huang ZZ, Shi JB, Huang TT, Peng M, Hu L (2018) Three-dimensional graphene supported catalysts for organic dyes degradation. App Catal B: Environ 228:19–28 He K, Chen GQ, Zeng GM, Chen AW, Huang ZZ, Shi JB, Huang TT, Peng M, Hu L (2018) Three-dimensional graphene supported catalysts for organic dyes degradation. App Catal B: Environ 228:19–28
20.
Zurück zum Zitat Wang ZJ, Gao H, Zhang Q, Liu YQ, Chen J, Guo ZQ (2018) Recent advances in 3D graphene architectures and their composites for energy storage applications. Small 15:1803858 Wang ZJ, Gao H, Zhang Q, Liu YQ, Chen J, Guo ZQ (2018) Recent advances in 3D graphene architectures and their composites for energy storage applications. Small 15:1803858
21.
Zurück zum Zitat Safdar M, Minh TD, Kinnunen N, Janis J (2016) Manganese oxide based catalytic micromotors: effect of polymorphism on motion. ACS Appl Mater Interfaces 8:32624–32629 Safdar M, Minh TD, Kinnunen N, Janis J (2016) Manganese oxide based catalytic micromotors: effect of polymorphism on motion. ACS Appl Mater Interfaces 8:32624–32629
22.
Zurück zum Zitat Wang NN, Zheng T, Zhang GS, Wang P (2016) A review on Fenton-like processes for organic wastewater treatment. J Environ Chem Eng 4:762–787 Wang NN, Zheng T, Zhang GS, Wang P (2016) A review on Fenton-like processes for organic wastewater treatment. J Environ Chem Eng 4:762–787
23.
Zurück zum Zitat Liu WJ, Ge HB, Gu ZW, Lu XL, Li JX, Wang J (2018) Electrochemical deposition tailors the catalytic performance of MnO2-based micromotors. Small 14:1802771 Liu WJ, Ge HB, Gu ZW, Lu XL, Li JX, Wang J (2018) Electrochemical deposition tailors the catalytic performance of MnO2-based micromotors. Small 14:1802771
24.
Zurück zum Zitat Wani OM, Safdar M, Kinnunen N, Janis J (2016) Dual effect of manganese oxide micromotors: catalytic degradation and adsorptive bubble separation of organic pollutants. Chem Eng J 22:1244–1247 Wani OM, Safdar M, Kinnunen N, Janis J (2016) Dual effect of manganese oxide micromotors: catalytic degradation and adsorptive bubble separation of organic pollutants. Chem Eng J 22:1244–1247
25.
Zurück zum Zitat Espinosa JC, Navalón S, Álvaro M, García H (2016) Reduced graphene oxide as a metal-free catalyst for the light-assisted Fenton-like reaction. Chemcatchem 8:2642–2648 Espinosa JC, Navalón S, Álvaro M, García H (2016) Reduced graphene oxide as a metal-free catalyst for the light-assisted Fenton-like reaction. Chemcatchem 8:2642–2648
26.
Zurück zum Zitat Chen MX, Zhang CC, Li XH, Zhang L, Ma YL, Zhang L, Xu XY, Xia FL, Wang W, Gao JQ (2013) A one-step method for reduction and self-assembling of graphene oxide into reduced graphene oxide aerogels. J Mater Chem A 1:2869–2877 Chen MX, Zhang CC, Li XH, Zhang L, Ma YL, Zhang L, Xu XY, Xia FL, Wang W, Gao JQ (2013) A one-step method for reduction and self-assembling of graphene oxide into reduced graphene oxide aerogels. J Mater Chem A 1:2869–2877
27.
Zurück zum Zitat Meng XY, Lu L, Sun CW (2018) Green synthesis of three-dimensional MnO2/graphene hydrogel composites as a high-performance electrode material for supercapacitors. ACS Appl Mater Interfaces 10:16474–16481 Meng XY, Lu L, Sun CW (2018) Green synthesis of three-dimensional MnO2/graphene hydrogel composites as a high-performance electrode material for supercapacitors. ACS Appl Mater Interfaces 10:16474–16481
28.
Zurück zum Zitat Fan ZJ, Yan J, Wei T, Zhi LJ, Ning GQ, Li TY, Wei F (2011) Asymmetric supercapacitors based on graphene/MnO2 and activated carbon nanofiber electrodes with high power and energy density. Adv Funct Mater 21:2366–2375 Fan ZJ, Yan J, Wei T, Zhi LJ, Ning GQ, Li TY, Wei F (2011) Asymmetric supercapacitors based on graphene/MnO2 and activated carbon nanofiber electrodes with high power and energy density. Adv Funct Mater 21:2366–2375
29.
