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A Novel 3D Europium (III) Coordination Polymer Constructed from 3,5-Pyridinedicarboxylate Acid: Synthesis, Crystal Structure and Emission Spectrum

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Abstract

A novel 3D coordination polymer Eu2(PDC)3(H2O)3 (1) has been synthesized by hydrothermal reaction of europium chloride with 3,5-pyridinedicarboxylate acid (H2PDC) under acidic condition (pH 2–3). Complex 1 is a 3D coordination polymer via 1D infinite chains built by the pyridinium moieties of the PDC2− anions. The thermal analyses and luminescent properties of 1 have also been investigated.

Graphical Abstract

A novel 3D coordination polymer Eu2(PDC)3(H2O)3 has been synthesized by hydrothermal reaction of europium chloride with 3,5-pyridinedicarboxylate acid under acidic conditions (pH 2–3). The formation of the title complex demonstrates that pH plays an important role during the synthesis.

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References

  1. (a) S.R. Batten, R. Robson, Angew. Chem. Int. Ed. 37, 1460 (1998); (b) M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 34, 319 (2001); (c) G.S. Papaefstathiou, L.R. MacGillivray, Coord. Chem. Rev. 246, 169 (2003); (d) O.R. Evans, W. Lin, Acc. Chem. Res. 35, 511 (2002); (e) B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

  2. (a) J.S. Seo, D. Whang, H. Lee, S.I. Jun, J. Oh, Y.J. Jeon, K. Kim, Nature 404, 982 (2000); (b) O.R. Evans, H.L. Ngo, W. Lin, J. Am. Chem. Soc. 123, 10395 (2001); (c) W. Lin, J. Solid State Chem. 178, 2486 (2005)

  3. (a) H. Li, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Nature 402, 276 (1999); (b) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe, O.M. Yaghi, Science 295, 469 (2002); (c) J.L.C. Rowsell, E.C. Spencer, J. Eckert, J.A.K. Howard, O.M. Yaghi, Science 309, 1350 (2005); (d) G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science 309, 2040 (2005)

  4. (a) A.J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K.A. Abboud, G. Christou, Angew. Chem. Int. Ed. 43, 2117 (2004); (b) M. Murugesu, M. Habrych, W. Wernsdorfer, K.A. Abboud, G. Christou, J. Am. Chem. Soc. 126, 4766 (2004); (c) G.J. Halder, C.J. Kepert, B. Moubaraki, K.S. Murray, J.D. Cashion, Science 298, 1762 (2002)

  5. G.B. Deacon, R. Philips, Coord. Chem. Rev. 88, 227 (1980)

    Google Scholar 

  6. (a) H.K. Chae, M. Eddaoudi, J. Kim, S.I. Hauck, J.F. Hartwig, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 123, 11482 (2001); (b) J.L.C. Rowsell, A.R. Millward, K.S. Park, O.M. Yaghi, J. Am. Chem. Soc. 126, 5666 (2004); (c) J.L.C. Rowsell, O.M. Yaghi, J. Am. Chem. Soc. 128, 1304 (2006)

  7. (a) L.-Y. Zhang, G.-F. Liu, S.-L. Zheng, B.-H. Ye, X.-M. Zhang, X.-M. Chen, Eur. J. Inorg. Chem. 2965 (2003); (b) J. Tao, M.-L. Tong, J.-X. Shi, X.-M. Chen, S.W. Ng, Chem. Commun. 2043 (2000); (c) C.S. McCowan, T.L. Groy, M.T. Caudle, Inorg. Chem. 41, 1120 (2002); (d) Q.B. Bo, Z.X. Sun, G.L. Song, G.X. Sun, J. Inorg. Organmet. Polym. Mater. 17, 615 (2007); (e) R.Y. Huang, X.J. Kong, G.X. Liu, J. Inorg. Organmet. Polym. Mater. 18, 304 (2008)

