Skip to main content

Advertisement

SpringerLink
Log in

Preparation and Performance of Bio-Based Polyol Ester from One-Pot Synthesis of Castor Oil as Nontoxic Poly(Vinyl Chloride) Plasticizer

  • Original Paper
  • Published:
Journal of Polymers and the Environment Aims and scope Submit manuscript

Abstract

Dioctyl phthalate (DEHP), as the most used commercial plasticizer, has been restricted in many polymer products due to its reproductive toxicity to human body. In this study, castor oil based polyol ester(CPE) was synthesized via a simple and efficient way and used as a sustainable plasticizer in poly(vinyl chloride) (PVC) films to replace toxic DEHP. The chemical structure of the obtained bio-based plasticizer was characterized. The oral toxicity test indicated that CPE had toxic doses of over 3000 mg/kg. Tg of PVC films decreased from 87.4 to 19.1 °C, which is lower than PVC-DEHP systems. The tensile strength and elongation at break of PVC films plasticized with 50 phr CPE is 12.10 MPa and 450.15% respectively, which shows more flexible than PVC/50 prh DEHP samples.The DMA and tensile tests results indicated that the plasctizing effect of CPE was more excellent than DEHP. DEHP can be completely replaced with CPE in flexible PVC products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Brostow W, Lu X, Osmanson AT (2018) Polym Test 69:63

