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A Magnetic, Core–Shell Structured, pH-Responsive Molecularly Imprinted Polymers for the Selective Detection of Sulfamethoxazole

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Abstract

A magnetic, core–shell structured pH-responsive molecularly imprinted polymer was prepared by surface imprinting technique and free radical polymerization for selective extraction of sulfamethoxazole. The imprinted polymer shell was prepared using 2-(Dimethylamino) ethyl methacrylate as pH-sensitive monomer, a certain amount of 4-vinylphenylbronic acid and methacrylic acid as common monomer to increase selectivity, sulfamethoxazole as template molecules. Excellent adsorption capacity (39.06 mg g−1) and selectivity (IF = 2.19) were achieved and the capture/release process can be regulated by pH value. In addition, it has been successfully applied to the detection of sulfamethoxazole in water samples and the recovery rate reached 96.2%. This study provides a new method and idea for the selective separation and detection of sulfamethoxazole in actual samples.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 21677064), Science and Technology Planning Social Development Project of Jiangsu Province (No. BE2018694), Science and Technology Planning Social Development Project of Zhenjiang City (No.SH2019013) and Jiangsu Collaborative Innovation Center of Technology and Material of Water Treatment.

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Authors and Affiliations

  1. School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang, 212013, China

    Weihong Huang, Haojie Si & Yujie Qing

  2. Zhenjiang Agricultural Products Quality Inspection and Testing Center, Zhenjiang, 212003, China

    Liming Zhang, Wenwen Zhang & Fei Song

  3. Zhenjiang Food and Drug Supervision and Inspection Center, Zhenjiang, 212004, China

    Xiaoni Ni

  4. School of Materials Science and Engineering, Jiangsu University, 301, Xuefu Road, Zhenjiang, 212013, Jiangsu Province, China

    Wenming Yang

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  1. Weihong Huang
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Huang, W., Si, H., Qing, Y. et al. A Magnetic, Core–Shell Structured, pH-Responsive Molecularly Imprinted Polymers for the Selective Detection of Sulfamethoxazole. J Inorg Organomet Polym 31, 2054–2062 (2021). https://doi.org/10.1007/s10904-021-01893-7

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