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Dielectric Investigation of NaLiS Nanoparticles Loaded on Alginate Polymer Matrix Synthesized by Single Pot Microwave Irradiation

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Abstract

Sodium lithium sulfide (NaLiS) nanocomposite have been successfully synthesized by using microwave-irradiation (MWI) method. The study suggested that the application of microwave heating is to produce homogeneous and fine NaLiS nanocomposite which were achieved by using the precursors of lithium acetate and thioacetamide in the presence of sodium alginate biopolymer. FTIR is used to identify the structural coordination and functional groups of the prepared nanocomposite. The structural property of NaLiS particles was investigated by XRD. The surface morphology and elemental composition of synthesized material was confirmed by SEM and EDX analyses. The optical property was studied by using UV–Vis spectrophotometer. Thermal stability of as prepared sample was studied by TGA/DTG analysis. Electrical transport studies of the prepared nanocomposite have been analyzed for various temperatures. NaLiS nanocomposite has ionic conductivity of ~ 10−7 S cm−1 at 35 °C which is six orders of magnitude higher than that of micro sized bulk Li2S (~ 10−13 S cm−1).

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References

  1. B. Choudhuri, A. Mondal, S. Murli, M.D. Dwivedi, M. Henini, J. Alloys Compd. 712, 7 (2017)

    Article  CAS  Google Scholar 

  2. C. Sasikala, N. Durairaj, I. Baskaran, B. Sathyaseelan, M. Henini, E. Manikandan, J. Alloys Compd. 712, 870 (2017)

    Article  CAS  Google Scholar 

  3. K. Thanigai Arul, E. Manikandan, P.P. Murmu, J. Kennedy, M. Henini, J. Alloys Compd. 720, 395 (2017)

    Article  CAS  Google Scholar 

  4. B. Sathyaseelan, E. Manikandan, I. Baskaran, K. Senthilnathan, K. Sivakumar, M.K. Moodley, R. Ladchumananandasivam, M. Maaza, J. Alloys Compd. 694, 556 (2017)

    Article  CAS  Google Scholar 

  5. B. Sathyaseelan, E. Manikandan, K. Sivakumar, J. Kennedy, M. Maaza, J. Alloys Compd. 651, 479 (2015)

    Article  CAS  Google Scholar 

  6. P. Couture, G.V.M. Williams, J. Kennedy, J. Leveneur, P.P. Murmu, S.V. Chong, S. Rubanov, J. Alloys Compd. 695, 3061 (2017)

    Article  CAS  Google Scholar 

  7. T. Prakash, G.V.M. Williams, J. Kennedy, S. Rubanov, J. Alloys Compd. 667, 255 (2016)

    Article  CAS  Google Scholar 

  8. J. Kennedy, A. Markwitz, Z. Li, W. Gao, C. Kendrick, S.M. Durbin, R. Reeves, Curr. Appl. Phys. 6, 495 (2006)

    Article  Google Scholar 

  9. J. Kennedy, P.P. Murmu, J. Leveneur, A. Markwitz, J. Futter, Appl. Surf. Sci. 367, 52 (2016)

    Article  CAS  Google Scholar 

  10. E. Manikandan, G. Kavitha, J. Kennedy, Ceram. Int. 40, 16065 (2014)

    Article  CAS  Google Scholar 

  11. J. Kennedy, P.P. Murmu, E. Manikandan, S.Y. Lee, J. Alloys Compd. 616, 614 (2014)

    Article  CAS  Google Scholar 

  12. F. Fang, J. Kennedy, J. Futter, T. Hopf, A. Markwitz, E. Manikandan, G. Henshaw, Nanotech 22, 335702 (2011)

    Article  CAS  Google Scholar 

  13. E. Manikandan, V. Murugan, G. Kavitha, P. Babu, M. Maaza, Mater. Lett. 131, 225 (2014)

    Article  CAS  Google Scholar 

  14. J. Kennedy, P.P. Murmu, P.S. Gupta, D.A. Carder, S.V. Chong, J. Leveneur, S. Rubanov, Mat. Sci. Sem. Pro. 26, 56 (2014)

