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Journal of Materials Science
Erschienen in: Journal of Materials Science 2/2020

01.10.2019 | Ceramics

Microscopic mapping of dopant content and its link to the structural and thermal stability of yttria-stabilized zirconia polycrystals

verfasst von: Wenliang Zhu, Shizuka Nakashima, Elia Marin, Hui Gu, Giuseppe Pezzotti

Erschienen in: Journal of Materials Science | Ausgabe 2/2020

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Abstract

The effect of yttria content on structural and thermal stability of zirconia in yttria-stabilized zirconia (YSZ) polycrystalline ceramics was systematically investigated by Raman spectroscopy and X-ray photoelectron spectroscopy. Taking advantage of an experimentally retrieved linear dependence of Raman bandwidth on yttria content, Raman imaging was applied as an effective tool in examining the local yttrium distribution in YSZ ceramics and its relationship with environmentally driven polymorphic transformation. A significant variation of monoclinic fraction with yttria content and temperature was found and interpreted according to a newly proposed model, which takes into account the change in lattice hydroxyl and oxygen vacancies and the possible formation of stable defect complexes.
Vorheriger Artikel Pore structure, porosity and compressive strength of highly porous reaction-bonded silicon nitride ceramics with various grain morphologies
Nächster Artikel Fast growth of nanodiamond in a microwave oven under atmospheric conditions

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Metadaten
Titel
Microscopic mapping of dopant content and its link to the structural and thermal stability of yttria-stabilized zirconia polycrystals
verfasst von
Wenliang Zhu
Shizuka Nakashima
Elia Marin
Hui Gu
Giuseppe Pezzotti
Publikationsdatum
01.10.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 2/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04080-9

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