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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 21/2019

05.10.2019 | Review

Facile synthesis of CoNi2S4 nanoparticles grown on carbon fiber cloth for supercapacitor application

verfasst von: Peng Liu, Yanwei Sui, Fuxiang Wei, Jiqiu Qi, Qingkun Meng, Yaojian Ren, Yezeng He

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 21/2019

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Abstract

A facile one-step hydrothermal route has been developed to directly synthesize CoNi2S4 nanoparticles on carbon fiber cloth (CC) to study the synergistic effect of bimetallic sulfides and carbon substrate on the electrochemical performance of supercapacitor electrode. The integrated binder-free CoNi2S4/CC electrode possesses an outstanding specific capacitance of 1165 F g−1 at 1 A g−1, and excellent rate capacitance (75.3% retention at 10 A g−1) in a three-electrode system, which is 27.2% and 32.2% higher than that of pure CoNi2S4 electrode. Detailed electrochemical tests and results showed that the surface capacitance effect ratio of the CoNi2S4/CC electrode is higher than that of pure CoNi2S4 electrode because of the introduction of CC. The CC substrates can provide a channel for electrolyte electrons and ions to promote reaction kinetics and shorten the diffusion distance of the redox reaction, thereby improving the performance of the pseudocapacitor CoNi2S4. Besides, the assembled asymmetric supercapacitors based on CoNi2S4/CC electrode and reduced graphene oxide electrode displayed a high specific energy density of 33.2 Wh kg−1 at 800 W kg−1, remarkable electrochemical stability (87.1% retention after 10,000 circulations) and high rate stability.
Nächster Artikel Advances in gas ionization sensors based on nanostructured materials: a review

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Metadaten
Titel
Facile synthesis of CoNi2S4 nanoparticles grown on carbon fiber cloth for supercapacitor application
verfasst von
Peng Liu
Yanwei Sui
Fuxiang Wei
Jiqiu Qi
Qingkun Meng
Yaojian Ren
Yezeng He
Publikationsdatum
05.10.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 21/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02304-x

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