Zurück zum Zitat Bai S, Shen XQ, Zhong X, Liu Y, Zhu GX, Xu X, Chen KM (2012) One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal. Carbon 50:2337–2346 Bai S, Shen XQ, Zhong X, Liu Y, Zhu GX, Xu X, Chen KM (2012) One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal. Carbon 50:2337–2346
30.
Zurück zum Zitat Chen W, Yan L (2011) In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures. Nanoscale 3:3132–3137 Chen W, Yan L (2011) In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures. Nanoscale 3:3132–3137
31.
Zurück zum Zitat Liu JT, Ge X, Ye X, Wang GZ, Zhang HM, Zhou HJ, Zhang YX, Zhao HJ (2016) 3D graphene/δ-MnO2 aerogels for highly efficient and reversible removal of heavy metal ions. J Mater Chem A 4:1970–1979 Liu JT, Ge X, Ye X, Wang GZ, Zhang HM, Zhou HJ, Zhang YX, Zhao HJ (2016) 3D graphene/δ-MnO2 aerogels for highly efficient and reversible removal of heavy metal ions. J Mater Chem A 4:1970–1979
32.
Zurück zum Zitat Maliyekkal SM, Sreeprasad TS, Krishnan D, Kouser S, Mishra AK, Waghmare UV, Pradeep T (2013) Graphene: a reusable substrate for unprecedented adsorption of pesticides. Small 9:273–283 Maliyekkal SM, Sreeprasad TS, Krishnan D, Kouser S, Mishra AK, Waghmare UV, Pradeep T (2013) Graphene: a reusable substrate for unprecedented adsorption of pesticides. Small 9:273–283
33.
Zurück zum Zitat Song Z, Ma YL, Li CE (2019) The residual tetracycline in pharmaceutical wastewater was effectively removed by using MnO2/graphene nanocomposite. Sci Total Environ 651:580–590 Song Z, Ma YL, Li CE (2019) The residual tetracycline in pharmaceutical wastewater was effectively removed by using MnO2/graphene nanocomposite. Sci Total Environ 651:580–590
34.
Zurück zum Zitat Zhang L, Li TH, Ji XG, Zhang ZY, Yang WB, Gao JJ, Li H, Xiong CY, Dang AL (2017) Freestanding three-dimensional reduced graphene oxide/MnO2 on porous carbon/nickel foam as a designed hierarchical multihole supercapacitor electrode. Electrochim Acta 252:306–314 Zhang L, Li TH, Ji XG, Zhang ZY, Yang WB, Gao JJ, Li H, Xiong CY, Dang AL (2017) Freestanding three-dimensional reduced graphene oxide/MnO2 on porous carbon/nickel foam as a designed hierarchical multihole supercapacitor electrode. Electrochim Acta 252:306–314
35.
Zurück zum Zitat Fasolino A, Los JH, Katsnelson MI (2007) Intrinsic ripples in graphene. Nat Mater 6:858–861 Fasolino A, Los JH, Katsnelson MI (2007) Intrinsic ripples in graphene. Nat Mater 6:858–861
36.
Zurück zum Zitat Jang WS, Kim HJ, Gao C, Lee D, Hammer DA (2018) Enzymatically powered surface-associated self-motile protocells. Small 14:1801715 Jang WS, Kim HJ, Gao C, Lee D, Hammer DA (2018) Enzymatically powered surface-associated self-motile protocells. Small 14:1801715
37.
Zurück zum Zitat Ma X, Jannasch A, Albrecht UR, Hahn K, Miguel-Lopez A, Schaffer E, Sanchez S (2015) Enzyme-powered hollow mesoporous Janus nanomotors. Nano Lett 15:7043–7050 Ma X, Jannasch A, Albrecht UR, Hahn K, Miguel-Lopez A, Schaffer E, Sanchez S (2015) Enzyme-powered hollow mesoporous Janus nanomotors. Nano Lett 15:7043–7050
38.
Zurück zum Zitat Hortelão AC, Patiño T, Perez-Jiménez A, Blanco À, Sánchez S (2018) Enzyme-powered nanobots enhance anticancer drug delivery. Adv Funct Mater 28:1705086 Hortelão AC, Patiño T, Perez-Jiménez A, Blanco À, Sánchez S (2018) Enzyme-powered nanobots enhance anticancer drug delivery. Adv Funct Mater 28:1705086
39.