    Article  CAS  Google Scholar 

  2. Kumar S (2019) Ind Eng Chem Res 58:11659

    Article  CAS  Google Scholar 

  3. Gama N, Santos R, Godinho B, Silva R, Ferreira A (2019) J Polym Environ 27:1294

    Article  CAS  Google Scholar 

  4. Wang R, Wang Q, Ma C, Li S, Han R (2018) Chemosphere 211:861

    Article  CAS  Google Scholar 

  5. Zheng T et al (2018) J Clean Prod 186:1021

    Article  CAS  Google Scholar 

  6. Kashyap D, Agarwal T (2018) Sci Total Environ 635:817

    Article  CAS  Google Scholar 

  7. Brown R, Russell S, May S, Regan F, Chapman J (2017) Adv Eng Mater 19:1700053

    Article  Google Scholar 

  8. Ma YF, Lao SL, Li QG, Guan Q, Jia PY, Zhou YH (2020) React Funct Polym 147:104458

    Article  CAS  Google Scholar 

  9. Lee KW, Chung JW, Kwak SY (2016) Macromol Rapid Commun 37:2045

    Article  CAS  Google Scholar 

  10. Jia P, Hu L, Shang Q, Wang R, Zhang M, Zhou Y (2017) ACS Sustain Chem Eng 5:6665

    Article  CAS  Google Scholar 

  11. Ferri JM, Garcia-Garcia D, Montanes N, Fenollar O, Balart R (2017) Polym Int 66:882

    Article  CAS  Google Scholar 

  12. Suzuki AH, Botelho BG, Oliveira LS, Franca AS (2018) Eur Polym J 99:142

    Article  CAS  Google Scholar 

  13. Briou B, Caillol S, Robin J-J, Lapinte V (2019) Ind Crops Prod 130:1

    Article  CAS  Google Scholar 

  14. Sahoo SK, Khandelwal V, Manik G (2019) Int J Adhes Adhes 89:174

    Article  CAS  Google Scholar 

  15. Sahoo SK, Khandelwal V, Manik G (2018) Ind Eng Chem Res 57:11323

    Article  CAS  Google Scholar 

  16. Jia P, Ma Y, Zhang M, Hu L, Zhou Y (2019) ACS Omega 4:3178

    Article  CAS  Google Scholar 

  17. Zhang G, Li J, Sun S, Luo Y (2019) Propellants Explos Pyrotech 44:345

    Article  CAS  Google Scholar 

  18. Li W, Qin J, Wang S, Han D, Xiao M, Meng Y (2018) ACS Sustain Chem Eng 6:8476

    Article  CAS  Google Scholar 

  19. Tsui OK, Zhang H (2001) Macromolecules 34:9139

    Article  CAS  Google Scholar 

  20. Kierkels J, Dona CL, Tervoort T, Govaert L (2008) J Polym Sci B 46:134

    Article  CAS  Google Scholar 

  21. Jia P, Zheng M, Ma Y, Feng G, Xia H, Hu L, Zhang M, Zhou Y (2019) J Clean Prod 206:838

    Article  CAS  Google Scholar 

  22. Li L, Tek AT, Wojtecki RJ, Braslau R (2019) J Polym Sci A 57:1821

    Article  CAS  Google Scholar 

  23. Chu H, Ma J (2018) Korean J Chem Eng 35:2296

    Article  CAS  Google Scholar 

  24. Jia P, Ma Y, Feng G, Hu L, Zhou Y (2019) J Clean Prod 227:662

    Article  CAS  Google Scholar 

  25. Jia P, Ma Y, Song F, Hu L, Zhang C, Zhou Y (2019) React Funct Polym 144:104363

    Article  Google Scholar 

  26. Jia P, Hu L, Feng G, Bo C, Zhou J, Zhang M, Zhou Y (2017) RSC Adv 7:897

    Article  CAS  Google Scholar 

  27. Liang H, Liu L, Lu J, Chen M, Zhang C (2018) Ind Crops Prod 117:169

    Article  CAS  Google Scholar 

  28. Feng Y, Man L, Hu Y, Chen L, Xie B, Zhang C, Yuan T, Yang Z (2019) Prog Org Coat 132:62

    Article  CAS  Google Scholar 

  29. Jia P, Zhang M, Hu L, Bo C, Zhou Y-H (2015) J Therm Anal Calorim 120:1731

    Article  CAS  Google Scholar 

  30. Endo K (2002) Prog Polym Sci 27:2021

    Article  CAS  Google Scholar 

  31. Percec V, Asgarzadeh F (2001) J Polym Sci A 39:1120

    Article  CAS  Google Scholar 

  32. Starnes WH Jr (2005) J Polym Sci A 43:2451

    Article  CAS  Google Scholar 

  33. Qi Y, Wu W, Han L, Qu H, Han X, Wang A, Xu J (2016) J Therm Anal Calorim 123:1263

    Article  CAS  Google Scholar 

  34. Zhang J, Wang L, Fan M, Hui X, Wei L, Wang S (2017) IOP Conf Ser Mater Sci Eng 199:012071

  35. Huang Y, Yu E, Li Y, Wei Z (2018) J Appl Polym Sci 135:46542

    Article  Google Scholar 

  36. Li Y, Yu E, Yang X, Wei Z (2020) J Vinyl Add Tech 26:35

    Article  CAS  Google Scholar 

  37. Feldmann M, Fuchs J (2016) Specialized injection molding techniques. Elsevier, Amsterdam, p 211

    Book  Google Scholar 

  38. Daniels PH (2010) J Vinyl Add Tech 15:219

    Article  Google Scholar 

  39. Bocqué M, Voirin C, Lapinte V, Caillol S, Robin JJ (2016) J Polym Sci A 54:11

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, People’s Republic of China

    Yufeng Ma & Qinying Kong

  2. Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry(CAF), Nanjing, 210042, People’s Republic of China

    Fei Song, Puyou Jia & Yonghong Zhou

  3. School of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou, 510225, People’s Republic of China

    Qiaoguang Li

Authors
  1. Yufeng Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Fei Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Qinying Kong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qiaoguang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Puyou Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yonghong Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Puyou Jia.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ma, Y., Song, F., Kong, Q. et al. Preparation and Performance of Bio-Based Polyol Ester from One-Pot Synthesis of Castor Oil as Nontoxic Poly(Vinyl Chloride) Plasticizer. J Polym Environ 28, 2101–2107 (2020). https://doi.org/10.1007/s10924-020-01754-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10924-020-01754-3

Keywords

Search

Navigation