  8. (a) N.W. Ockwig, O. Delgado-Friedrichs, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 38, 176 (2005); (b) I.A. Baburin, V.A. Blatov, L. Carlucci, G. Ciani, D.M. Proserpio, J. Solid State Chem. 178, 2452 (2005); (c) V.A. Blatov, L. Carlucci, G. Ciani, D.M. Proserpio, CrystEngComm 6, 377 (2004)

  9. A.F. Wells, Three-Dimensional Nets and Polyhedra, (Wiley–Interscience, New York, 1977)

  10. M. Bredol, U. Kynast, C. Ronda, Adv. Mater. 3, 361 (1991)

    Google Scholar 

  11. (a) Y.-Q. Sun, J. Zhang, Y.-M. Chen, G.-Y. Yang, Angew. Chem. Int. Ed. 44, 5814 (2005); (b) M.R. Bnrgstein, M.T. Gamer, P.W. Roesky, J. Am. Chem. Soc. 126, 5213 (2004); (c) T.M. Reineke, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Angew. Chem. Int. Ed. 38, 2590 (1999)

  12. SAINT Version 6.02a, Software Reference Manual (Bruker AXS Inc. Madison, W1, 2002)

  13. G.M. Sheldrick, SADABS: Program for Empirical Absorption Correction of Area Detector Data (University of Göttingen, 1996)

  14. G.M. Sheldrick, SHELXS-97: Program for Crystal Structure Solution (University of Göttingen, 1997)

  15. G.M. Sheldrick, SHELXL-97: Program for Crystal Structure Refinement (University of Göttingen, 1997)

  16. X.W. Wang, X. Li, J.Z. Chen, G. Zheng, H.L. Hong, Eur. J. Inorg. Chem. 98 (2008)

  17. Z.M. Wang, L.J. van de Burgt, G.R. Choppin, Inorg. Chim. Acta 310, 248 (2000)

    Google Scholar 

  18. X.L. Wang, C. Qin, E.B. Wang, Y.G. Li, N. Hao, C.W. Hu, L. Xu, Inorg. Chem. 43, 1850 (2004)

    Google Scholar 

  19. L. Pan, N.W. Zheng, Y.G. Wu, S. Han, R.Y. Yang, X.Y. Huang, J. Li, Inorg. Chem. 40, 828 (2001)

    Google Scholar 

  20. A. De Betterncount Dias, S. Viswanathan, Chem. Commun. 1024 (2004)

  21. B. Zhao, X.Y. Chen, P. Cheng, D.Z. Liao, S.P. Yan, Z.H. Jiang, J. Am. Chem. Soc. 126, 15394 (2004)

    Google Scholar 

  22. J.-C.G. Bünzli, G.R. Choppin (eds.) Lanthanide Probes in life, Chemical and Earth Sciences, Theory and Practice (Elsevier Scientific Publishers, Amsterdam, 1989)

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20731004), the Natural Science Foundation for Outstanding Scholars of Anhui Province (Grant No. 044-J-04011), the Natural Science Foundation of Education Commission of Anhui Province (No. KJ2007B092, KJ2008B004) and the Natural Science Foundation of Anqing Normal University, China (No. 2003ylz06).

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Authors and Affiliations

  1. Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003, People’s Republic of China

    Guang-Xiang Liu, Hong Chen, Kun Zhu & Xiao-Ming Ren

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  1. Guang-Xiang Liu
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  2. Hong Chen
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  3. Kun Zhu
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  4. Xiao-Ming Ren
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Correspondence to Guang-Xiang Liu.

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Liu, GX., Chen, H., Zhu, K. et al. A Novel 3D Europium (III) Coordination Polymer Constructed from 3,5-Pyridinedicarboxylate Acid: Synthesis, Crystal Structure and Emission Spectrum. J Inorg Organomet Polym 18, 457–462 (2008). https://doi.org/10.1007/s10904-008-9222-z

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