Abstract
The present article summarizes the development of poly(butylene adipate-co-terephthalate) (PBAT) and organically modified layered silicates nanocomposite using a co-rotating twin screw extruder having a blown film unit. Wide angle X-ray diffraction (WAXD) studies indicated an increase in d spacing of the nanoclays in the bio-nanocomposite hybrids revealing formation of intercalated morphology. Transmission Electron Microscopy (TEM) also confirmed presence of partially exfoliated clay galleries as well as layers of intercalated structures within the PBAT matrix in the nanocomposite. Mechanical tests showed that the nanocomposite hybrids prepared using B109 nanoclay exhibited higher tensile modulus. Functionalization of PBAT matrix upon grafting with maleic anhydride (MA) resulted in further improvement in mechanical properties. The existence of interfacial bonds in grafted bio-nanocomposite hybrids are substantiated using FTIR spectroscopy. Thermal properties of nanocomposite hybrids employing DSC, TGA also revealed improved Tg, Tc and thermal stability over the virgin polymer. Dynamic Mechanical Analysis (DMA) indicated an increase of storage modulus (E′) of PBAT biopolymer with incorporation of nanofiller. The biodegradability of PBAT bionanocomposite hybrids showed an increase in the rate of biodegradability with addition of Na+MMT due to hydrophilic nature of the nanoclay.
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Ray SS, Yamada K, Ogami A, Okamoto M, Ueda K (2003) Macromol R Commun 23:943
Pluta M, Galeski A, Alexandre M, Paul M, Dubois P (2002) J Appl Polym Sci 86:1497
Chang JH, An XU, Sur GS (2003) J Polym Sci Part B Polym Phy 41(1):94
Messermith PB, Giannelis EP (1995) J Polym Sci Part A Polym Chem 33:1047
Jimenez G, Ogata N, Kawai H, Ogihara T (1997) J Appl Polym Sci 64:2211
Pantoustier N, Lepoittevin B, Alexandre M, Kubeis D, Calberg C, Jerome R, Dubois P (2002) Polym Eng Sci 42:1928
Chen GX, Hao GJ, Guo TY, Song MD, Zhang BH (2002) J Mater Sci Lett 43:2495
Lee SR, Park HM, Lim H, Kang T, Li X, Cho WJ, Ha CS (2002) Polymer 43:2495
Ray SS, Okamoto K, Maiti P, Okamoto M (2002) J Nanosci Nanotechnol 2:1
Lim ST, Hyun YH, Choi HJ (2002) Chem Mater 14:1839
Alexander M, Dubois P (2000) Mater Sci Eng 28:1
Li X, Kang T, Cho WJ, Lee JK, Ha CS (2001) Macromol R Commun 22:1306
Fisher H (2003) Mater Sci Eng 23:763
Lai SM, Huang CK, Shen HF (2005) J Appl Polym Sci 97:257
Someya Y, Nakazato T, Teramoto N, Shibata M (2004) J Appl Polym Sci 91(3):1463
Di Y, Iannace S, Maio ED, Nicolais L (2003) J Polym Sci Part B Polym Phys 41(7):670
Jain H, Wang Q, Zeng J, Yan Q (2005) J Appl Polym Sci 97(6):2273
Ray SS, Okamoto M (2003) Macromolecules 36(7):2355
Averous L (2004) J Macromol Sci Part C Polym Rev 4(3):231
Someya Y, Kondo N, Shibata M (2007) J Appl Polym Sci 106(2):730
Rajkiran R, Tiwari M, Natarajan U (2007) J Appl Polym Sci 105(5):2433
Ray SS, Okamoto K, Okamoto M (2005) Macromol Mater Eng 290(8):759
Someya Y, Shibata M (2005) J Appl Polym Sci 95(2):386
Gunaratne LMWK, Shanks RA (2005) Eur Polym J 41(12):2980
Chen DZ, Tang CY, Chan KC (2007) Compos Sci Technol 67(7):1617
Hullihen K (2006) Ind Eng Chem Res 45(18):6095
Suprakas S, Kazunobu Y, Masami O (2002) Nano Lett 2(10):1093
Zhang X, Lin G, Abou-Hussein R, Hassan MK, Noda I, Mark JE (2007) Eur Polym J 43(8):3128
Mu TM, Wu CY (2006) Polym Degrad Stab 91(9):2198
Ray SS, Okamoto K, Okamoto M (2003) J Polym Sci Part B Polym Phys 41(24):3160
Inoue Y, Yoshie N (1992) Prog Polym Sci 17(4):571
Averous L, Chivrac F (2006) J Polym Environ 14(4):393
Raquez JM, Nabar Y, Dubois P, Narayan R (2008) Macromol Mater Eng 293(6):447
Ray SS, Okamoto M (2003) Macromol R Commun 24(14):815
Messermith PB, Giannelis EP (1995) J Polym Sci Part A Polym Chem 33(7):1047
Chen GX, Hao GJ, Guo TY (2004) J Appl Polym Sci 93(2):655
Muller R, Deckwer W (1997) J Environ Polym Degrad 5(2):81
Witt U, Einig T, Yamamoto M (2001) Chemosphere 44(2):289
Wang YW, Weike M, Huilan Y (2004) Polym Degrad Stab 85(2):815
Annual Book of ASTM Standards, Standard Specification for Compostable Plastics 8(3):960
Annual Book of ASTM Standards, Standard test method for determining Anerobic Biodegradation in soil of Plastic 8(3):760
Annual Book of ASTM Standards, Standard test method for determining Aerobic Biodegradation in soil of Plastic 8(3):472
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Mohanty, S., Nayak, S.K. Biodegradable Nanocomposites of Poly(butylene adipate-co-terephthalate) (PBAT) and Organically Modified Layered Silicates. J Polym Environ 20, 195–207 (2012). https://doi.org/10.1007/s10924-011-0408-z
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DOI: https://doi.org/10.1007/s10924-011-0408-z