Abstract
This paper aims to investigate the structural, optical, electronic and electrical properties of PVA/PVP blend and PVA/PVP blend doped with In2O3 and Cr2O3 nanoparticles to use it for various flexible electronics devices like solar cell, sensors diodes, electronics gates, transistors have low cost, high corrosion resistance, low energy gap, flexible, low weight, high optical and electrical conductivities. The results indicated that absorbance of PVA/PVP blend improved about 30% and 34 with the increase of In2O3 and Cr2O3 nanoparticles concentrations. The energy gap value of PVA/PVP blend was reduces from 2.8 eV of PVA/PVP to 1.2 eV and 1.77 eV as In2O3 and Cr2O3 nanoparticles concentrations increase. Doping PVA/PVP with In2O3 and Cr2O3 nanoparticles enhance the optical constants, electronics parameters and electrical conductivity. The obtained results showed that the doping PVA/PVP blend with In2O3 and Cr2O3 improved the structural, optical, electronic and electrical characteristics which make the (PVA/PVP/In2O3) and (PVA/PVP/Cr2O3) nanocomposites are promising materials for flexible optoelectronics fields in the development of electronics applications.
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References
H.-L. Tai, Y.-D. Jiang, G.-Z. Xie, Preparation of surfactants directed PANI/In2O3 nanocomposite thin films and Its NH3-sensing properties. J. Electron. Sci. Technol. 8(2), 154–159 (2010)
S.A. Nouh, M.H. Abdel-Kader, M.B. Mohamed, Structural and optical modifications in polyvinyl alcohol due to Cr2O3 nanoparticles additives concentration, and gamma irradiation. Adv. Polym. Technol. 3(1–5), 21614 (2017). https://doi.org/10.1002/adv.21614
A.-F. Mohammad, Basha, Magnetic and optical studies on polyvinylpyrrolidone thin films doped with rare earth metal salts. Polym. J. 42, 728–734 (2010). https://doi.org/10.1038/pj.2010.60
husseinjudran Naser, A. Kumar, Development of polymer matrix decorated In2O3 particles it’s electrical and optical. Int. J. Eng. Adv. Technol. 8(5), 1359–1375 (2019)
J.T. Anandhi, S.L. Rayer, T. Chithambarathanu, F.T.I.R. Synthesis, Studies, Optical properties of aluminium doped chromium oxide nanoparticles by microwave irradiation at different concentrations. Chem. Mater. Eng. 5(2), 43–54 (2017). https://doi.org/10.13189/cme.2017.050204
K.K. Singh, K.K. Senapati, C. Borgohain, K.C. Sarma, Newly developed Fe3O4–Cr2O3 magnetic nanocomposite for photocatalytic decomposition of 4-chlorophenol in water. J. Environ. Sci. 52, 333–340 (2017)
J. Selvi, V. Parthasarathy, S. Mahalakshmi, R. Anbarasan, M.O. Daramola, P. Senthil Kumar, Optical, electrical, mechanical, and thermal properties and non-isothermal decomposition behavior of poly(vinyl alcohol)–ZnO nanocomposites. Iran. Polym. J. (2020). https://doi.org/10.1007/s13726-020-00806-8
A. Hassen, S. El-Sayed, W.M. Morsi, A.M. El Sayed, Preparation, dielectric and optical properties of Cr2O3 /PVC nanocomposite films. J. Adv. Phys. 4(3), 571–584 (2014)
E.A. El-sayd, A.A. Ibrahiem, R.M. Ahmed, Effect of cobalt chloride on the optical properties of PVA/PEG blend. Arab J. Nucl. Sci. Appl. 52(1), 22–32 (2019)
C.S. Sathish Sugumaran, M. Bellan, Nadimuthu, Characterization of composite PVA–Al2O3 thin films prepared by dip coating method. Iran. Polym. J. 24, 63–74 (2015). https://doi.org/10.1007/s13726-014-0300-5