Zurück zum Zitat Liang CY, Zhan C, Zeng FY, Xu DD, Wang Y, Zhao WW, Zhang JH, Guo JH, Feng HH, Ma X (2018) Bilayer tubular micromotors for simultaneous environmental monitoring and remediation. ACS Appl Mater Interfaces 10:35099–35107 Liang CY, Zhan C, Zeng FY, Xu DD, Wang Y, Zhao WW, Zhang JH, Guo JH, Feng HH, Ma X (2018) Bilayer tubular micromotors for simultaneous environmental monitoring and remediation. ACS Appl Mater Interfaces 10:35099–35107
40.
Zurück zum Zitat Wang H, Moo JG, Pumera M (2016) From nanomotors to micromotors: the influence of the size of an autonomous bubble-propelled device upon its motion. ACS Nano 10:5041–5050 Wang H, Moo JG, Pumera M (2016) From nanomotors to micromotors: the influence of the size of an autonomous bubble-propelled device upon its motion. ACS Nano 10:5041–5050
41.
Zurück zum Zitat Ma X, Hortelao AC, Miguel-Lopez A, Sanchez S (2016) Bubble-free propulsion of ultrasmall tubular nanojets powered by biocatalytic reactions. J Am Chem Soc 138:13782–13785 Ma X, Hortelao AC, Miguel-Lopez A, Sanchez S (2016) Bubble-free propulsion of ultrasmall tubular nanojets powered by biocatalytic reactions. J Am Chem Soc 138:13782–13785
42.
Zurück zum Zitat Paxton WF, Sen A, Mallouk TE (2005) Motility of catalytic nanoparticles through self-generated forces. Chem Eng J 11:6462–6470 Paxton WF, Sen A, Mallouk TE (2005) Motility of catalytic nanoparticles through self-generated forces. Chem Eng J 11:6462–6470
43.
Zurück zum Zitat Li JX, Huang GS, Ye MM, Li ML, Liu R, Mei YF (2011) Dynamics of catalytic tubular microjet engines: dependence on geometry and chemical environment. Nanoscale 3:5083–5089 Li JX, Huang GS, Ye MM, Li ML, Liu R, Mei YF (2011) Dynamics of catalytic tubular microjet engines: dependence on geometry and chemical environment. Nanoscale 3:5083–5089
44.
Zurück zum Zitat Fang Q, Chen B (2014) Self-assembly of graphene oxide aerogels by layered double hydroxides cross-linking and their application in water purification. J Mater Chem A 2:8941–8951 Fang Q, Chen B (2014) Self-assembly of graphene oxide aerogels by layered double hydroxides cross-linking and their application in water purification. J Mater Chem A 2:8941–8951
45.
Zurück zum Zitat Chen RX, Yu JG, Xiao W (2013) Hierarchically porous MnO2 microspheres with enhanced adsorption performance. J Mater Chem A 1:11682–11690 Chen RX, Yu JG, Xiao W (2013) Hierarchically porous MnO2 microspheres with enhanced adsorption performance. J Mater Chem A 1:11682–11690
46.
Zurück zum Zitat Zhang LL, Nie YL, Hu C, Hu XX (2011) Decolorization of methylene blue in layered manganese oxide suspension with H2O2. J Hazard Mater 190:780–785 Zhang LL, Nie YL, Hu C, Hu XX (2011) Decolorization of methylene blue in layered manganese oxide suspension with H2O2. J Hazard Mater 190:780–785
47.
Zurück zum Zitat Hao Z, Lv XJ, Li YM, Wang Y, Li JH (2010) P25-graphene composite as a high performance photocatalyst. ACS Nano 4:380–386 Hao Z, Lv XJ, Li YM, Wang Y, Li JH (2010) P25-graphene composite as a high performance photocatalyst. ACS Nano 4:380–386
48.
Zurück zum Zitat Zou RJ, Zhang ZY, Yu L, Tian QW, Chen ZG, Hu JQ (2011) A general approach for the growth of metal oxide nanorod arrays on graphene sheets and their applications. Chem Eng J 17:13912–13917 Zou RJ, Zhang ZY, Yu L, Tian QW, Chen ZG, Hu JQ (2011) A general approach for the growth of metal oxide nanorod arrays on graphene sheets and their applications. Chem Eng J 17:13912–13917
Metadaten
Titel
Highly efficient MnO2/reduced graphene oxide hydrogel motors for organic pollutants removal
verfasst von
Laibo Song
Chaoqing Li
Wei Chen
Bo Liu
Yuandi Zhao
Publikationsdatum
01.10.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 5/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04076-5

Weitere Artikel der Ausgabe 5/2020

Journal of Materials Science 5/2020 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.