Preparation and structural study of Mg_1−x Zn _x TiO₃ ceramics and their dielectric properties from 1 Hz to 7.7 GHz

A series of Mg_1−x Zn _x TiO₃, x = 0–0.5 (MZT0–MZT0.5) ceramics was synthesised and characterised. The dielectric properties of the samples in the frequency range of 1 Hz–7.7 GHz were explored using three different methods: a contacting electrode method, a parallel-plate method and a perturbed resonator method. The electrical properties in the space charge and dipolar polarisation frequency ranges are discussed in relation to the phase composition and microstructure data. Differences in the zinc substitution divided the dielectrics into two groups, namely MZT0–MZT0.2 and MZT0.3–MZT0.5, each with different amount of a main Mg_1−x Zn _x TiO₃ solid solution phase and a secondary solid solution phase. Zinc substitution promoted the density of the ceramics, improved the purity of the main phase and increased the permittivity for frequencies up to 10⁸ Hz, but reduced the permittivity in the microwave range. In the MZT0.3–MZT0.5 samples, for frequencies less than 1 MHz the quality (Q × f) factors were lower and log σ _a.c, the AC conductivity, was higher than for the MZT0–MZT0.2 samples. Above 10 MHz, the (Q × f) factors and log σ _a.c of the two groups were similar.