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Enhanced Structural, Optical, and Electronic Properties of In2O3 and Cr2O3 Nanoparticles Doped Polymer Blend for Flexible Electronics and Potential Applications

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Abstract

This paper aims to investigate the structural, optical, electronic and electrical properties of PVA/PVP blend and PVA/PVP blend doped with In2O3 and Cr2O3 nanoparticles to use it for various flexible electronics devices like solar cell, sensors diodes, electronics gates, transistors have low cost, high corrosion resistance, low energy gap, flexible, low weight, high optical and electrical conductivities. The results indicated that absorbance of PVA/PVP blend improved about 30% and 34 with the increase of In2O3 and Cr2O3 nanoparticles concentrations. The energy gap value of PVA/PVP blend was reduces from 2.8 eV of PVA/PVP to 1.2 eV and 1.77 eV as In2O3 and Cr2O3 nanoparticles concentrations increase. Doping PVA/PVP with In2O3 and Cr2O3 nanoparticles enhance the optical constants, electronics parameters and electrical conductivity. The obtained results showed that the doping PVA/PVP blend with In2O3 and Cr2O3 improved the structural, optical, electronic and electrical characteristics which make the (PVA/PVP/In2O3) and (PVA/PVP/Cr2O3) nanocomposites are promising materials for flexible optoelectronics fields in the development of electronics applications.

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References

  1. H.-L. Tai, Y.-D. Jiang, G.-Z. Xie, Preparation of surfactants directed PANI/In2O3 nanocomposite thin films and Its NH3-sensing properties. J. Electron. Sci. Technol. 8(2), 154–159 (2010)

    CAS  Google Scholar 

  2. S.A. Nouh, M.H. Abdel-Kader, M.B. Mohamed, Structural and optical modifications in polyvinyl alcohol due to Cr2O3 nanoparticles additives concentration, and gamma irradiation. Adv. Polym. Technol. 3(1–5), 21614 (2017). https://doi.org/10.1002/adv.21614

    Article  CAS  Google Scholar 

  3. A.-F. Mohammad, Basha, Magnetic and optical studies on polyvinylpyrrolidone thin films doped with rare earth metal salts. Polym. J. 42, 728–734 (2010). https://doi.org/10.1038/pj.2010.60

    Article  CAS  Google Scholar 

  4. husseinjudran Naser, A. Kumar, Development of polymer matrix decorated In2O3 particles it’s electrical and optical. Int. J. Eng. Adv. Technol. 8(5), 1359–1375 (2019)

    Google Scholar 

  5. J.T. Anandhi, S.L. Rayer, T. Chithambarathanu, F.T.I.R. Synthesis, Studies, Optical properties of aluminium doped chromium oxide nanoparticles by microwave irradiation at different concentrations. Chem. Mater. Eng. 5(2), 43–54 (2017). https://doi.org/10.13189/cme.2017.050204

    Article  CAS  Google Scholar 

  6. K.K. Singh, K.K. Senapati, C. Borgohain, K.C. Sarma, Newly developed Fe3O4–Cr2O3 magnetic nanocomposite for photocatalytic decomposition of 4-chlorophenol in water. J. Environ. Sci. 52, 333–340 (2017)

    Article  Google Scholar 

  7. J. Selvi, V. Parthasarathy, S. Mahalakshmi, R. Anbarasan, M.O. Daramola, P. Senthil Kumar, Optical, electrical, mechanical, and thermal properties and non-isothermal decomposition behavior of poly(vinyl alcohol)–ZnO nanocomposites. Iran. Polym. J. (2020). https://doi.org/10.1007/s13726-020-00806-8

    Article  Google Scholar 

  8. A. Hassen, S. El-Sayed, W.M. Morsi, A.M. El Sayed, Preparation, dielectric and optical properties of Cr2O3 /PVC nanocomposite films. J. Adv. Phys. 4(3), 571–584 (2014)

    Article  Google Scholar 

  9. E.A. El-sayd, A.A. Ibrahiem, R.M. Ahmed, Effect of cobalt chloride on the optical properties of PVA/PEG blend. Arab J. Nucl. Sci. Appl. 52(1), 22–32 (2019)

    Google Scholar 

  10. C.S. Sathish Sugumaran, M. Bellan, Nadimuthu, Characterization of composite PVA–Al2O3 thin films prepared by dip coating method. Iran. Polym. J. 24, 63–74 (2015). https://doi.org/10.1007/s13726-014-0300-5

