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02.02.2021 | Energy materials

Novel nanoscale Yb-MOF used as highly efficient electrode for simultaneous detection of heavy metal ions

verfasst von: Manh B. Nguyen, Dau Thi Ngoc Nga, Vu Thi Thu, Benoît Piro, Thuan Nguyen Pham Truong, Pham Thi Hai Yen, Giang H. Le, Le Quoc Hung, Tuan A. Vu, Vu Thi Thu Ha

Erschienen in: Journal of Materials Science | Ausgabe 13/2021

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Abstract

It is essential to develop new nanomaterials able to improve sensing performance of electrochemical sensors for determination of heavy metal pollutants. In this work, a novel nanoscale metal–organic-framework material (Yb-MOF) with Ytterbium (Yb) rare-earth metal core and benzenetricarboxylic (BTC) ligands was prepared in aqueous conditions using hydrothermal approach. The results have revealed highly porous structure of the as-synthesized material with specific active area up to 1166 m² g⁻¹. A sensing platform was then constructed by drop-casting Yb-MOF onto glassy carbon electrode for detection of two most commonly found heavy metal ion pollutants (Cd²⁺ and Pb²⁺) in water sources. The nanoporous structure of Yb-MOF is very profitable to the selective preconcentration of targeted metal ions. The detection limits were estimated to be 3.0 ppb, 1.6 ppb for Cd²⁺ and Pb²⁺ species, respectively. This work provides a new electrochemical sensing platform for fast and sensitive in-situ detection of water contaminants.

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Vorheriger Artikel Superior electrochemical characteristics of A2B7-type hydrogen storage alloy at ultralow temperature with the addition of alane

Nächster Artikel Ionic liquid-induced graphitization of biochar: N/P dual-doped carbon nanosheets for high-performance lithium/sodium storage

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Riman D, Jirovsky D, Hrbac J, Prodromidis M (2014) Green and facile electrode modification by spark discharge: bismuth oxide-screen printed electrodes for the screening of ultra-trace Cd(II) and Pb(II). Electrochem Commun 50:20–23CrossRef

Giao NQ, Dang VH, Yen PTH, Phong PH, Ha VTT, Duy PK, Chung H (2019) Au nanodendrite incorporated graphite pencil lead as a sensitive and simple electrochemical sensor for simultaneous detection of Pb(II), Cu(II) and Hg(II). J Appl Electrochem 49(8):839–846CrossRef

Lee S, Bong S, Ha J, Kwak M, Park S-K, Piao Y (2015) Electrochemical deposition of bismuth on activated graphene-nafion composite for anodic stripping voltammetric determination of trace heavy metals. Sens Actuat B 215:62–69CrossRef

Zhao G, Liu G (2019) Synthesis of a three-dimensional (BiO)₂CO₃@single-walled carbon nanotube nanocomposite and its application for ultrasensitive detection of trace Pb(II) and Cd(II) by incorporating Nafion. Sens Actuat B 288:71–79CrossRef

Yu L, Zhang Q, Yang B, Xu Q, Xu Q, Hu X (2018) Electrochemical sensor construction based on Nafion/calcium lignosulphonate functionalized porous graphene nanocomposite and its application for simultaneous detection of trace Pb2+ and Cd2+. Sens Actuat B 259:540–551CrossRef

Wang Y, Wu Y, Xie J, Hu X (2013) Metal–organic framework modified carbon paste electrode for lead sensor. Sens Actuat B 177:1161–1166CrossRef

Guo H, Zheng Z, Zhang Y, Lin H, Xu Q (2017) Highly selective detection of Pb2+ by a nanoscale Ni-based metal–organic framework fabricated through one-pot hydrothermal reaction. Sens Actuat B 248:430–436CrossRef

Li Y, Xia T, Zhang J, Cui Y, Li B, Yang Y, Qian G (2019) A manganese-based metal-organic framework electrochemical sensor for highly sensitive cadmium ions detection. J Solid State Chem 275:38–42CrossRef

Sanati S, Abazari R, Morsali A, Kirillov AM, Junk PC, Wang J (2019) An asymmetric supercapacitor based in a non-calcined 3D pillared cobalt (II) metal-organic framework with long cylic stability. Inorg Chem 58:16100–16111CrossRef

10.

