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Synthesis and Dielectric Properties of Polyimide-Titania Hybrid Composites

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Abstract

A new class of polyimide-titania (TiO2) composites with chemical bonds between the polyimide and titania system has been synthesized by the sol–gel reaction and characterized. The hybrid composite films were obtained by the reaction of lysine-organotitane monomer, which is formulated as [(EtO)3Ti (lysinate)]2, followed by polycondensation with dianhyride in N-methyl-2-pyrrolidone (NMP) solution, followed by heating at 100, 200, and 300 °C. The presence of chemical bonds between polyimide (PI) and titania has great effect on the properties of polyimide films, especially on their thermal and dielectric properties. The dielectric constants of the resultant nanocomposites are lower than the usual polyimide films due to the increased free volume and less polar Ti–O–Ti groups, and can be tuned by varying the molar ratio of tetraethoxysilane (TEOT) in the feed. The polyimide units offer additional advantages of imparting thermal and mechanical strength.

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References

  1. S. Sakka, K. Kamiya, J. Non-Cryst. Solids. 42, 403 (1980)

    Article  CAS  Google Scholar 

  2. G.L. Wilkes, B. Orler, H. Huang, Polym. Prepr. 26, 300 (1985)

    CAS  Google Scholar 

  3. H. Schmidt, J. Non-Cryst. Solids. 73, 681 (1985)

    Article  CAS  Google Scholar 

  4. R. Roy, Science 238, 1664 (1987)

    Article  CAS  Google Scholar 

  5. L.L. Hench, M.J.R. Wilson, J. Non-Cryst Solids 121, 234 (1990)

    Article  CAS  Google Scholar 

  6. R. Reisfeld, D. Brusilovsky, M. Eyal, E. Miron, Z. Burshstein, J. Ivri, Chem. Phys. Lett. 160, 43 (1989)

    Article  CAS  Google Scholar 

  7. A. Chatterjee, D. Das, D. Chakravorty, K. Choudhury, Appl. Phys. Lett. 57, 1360 (1990)

    Article  CAS  Google Scholar 

  8. A. Chatterjee, A. Datta, A.K. Giri, D. Das, D. Chakravorty, J. Appl. Phys. 72, 3832 (1992)

    Article  CAS  Google Scholar 

  9. U. Schubert, S. Tewinkel, R. Lamber, Chem. Mater. 8, 2047 (1996)

    Article  CAS  Google Scholar 

  10. S. Gross, V.D. Noto, U. Schubert, J. Non-Cryst. Solids 322, 154 (2003)

    Article  CAS  Google Scholar 

  11. D.W. Schaefer, J.E. Mark, Polymer-Based Molecular Composites, vol. 171 (Materials Research Society, Pittsburgh, 1990)

  12. J. Wen, J.E. Mark, Polym. J. 27, 492 (1995)

    Article  CAS  Google Scholar 

  13. S.J. Clarson, J.E. Mark, Polym. Commun. 28, 249 (1987)

    CAS  Google Scholar 

  14. B.M. Novak, D. Auerbach, C. Verrier, Chem. Mater. 6, 282 (1994)

    Article  CAS  Google Scholar 

  15. C.J.T. Landry, B.K. Coltrain, J.A. Wesson, N. Zumbulyadis, J.L. Lippert, Polymer. 33, 1496 (1992)

    Article  CAS  Google Scholar 

  16. H.H. Huang, G.L. Wilkes, J.G. Carlson, Polymer 30, 2001 (1989)

    Article  CAS  Google Scholar 

  17. A. Morikawa, Y. Iyoku, M. Kakimoto, Y. Imai, Polym. J. 24(1), 107 (1992)

    Article  CAS  Google Scholar 

  18. S. Wang, Z. Ahmad, JE Mark, Chem. Mater. 6, 943 (1994)

    Article  CAS  Google Scholar 

  19. A. Morikawa, Y. Iyoku, M. Kakimoto, Y. Imai, Chem. Mater. 6, 913 (1994)

    Article  CAS  Google Scholar 

  20. S.A. Jenekhe, J.A. Osaheni, Chem. Mater. 6, 1906 (1994)

    Article  CAS  Google Scholar 

  21. P.L. Shao, K.A. Mauritz, R.B. Moore, Chem. Mater. 7, 192 (1995)

    Article  CAS  Google Scholar 

  22. K.A. Mauritz, I.D. Stefanithis, S.V. Davis, R.W. Scheetz, R.K. Rope, G.L. Wilkes, J. Appl. Polym. Sci. 55, 181 (1995)

    Article  CAS  Google Scholar 

  23. S. Wu, Polymer Interface and Adhesion (Marcel Dekker, New York, 1982)

    Google Scholar 

  24. J. Wen, G.L. Wikes, Chem. Mater. 8, 1667 (1996)

    Article  CAS  Google Scholar 

  25. K.L. Mittal, Polyimides: Synthesis, Characterization and Applications (Plenum, New York, 1984)

    Google Scholar 

  26. M.T. Bessonov, M.M. Koton, V.V. Kudryavtsev, L.A. Laius, Polyimides: Thermally Stable Polymers (Consultants Bureau, New York, 1987)

    Google Scholar 

  27. C. Feger, M.M. Khojasteh, J.E. McGrath (eds.), Polyimides: Materials, Chemistry and Characterization (Elsevier, Amsterdam, 1989)

  28. Z. Ahmad, J.E. Mark, Chem. Mater. 13, 3320 (2001)

    Article  CAS  Google Scholar 

  29. T. Seçkin, S. Köytepe, I. Ozdemir, Des. Monomers Polym. 6, 175 (2003)

    Article  Google Scholar 

  30. C.P. Yang, S.H. Hsiao, H.Y. Yang, Mat. Chem. Phys. 64, 116 (2000)

    Article  CAS  Google Scholar 

  31. T. Seckin, S. Koytepe, S. Demir, I. Ozdemir, B. Centinkaya, J. Inorg. Organometal. Polym. 13, 223 (2003)

    Article  CAS  Google Scholar 

  32. Y. Akhmad, X. Jungmin, J. Wang, J. Wei, J. Electroceramics 16(4), 431 (2006)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Inonu, Malatya, 44280, Turkey

    Süleyman Köytepe, Turgay Seçkin & Nilüfer Kıvrılcım

  2. Department of Physics, University of Inonu, Malatya, 44280, Turkey

    H. İbrahim Adıgüzel

Authors
  1. Süleyman Köytepe
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  2. Turgay Seçkin
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  3. Nilüfer Kıvrılcım
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  4. H. İbrahim Adıgüzel
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Correspondence to Turgay Seçkin.

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Köytepe, S., Seçkin, T., Kıvrılcım, N. et al. Synthesis and Dielectric Properties of Polyimide-Titania Hybrid Composites. J Inorg Organomet Polym 18, 222–228 (2008). https://doi.org/10.1007/s10904-007-9169-5

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