A. AbouElfadl, Structure, optical and thermal properties of gamma irradiated PVA/Cd0.9Mn0.1S nanocomposite films. Arab J. Nucl. Sci. Appl. 52(4), 145–158 (2019)
S.K. Shahenoor Basha, K. Vijay Kumar, G. Sunita Sundari, M.C. Rao, Structural and electrical properties of graphene oxide-doped PVA/PVP blend nanocomposite polymer films. Adv. Mater. Sci. Eng. 11, 4372365 (2018)
Y. Ahmed, A.-R. Yassin, E.M. Mohamed, M.A. Abdelrazek, M. Morsi, Amr, Abdelghany, Structural investigation and enhancement of optical, electrical and thermal properties of poly (vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate)/graphene oxide nanocomposites. J. Mater. Res. Technol. 8(1), 1111–1120 (2019). https://doi.org/10.1016/j.jmrt.2018.08.005
A. Hashim, I.R. Agool, K.J. Kadhim, Novel of (polymer blend-Fe3O4) magnetic nanocomposites: preparation and characterization for thermal energy storage and release, gamma ray shielding, antibacterial activity and humidity sensors applications. J. Mater. Sci. 29(12), 10369–10394 (2018). https://doi.org/10.1007/s10854-018-9095-z
A. Hashim, Q. Hadi, Structural, electrical and optical properties of (biopolymer blend/ titanium carbide) nanocomposites for low cost humidity sensors. J. Mater. Sci. 29, 11598–11604 (2018). https://doi.org/10.1007/s10854-018-9257-z
R.S. Al-Faleh, A.M. Zihlif, A study on optical absorption and constants of doped poly(ethyleneoxide. Physics B 406, 1919–1925 (2011)
A. Hashim, Q. Hadi, Synthesis of novel (polymer blend-ceramics) nanocomposites: structural, optical and electrical properties for humidity sensors. J. Inorg. Organomet. Polym Mater. 28(4), 1394–1401 (2018). https://doi.org/10.1007/s10904-018-0837-4
M. ElMetwally, A.M. Abdelrazek, I. Abdelghany, M.A. Shalabya, M. Badr, Structural, optical, morphological and thermal properties of PEO/PVP blend containing different concentrations of biosynthesized Au nanoparticles. J. Mater. Res. Technol. 7(4), 419–431 (2018)
S.Ak.il Dana, Structural and optical properties of TiO2 nanoparticles/PVA for different composites thin films. Int. J. Nanoelectron. Mater. 9, 17–36 (2016)
T.A. Taha, Optical properties of PVC/Al2O3 nanocomposite films. Polym. Bull. (2018). https://doi.org/10.1007/s00289-018-2417-8
A.O. Salohub, A.A. Voznyi, O.V. Klymov, N.V. Safryuk, D.I. Kurbatov, A.S. Opanasyuk, Determination of fundamental optical constants of Zn2SnO4 films. Semicond. Phys. Q. Electron. Optoelectron. 20(1), 79–84 (2017)
C.S. Karthik, L. Mallesha, M. Veeranna Santhosh, S. Nagashree, P. Mallu, Synthesis, characterization, antimicrobial activity, and optical properties of Schiff bases derived from 4-(Aminomethyl) piperidine. Indian J. Adv. Chem. Sci. S1, 206–212 (2016)
E.M. Abdelrazek, I.S. Elashmawi, A. El-khodary, A. Yassin, Structural, optical, thermal and electrical studies on PVA/PVP blends filled with lithium bromide. Curr. Appl. Phys. 10, 607–613 (2010). https://doi.org/10.1016/j.cap.2009.08.005
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Hashim, A. Enhanced Structural, Optical, and Electronic Properties of In2O3 and Cr2O3 Nanoparticles Doped Polymer Blend for Flexible Electronics and Potential Applications. J Inorg Organomet Polym 30, 3894–3906 (2020). https://doi.org/10.1007/s10904-020-01528-3
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DOI: https://doi.org/10.1007/s10904-020-01528-3