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New Flower-Shaped Lead(II) Coordination Polymer at the Nano Scale: Synthesis, Structural Characterization and DFT Calculations of [Pb(o-phen)(N3)2] n Containing the Pb-(μ1,1-N3)(μ1,3-N3) Motif

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Abstract

A new nano-flower lead(II) azido coordination polymer from the ligand, orthophenanthroline (o-phen), [Pb(o-phen)(μ1,1-N3)(μ1,3-N3)] n (1), was synthesized by a sonochemical method. Compound 1 was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), elemental analyses and IR spectroscopy. Single crystalline material was obtained using a heat gradient applied to a solution of the reagents. The structure of 1 is a coordination polymer of lead(II) containing the Pb-(μ1,1-N3)(μ1,3-N3) motif, formed of one-dimensional chains. The structure of the 1 was optimized by density functional theory. Structural parameters and IR spectra for 1 are consistent with the crystal structure. Pure phase PbO nanoparticles were obtained by thermolysis of 1 with oleic acid as a surfactant at 180 and 200 °C an air. PbO nanoparticles were characterized by XRD and SEM.

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Acknowledgments

This work was supported by Grant No. RTI04-01-04 from the Regional Technology Innovation Program of the Ministry of Knowledge Economy (MKE).

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Authors and Affiliations

  1. Department of Chemistry, Shahrood Branch, Islamic Azad University, 36155/133, Shahrood, Iran

    Safa Ali-Asgari & Ehsan Maskani

  2. WCU Nano Research Center, School of Mechanical Engineering, Yeungnam University, Gyeongsan, 712-749, South Korea

    Babak Mirtamizdoust, Sang Woo Joo & Younes Hanifehpour

  3. Inorganic Compounds Research Laboratory, Faculty of Chemistry, University of Tabriz, 51666-16471, Tabriz, Iran

    Babak Mirtamizdoust & Younes Hanifehpour

  4. Department of Nano, Medical and Polymer Materials, Yeungnam University, Gyeongsan, 712-749, South Korea

    Tae Hwan Oh

Authors
  1. Babak Mirtamizdoust
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  2. Safa Ali-Asgari
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  3. Sang Woo Joo
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  4. Ehsan Maskani
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  5. Younes Hanifehpour
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Correspondence to Babak Mirtamizdoust or Sang Woo Joo.

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Mirtamizdoust, B., Ali-Asgari, S., Joo, S.W. et al. New Flower-Shaped Lead(II) Coordination Polymer at the Nano Scale: Synthesis, Structural Characterization and DFT Calculations of [Pb(o-phen)(N3)2] n Containing the Pb-(μ1,1-N3)(μ1,3-N3) Motif. J Inorg Organomet Polym 23, 751–757 (2013). https://doi.org/10.1007/s10904-012-9807-4

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