    Google Scholar 

  15. M. Eom, S. Son, C. Park, S. Noh, W.T. Nichols, D. Shin, Electrochim. Acta 230, 279 (2017)

    Article  CAS  Google Scholar 

  16. B. Dunn, H. Kamath, J.M. Tarascon, Science 334, 928 (2011)

    Article  CAS  Google Scholar 

  17. P.G. Bruce, S.A. Freunberger, L.J. Hardwick, J.M. Tarascon, Nat. Mater. 11, 19 (2012)

    Article  CAS  Google Scholar 

  18. A. Manthiram, Y. Fu, Y.S. Su, Acc. Chem. Res. 46, 1125 (2013)

    Article  CAS  Google Scholar 

  19. J. Hassouna, Y.K. Sunb, B. Scrosatia, J. Power Sources 196(1), 343 (2011)

    Article  Google Scholar 

  20. J. Hassoun, B. Scrosati, Angew. Chem. Int. Ed. 49, 2371 (2010)

    Article  CAS  Google Scholar 

  21. M. Hagen, E.Q. González, S. Dorfler, G. Fahrer, J. Tubke, M.J. Hoffmann, H. Althues, R. Speck, M. Krampfert, S. Kaskel, H. Föll, J. Power Sources, 248, 1058 (2014)

    Article  CAS  Google Scholar 

  22. Z.W. Seh, W. Li, J.J. Cha, G. Zheng, Y. Yang, M.T. McDowell, P.C. Hsu, Y. Cui, Nat. Commun. 4, 1331 (2013)

    Article  Google Scholar 

  23. X. He, J. Ren, L. Wang, W. Pu, C. Jiang, C. Wan, J. Power Sources 190, 154 (2009)

    Article  CAS  Google Scholar 

  24. K. Cai, M.K. Song, E.J. Cairns, Y. Zhang, Nano Lett. 12, 6474 (2012)

    Article  CAS  Google Scholar 

  25. Y. Yang, M.T. McDowell, A. Jackson, J.J. Cha, S.S. Hong, Y. Cui, Nano Lett. 10, 1486 (2010)

    Article  CAS  Google Scholar 

  26. L. Suo, Y.S. Hu, H. Li, M. Armand, L. Chen, Nat. Commun. 4, 1481 (2013)

    Article  Google Scholar 

  27. J. He, Y. Chen, W. Lv, K. Wen, C. Xu, W. Zhang, Y. Li, W. Qin, W. He, ACS Nano 10(12), 10981 (2016)

    Article  CAS  Google Scholar 

  28. C. Wang, X. Wang, Y. Yang, A. Kushima, J. Chen, Y. Huang, J. Li, Nano Lett. 15(3), 1796 (2015)

    Article  CAS  Google Scholar 

  29. L. Wang, Y.W.Y. Xia, Energy Environ. Sci. 8, 1551 (2015)

    Article  CAS  Google Scholar 

  30. L. Sun, D. Wang, Y. Luo, K. Wang, W. Kong, Y. Wu, L. Zhang, K. Jiang, Q. Li, Y. Zhang, J. Wang, S. Fan, ACS Nano 10(1), 1300 (2016)