    Article  CAS  Google Scholar 

  11. A. AbouElfadl, Structure, optical and thermal properties of gamma irradiated PVA/Cd0.9Mn0.1S nanocomposite films. Arab J. Nucl. Sci. Appl. 52(4), 145–158 (2019)

    Google Scholar 

  12. S.K. Shahenoor Basha, K. Vijay Kumar, G. Sunita Sundari, M.C. Rao, Structural and electrical properties of graphene oxide-doped PVA/PVP blend nanocomposite polymer films. Adv. Mater. Sci. Eng. 11, 4372365 (2018)

    Google Scholar 

  13. Y. Ahmed, A.-R. Yassin, E.M. Mohamed, M.A. Abdelrazek, M. Morsi, Amr, Abdelghany, Structural investigation and enhancement of optical, electrical and thermal properties of poly (vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate)/graphene oxide nanocomposites. J. Mater. Res. Technol. 8(1), 1111–1120 (2019). https://doi.org/10.1016/j.jmrt.2018.08.005

    Article  CAS  Google Scholar 

  14. A. Hashim, I.R. Agool, K.J. Kadhim, Novel of (polymer blend-Fe3O4) magnetic nanocomposites: preparation and characterization for thermal energy storage and release, gamma ray shielding, antibacterial activity and humidity sensors applications. J. Mater. Sci. 29(12), 10369–10394 (2018). https://doi.org/10.1007/s10854-018-9095-z

    Article  CAS  Google Scholar 

  15. A. Hashim, Q. Hadi, Structural, electrical and optical properties of (biopolymer blend/ titanium carbide) nanocomposites for low cost humidity sensors. J. Mater. Sci. 29, 11598–11604 (2018). https://doi.org/10.1007/s10854-018-9257-z

    Article  CAS  Google Scholar 

  16. R.S. Al-Faleh, A.M. Zihlif, A study on optical absorption and constants of doped poly(ethyleneoxide. Physics B 406, 1919–1925 (2011)

    Article  CAS  Google Scholar 

  17. A. Hashim, Q. Hadi, Synthesis of novel (polymer blend-ceramics) nanocomposites: structural, optical and electrical properties for humidity sensors. J. Inorg. Organomet. Polym Mater. 28(4), 1394–1401 (2018). https://doi.org/10.1007/s10904-018-0837-4

    Article  CAS  Google Scholar 

  18. M. ElMetwally, A.M. Abdelrazek, I. Abdelghany, M.A. Shalabya, M. Badr, Structural, optical, morphological and thermal properties of PEO/PVP blend containing different concentrations of biosynthesized Au nanoparticles. J. Mater. Res. Technol. 7(4), 419–431 (2018)

    Article  Google Scholar 

  19. S.Ak.il Dana, Structural and optical properties of TiO2 nanoparticles/PVA for different composites thin films. Int. J. Nanoelectron. Mater. 9, 17–36 (2016)

    Google Scholar 

  20. T.A. Taha, Optical properties of PVC/Al2O3 nanocomposite films. Polym. Bull. (2018). https://doi.org/10.1007/s00289-018-2417-8

    Article  Google Scholar 

  21. A.O. Salohub, A.A. Voznyi, O.V. Klymov, N.V. Safryuk, D.I. Kurbatov, A.S. Opanasyuk, Determination of fundamental optical constants of Zn2SnO4 films. Semicond. Phys. Q. Electron. Optoelectron. 20(1), 79–84 (2017)

    Article  CAS  Google Scholar 

  22. C.S. Karthik, L. Mallesha, M. Veeranna Santhosh, S. Nagashree, P. Mallu, Synthesis, characterization, antimicrobial activity, and optical properties of Schiff bases derived from 4-(Aminomethyl) piperidine. Indian J. Adv. Chem. Sci. S1, 206–212 (2016)

    Google Scholar 

  23. E.M. Abdelrazek, I.S. Elashmawi, A. El-khodary, A. Yassin, Structural, optical, thermal and electrical studies on PVA/PVP blends filled with lithium bromide. Curr. Appl. Phys. 10, 607–613 (2010). https://doi.org/10.1016/j.cap.2009.08.005

    Article  Google Scholar 

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Hashim, A. Enhanced Structural, Optical, and Electronic Properties of In2O3 and Cr2O3 Nanoparticles Doped Polymer Blend for Flexible Electronics and Potential Applications. J Inorg Organomet Polym 30, 3894–3906 (2020). https://doi.org/10.1007/s10904-020-01528-3

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  • DOI: https://doi.org/10.1007/s10904-020-01528-3

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