Skip to main content
SpringerLink
Log in

Molecular Recognition and Catalysis by Molecularly Imprinted Polymer Catalysts: Thermodynamic and Kinetic Surveys on the Specific Behaviors

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

The article presents thermodynamic and kinetic surveys on the specific recognition and catalysis by molecularly imprinted polymer catalysts. Using p-nitrophenyl phosphate as templates and 1-allylimidazole as functional monomers, the imprinted material was prepared. The prepared polymer catalyst shows a highly specific recognition and catalysis toward the imprint species. Kinetic analysis indicates that this specific behavior, in nature, can be a result of a preferential promotion. The specific imprint leads to a larger hydrolysis rate in the imprint species than in its analogue. Thermodynamic study also implies that the molecular induction generating from the imprint to NPA is larger than to its analogue, which thus makes the polymer capable of specifically alluring the imprint species to bind.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. U. Lange, N.V. Roznyatovskaya, V.M. Mirsky, Anal. Chim. Acta 614(1), 1–26 (2008)

    Article  CAS  Google Scholar 

  2. X. Hu, J. Pan, Y. Hu, Y. Huo, G. Li, J. Chromatogr. A 1188(2), 97–107 (2008)

    Article  CAS  Google Scholar 

  3. N. Bereli, M. Andac, G. Baydemir, R. Say, I.Y. Galaev, A. Denizli, J. Chromatogr. A 1190(1), 18–26 (2008)

    Article  CAS  Google Scholar 

  4. A.M. Gue, A. Lattes, E. Laurent, M. Mauzac, A.F. Mingotaud, Anal. Chim. Acta 614(1), 63–70 (2008)

    Article  CAS  Google Scholar 

  5. Z.S. Liu, C. Zheng, C. Yan, R.Y. Gao, Electrophoresis 28(2), 127–136 (2007)

    Article  CAS  Google Scholar 

  6. J.Y. Philip, J.J. Buchweishaija, L.L. Mkayula, L.L. Ye, J. Agric. Food Chem. 55(22), 8870–8876 (2007)

    Article  CAS  Google Scholar 

  7. C. Gomy, A.R. Schmitzer, Org. Lett. 9(20), 3865–3868 (2007)

    Article  CAS  Google Scholar 

  8. M. Haruki, Y. Konnai, A. Shimada, H. Takeuchi, Biotechnol. Prog. 23(5), 1254–1257 (2007)

    CAS  Google Scholar 

  9. B. Sellergren, Angew. Chem. Int. Ed. 39(6), 1031–1037 (2000)

    Article  CAS  Google Scholar 

  10. W.K. Li, S.J. Li, Adv. Polym. Sci. 206(4), 191–210 (2007)

    Article  CAS  Google Scholar 

  11. P. Parmpi, P. Kofinas, Biomaterials 25(10), 1969–1973 (2004)

    Article  CAS  Google Scholar 

  12. S.J. Li, K.J. Tong, D.N. Zhang, X. Huang, J. Inorg. Organomet. Polym. 18(2), 264–271 (2008)

    Article  CAS  Google Scholar 

  13. D.N. Zhang, S.J. Li, W.K. Li, Y.F. Chen, Catal. Lett. 115(3), 169–175 (2007)

    Article  CAS  Google Scholar 

  14. M.X. Zheng, S.J. Li, X. Luo, J. Macromol. Sci. A 44(11), 1187–1194 (2007)

    Article  CAS  Google Scholar 

  15. X. Huang, S.J. Li, J. Inorg. Organomet. Polym. 18(2), 277–283 (2008)

    Article  CAS  Google Scholar 

  16. M. Melaimi, S. Sole, C.W. Chiu, H. Wang, F.P. Gabbai, Inorg. Chem. 45(20), 8136–8143 (2006)

    Article  CAS  Google Scholar 

  17. A.K. Udit, K.D. Hagen, P.J. Goldman, A. Star, J.M. Gillan, H.B. Gray, M.G. Hill, J. Am. Chem. Soc. 128(31), 10320–10325 (2006)

    Article  CAS  Google Scholar 

  18. S. Dorr, U. Schade, P. Hellwig, M. Ortolani, J. Phys. Chem. B. 111(51), 14418–14422 (2007)

    Article  CAS  Google Scholar 

  19. K. Lettau, A. Warsinke, M. Katterle, B. Danielsson, F.W. Scheller, Angew. Chem. Int. Ed. 45(42), 6986–6990 (2006)

    Article  CAS  Google Scholar 

  20. C.L. Fang, S.J. Li, J. Inorg. Organomet. Polym. 17(4), 623–629 (2007)

    Article  CAS  Google Scholar 

  21. S.J. Li, J. Hu, B.L. Liu, H. Li, D.Q. Wang, X.F. Liao, Polymer 45(5), 1511–1516 (2004)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors like to thank the National Science Foundation of China (Grant No. 20603010) and the Science Foundation of Hubei Province (Grant Nos. 2007ABA339 and 2007ABA381) for presenting financial supports to carry out this research.

Author information

Authors and Affiliations

  1. Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079, China

    Kejun Tong, Shan Xiao, Songjun Li & Jing Wang

Authors
  1. Kejun Tong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shan Xiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Songjun Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jing Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Songjun Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tong, K., Xiao, S., Li, S. et al. Molecular Recognition and Catalysis by Molecularly Imprinted Polymer Catalysts: Thermodynamic and Kinetic Surveys on the Specific Behaviors. J Inorg Organomet Polym 18, 426–433 (2008). https://doi.org/10.1007/s10904-008-9217-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-008-9217-9

Keywords

Search

Navigation