    Article  CAS  Google Scholar 

  31. Z. Yang, J. Guo, S.K. Das, Y. Yu, Z. Zhou, H.D. Abruna, L.A. Archer, J. Mater. Chem. A 1, 1433 (2013)

    Article  CAS  Google Scholar 

  32. G.T. Zhou, O. Palchik, V.G. Pol, E. Sominski, Y. Koltypin, A. Gedanken, J. Mater. Chem. 13, 2607 (2003)

    Article  CAS  Google Scholar 

  33. H.L. Cao, Q. Gong, X.F. Qian, H.L. Wang, J.T. Zai, Z.K. Zhu, Cryst. Growth Des. 7, 425 (2007)

    Article  CAS  Google Scholar 

  34. Q.Z. Yao, G. Jin, G.T. Zhou, Mater. Chem. Phys. 109, 164 (2008)

    Article  CAS  Google Scholar 

  35. T. Druzhinina, S. Hoeppener, U.S. Schubert, Adv. Funct. Mater. 19, 2819 (2009)

    Article  CAS  Google Scholar 

  36. E. Fourest, B. Volesky, Environ. Sci. Technol. 30(1), 277 (1995)

    Article  Google Scholar 

  37. D. Fang, Y. Liu, S. Jiang, J. Nie, G. Ma, Carbohydr. Polym. 85, 276 (2011)

    Article  CAS  Google Scholar 

  38. S. Parani, E. Prabakaran, M. Alexander, B.S. Lakshmi, K. Pandian, Bull. Korean Chem. Soc. 33, 10 (2012)

    Google Scholar 

  39. C. Sartori, D.S. Finch, B. Ralph, Polymer 38, 43 (1997)

    Article  CAS  Google Scholar 

  40. K. Sakugawa, A. Ikeda, A. Takemura, H. Ono, J. Appl. Polym. Sci. 93, 1372 (2004)

    Article  CAS  Google Scholar 

  41. P. Premlata, R. Bipul, P.S. Sankar, Indian J. Pure Appl. Phys. 47, 804 (2009)

    Google Scholar 

  42. H. Wang, P. Fang, Z. Chen, S. Wang, Appl. Surf. Sci. 253, 8495 (2007)

    Article  CAS  Google Scholar 

  43. R.J. Klein, S. Zhang, S. Dou, B.H. Jones, R.H. Colby, J. Runt, J. Chem. Phys. 124, 144903 (2006)

    Article  Google Scholar 

  44. A. Chandra, A. Chandra, K. Thakur, Electrochim. Acta 30(2), 81 (2012)

    Article  CAS  Google Scholar 

  45. D. Vanitha, S.A. Bahadur, N. Nallamuthu, S. Athimoolam, A. Manikandan, J. Inorg. Organomet. Polym. 27, 257 (2017)

    Article  CAS  Google Scholar 

  46. D. Vanitha, S.A. Bahadur, N. Nallamuthu, S. Athimoolam, A. Manikandan, J. Inorg. Organomet. Polym. 27, 363 (2017)

    Article  Google Scholar 

  47. V. Parameswaran, N. Nallamuthu, P. Devendran, E.R. Nagarajan, A. Manikandan, Phys. B 515, 89 (2017)

    Article  CAS  Google Scholar 

  48. Z. Lin, Z. Liu, N.J. Dudney, C. Liang, ACS Nano 7(3), 2829 (2013)

    Article  CAS  Google Scholar 

  49. T. Shekharam, V.L. Rao, G. Yellaiah, T. Mohan Kumar, M. Nagubhushanam, J. Alloys Compd. 617, 952 (2014)

    Article  CAS  Google Scholar 

  50. I.M. Hodge, M.D. Ingram, A.R. West, J. Electroanal. Chem. 74, 125 (1976)

    Article  CAS  Google Scholar 

  51. G. Yellaiah, T. Shekharam, K. Hadasa, M. Nagabhushanam, J. Alloys Compd. 609, 192 (2014)

    Article  CAS  Google Scholar 

  52. D.C. Onwudiwe, T. Arfin, C.A. Strydom, Electrochim. Acta 116, 217 (2014)

    Article  CAS  Google Scholar 

  53. R. Gerhardt, J. Phys. Chem. Solids 55(12), 1491 (1994)

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Physics, International Research Centre (IRC), Kalasalingam University, Krishnankoil, Tamil Nadu, 626126, India

    A. Shameem, P. Devendran, V. Siva, K. S. Venkatesh, S. Asath Bahadur & N. Nallamuthu

  2. Department of Chemistry, Bharath Institute of Higher Education and Research, Bharath University, Chennai, Tamil Nadu, 600073, India

    A. Manikandan

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  1. A. Shameem
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  2. P. Devendran
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  3. V. Siva
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  4. K. S. Venkatesh
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  5. A. Manikandan
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  6. S. Asath Bahadur
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  7. N. Nallamuthu
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Correspondence to A. Manikandan, S. Asath Bahadur or N. Nallamuthu.

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Shameem, A., Devendran, P., Siva, V. et al. Dielectric Investigation of NaLiS Nanoparticles Loaded on Alginate Polymer Matrix Synthesized by Single Pot Microwave Irradiation. J Inorg Organomet Polym 28, 671–678 (2018). https://doi.org/10.1007/s10904-017-0710-x

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  • DOI: https://doi.org/10.1007/s10904-017-0710-x

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