Sanati S, Abazari R, Morsali A (2020) Enhanced electrochemical oxygen and hydrogen evolution using an NU-1000@NiMn-LDHS composite electrode in alkaline electrolyte. Chem Commun 56:6652–6655CrossRef

11.

Abazari R, Morsali A, Dubai DP (2020) An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni-Ti LDH: mechanistic insight and toxicity assessment. Inorg Chem Front 7:2287–2304CrossRef

12.

Roushani M, Valipour A, Saedi Z (2016) Electroanalytical sensing of Cd2+ based on metal–organic framework modified carbon paste electrode. Sens Actuat B 233:419–425CrossRef

13.

Wang Y, Wang L, Huang W, Zhang T, Hu X, Perman JA, Ma S (2017) A metal–organic framework and conducting polymer based electrochemical sensor for high performance cadmium ion detection. J Mater Chem A 5(18):8385–8393CrossRef

14.

Wang X, Qi Y, Shen Y, Yuan Y, Zhang L, Zhang C, Sun Y (2020) A ratiometric electrochemical sensor for simultaneous detection of multiple heavy metal ions based on ferrocene-functionalized metal-organic framework. Sens Actuat B 310:127756CrossRef

15.

Ye W, Li Y, Wang J, Li B, Cui Y, Yang Y, Qian G (2020) Electrochemical detection of trace heavy metal ions using a Ln-MOF modified glass carbon electrode. J Solid State Chem 281:121032CrossRef

16.

Jiang H-L, Tsumori N, Xu Q (2010) A series of (6,6)-connected porous lanthanide−organic framework enantiomers with high thermostability and exposed metal sites: scalable syntheses, structures, and sorption properties. Inorg Chem 49(21):10001–10006CrossRef

17.

Jamali A, Tehrani AA, Shemirani F, Morsali A (2016) Lanthanide metal–organic frameworks as selective microporous materials for adsorption of heavy metal ions. Dalton Trans 45(22):9193–9200CrossRef

18.

Burnett DL, Oozeerally R, Pertiwi R, Chamberlain TW, Cherkasov N, Clarkson GJ, Krisnandi YK, Degirmenci V, Walton RI (2019) A hydrothermally stable ytterbium metal-organic framework as a bifunctional solid-acid catalyst for glucose conversion. Chem Commun 55:11446–11449CrossRef

19.

Gustafsson M, Bartoszewicz A, Martín-Matute B, Sun J, Grins J, Zhao T, Li Z, Zhu G, Zou X (2010) A family of highly stable lanthanide metal−organic frameworks: structural evolution and catalytic activity. Chem Mater 22(11):3316–3322CrossRef

20.

Andrius L, Aldona B, Aivaras K (2018) On the synthesis and chracterization of lanthanide metal organic framework. Ceramics 1:54–64CrossRef

21.

Dau TNN, Vu VH, Cao TT, Nguyen VC, Ly CT, Tran DL, Pham TTN, Loc NT, Piro B, Vu TT (2019) In-situ electrochemically deposited Fe₃O₄ nanoparticles onto graphene nanosheets as amperometric amplifier for electrochemical biosensing applications. Sens Actuact B Chem 283:52–60CrossRef

22.

Sun Y, Ma M, Tang B, Li S, Jiang L, Sun X, Que M, Tao C, Wu Z (2019) Graphene modified Cu-BTC with high stability in water and controllable selective adsorption of various gases. J Alloys Compd 808:151721CrossRef

23.

Torres N, Galicia J, Plasencia Y, Cano A, Echevarría F, Desdin-Garcia LF, Reguera E (2018) Implications of structural differences between Cu-BTC and Fe-BTC on their hydrogen storage capacity. Colloids Surf A 549:138–146CrossRef

24.

Teterin YA, Teterin AYu (2002) Structure of X-ray photoelectron spectra of lanthanide compounds. Russ Chem Rev 71(5):347–381CrossRef

25.

Xu X, Clarke C, Ma C, Casillas G, Das M, Guan M, Liu D, Wang L, Tadich A, Du Y, Ton-That C, Jin D (2017) Depth-profiling of Yb3+ sensitizer ions in NaYF4 upconversion nanoparticles. Nanoscale 9(23):7719–7726CrossRef

26.

Kumar KN, Vijayalakshmi L, Choi J (2019) Investigation of upconversion photoluminescence of Yb3+/Er3+:NaLaMgWO6 noncytotoxic double-perovskite nanophosphors. Inorg Chem 58(3):2001–2011CrossRef

27.

