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Hg(II) Selective Complexation by Chromoionophoric Calix[4]arene Derivative

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Abstract

The present article describes an exploration regarding Hg(II) selective complexation behavior of 5,11,17,23-tetrakis[(N,N-dimethylamino)methyl]-25,26,27,28-tetrahydroxycalix[4]arene (4). The binding affinity of 4 toward selected transition metal ions such as Cd(II), Co(II), Cu(II), Hg(II), Ni(II), Pb(II) and Zn(II) have been investigated by UV-visible and fluorescence spectroscopies. From the results it has been noticed that 4 confers a pronounced preference for Hg(II) in complexation phenomenon even in the presence of other metal ions. The results of Job’s plot analysis reveal 1:1 host-guest complex formation between Hg(II) and 4. The FT-IR spectroscopy also supports the complexation affinity of 4 for Hg(II).

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Acknowledgements

We thank the National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro/Pakistan for the financial support of this work.

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  1. National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, 76080, Pakistan

    Mansoor Ahmed Qazi, Imdadullah Qureshi & Shahabuddin Memon

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  1. Mansoor Ahmed Qazi
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  2. Imdadullah Qureshi
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  3. Shahabuddin Memon
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Correspondence to Shahabuddin Memon.

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Qazi, M.A., Qureshi, I. & Memon, S. Hg(II) Selective Complexation by Chromoionophoric Calix[4]arene Derivative. J Fluoresc 21, 1231–1238 (2011). https://doi.org/10.1007/s10895-010-0802-2

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  • DOI: https://doi.org/10.1007/s10895-010-0802-2

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