Gong G, Song Y, Tan H, Xie S, Zhang C, Xu L, Xu J, Zheng J (2019) Design of core/active-shell NaYF4:Ln3+@NaYF4:Yb3+ nanophosphors with enhanced red-green-blue upconversion luminescence for anti-counterfeiting printing. Compos Part B-Eng 179:107504CrossRef

28.

Ramasamy P, Chandra P, Rhee SW, Kim J (2013) Enhanced upconversion luminescence in NaGdF4:Yb, Er nanocrystals by Fe3+ doping and their application in bioimaging. Nanoscale 5(18):8711–8717CrossRef

29.

Wu F, Su H, Zhu X, Wang K, Zhang Z, Wong W-K (2016) Near-infrared emissive lanthanide hybridized carbon quantum dots for bioimaging applications. J Mater Chem B 4(38):6366–6372CrossRef

30.

Wang L, He J, Chen X, Lv Y (2020) A lanthanide MOF catalyst with an excellent thermal stability for the synthesis of polycarbonate diol. J Iran Chem Soc 17:2335–2343CrossRef

31.

Wu Y, Qiu L-G, Wang W, Li Z-Q, Xu T, Wu Z-Y, Jiang X (2009) Kinetics of oxidation of hydroquinone to p-benzoquinone catalyzed by microporous metal-organic frameworks M3(BTC)2 [M = copper(II), cobalt(II), or nickel(II); BTC = benzene-1,3,5-tricarboxylate] using molecular oxygen. Transit Met Chem 34(3):263–268CrossRef

32.

Oveisi AR, Khorramabadi-zad A, Daliran S (2016) Iron-based metal–organic framework, Fe(BTC): an effective dual-functional catalyst for oxidative cyclization of bisnaphthols and tandem synthesis of quinazolin-4(3H)-ones. RSC Adv 6(2):1136–1142CrossRef

33.

Pérez VG, Jiménez M, Blanco R, Sanchez-Sanchez M (2017) Semi-crystalline Fe-BTC MOF material as an efficient support for enzyme immobilization. Catal Today 304:119–126

34.

Yadav RS, Kumar D, Singh AK, Rai E, Rai SB (2018) Effect of Bi3+ ion on upconversion-based induced optical heating and temperature sensing characteristics in the Er3+/Yb3+ co-doped La₂O₃ nano-phosphor. RSC Adv 8(60):34699–34711CrossRef

35.

Naderi HR, Ganjali MR, Dezfuli AS, Norouzi P (2016) Sonochemical preparation of a ytterbium oxide/reduced graphene oxide nanocomposite for supercapacitors with enhanced capacitive performance. RSC Adv 6(56):51211–51220CrossRef

36.

da Luz LL, Lucena Viana BF, da Silva GCO, Gatto CC, Fontes AM, Malta M, Weber IT, Rodrigues MO, Júnior SA (2014) Controlling the energy transfer in lanthanide–organic frameworks for the production of white-light emitting materials. CrystEngComm 16(30):6914–6918CrossRef

37.

Donohue MD, Aranovich GL (1998) Classification of Gibbs adsorption isotherms. Adv Colloid Interface Sci 76–77:137–152CrossRef

38.

Dong S, Suo G, Li N, Chen Z, Peng L, Fu Y, Yang Q, Huang T (2016) A simple strategy to fabricate high sensitive 2,4-dichlorophenol electrochemical sensor based on metal organic framework Cu3(BTC)2. Sens Actuat B 222:972–979CrossRef

39.

Gumpu MB, Veerapandian M, Krishnan UM, Rayappan JB (2017) Simultaneous electrochemical detection of Cd(II), Pb(II), As(III) and Hg(II) ions using ruthenium(II)-textured graphene oxide nanocomposite. Talanta 162:574–582CrossRef

Titel: Novel nanoscale Yb-MOF used as highly efficient electrode for simultaneous detection of heavy metal ions
verfasst von: Manh B. Nguyen
Dau Thi Ngoc Nga
Vu Thi Thu
Benoît Piro
Thuan Nguyen Pham Truong
Pham Thi Hai Yen
Giang H. Le
Le Quoc Hung
Tuan A. Vu
Vu Thi Thu Ha
Publikationsdatum: 02.02.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 13/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05815-3

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