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Recycling of waste glasses into partially crystallized glass foams

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Abstract

Waste soda-lime glass, alone or mixed with wastes from the manufacturing of glass fibers, was successfully converted into partially crystallized glass foams by a particularly simple and economic processing, consisting of a direct heating of glass powders at temperatures from 900 to 1050 °C. The foaming operated by the oxidation of SiC, inserted as powder additive, was found to depend on a complex combination of processing temperature, soaking time, tendency of the investigated glasses toward devitrification, and amount of MnO2, acting as oxidation promoter. Selected combinations led to foams with a good microstructural homogeneity and mechanical strength, suitable for application as aggregates in lightweight concrete.

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References

  1. A. Mueller, S.N. Sokolova, V.I. Vereshagin, Construct. Build. Mater. 22, 703 (2008). doi:10.1016/j.conbuildmat.2007.06.009

    Article  Google Scholar 

  2. G. Scarinci, G. Brusatin, E. Bernardo, in Cellular ceramics, structure, manufacturing, properties and applications, ed. by M. Scheffler, P. Colombo (Wiley-VCH, Weinheim, 2005), pp. 158–176

    Google Scholar 

  3. P. Colombo, G. Brusatin, E. Bernardo, G. Scarinci, Curr. Opin. Solid. State. Mater. Sci. 7, 225 (2003). doi:10.1016/j.cossms.2003.08.002

    Article  CAS  Google Scholar 

  4. E. Bernardo, G. Scarinci, S. Hreglich, Glass Sci. Technol. 78, 7 (2005)

    CAS  Google Scholar 

  5. W.O. Lytle, U.S. Patent 2,215,223, 1940

  6. B.K. Demidovich, Production and application of glass foam (Nauka i Tekhnika, Minsk, 1972)

    Google Scholar 

  7. E.H. Haux, U.S. Patent 2,191,658, 1940

  8. W.D. Ford, U.S. Patent 2,691,248, 1954

  9. J. Hurley, Glass research and development final report: a UK market survey for foam glass. (WRAP, The Waste and Resources Action Programme, 2003), http://www.wrap.org.uk/downloads/AUKMarketSurveyForFoamGlass.ed91e9c7.358.pdf, Accessed 8 Jan 2009

  10. E. Bernardo, R. Cedro, M. Florean, S. Hreglich, Ceram. Int. 33, 963 (2007). doi:10.1016/j.ceramint.2006.02.010

    Article  CAS  Google Scholar 

  11. http://www.sasil-life.com/pagine_UK/default_uk.html, Accessed 12 March 2009

  12. http://www.enco.ch/glass.htm, Accessed 8 January 2009

  13. A. Saburit Llaudis, M.J. Orts Tari, F.J. García Ten, E. Bernardo, P. Colombo, Ceram. Int. (2008). doi:10.1016/j.ceramint.2008.10.022

  14. J.E. Post, Proc. Natl. Acad. Sci. USA 96, 3447 (1999). doi:10.1073/pnas.96.7.3447

    Article  CAS  Google Scholar 

  15. K.L. Berg, S.E. Olsen, Metall. Mater. Trans. 31B, 477 (2000)

    CAS  Google Scholar 

  16. G. Brusatin, G. Scarinci, L. Zampieri, P. Colombo, in Proceedings of the XIXth International Congress on Glass—ICG XIX, vol. 2 (Society of Glass Technology, Edinburgh, 2001), pp. 17–18

  17. D.U. Tulyaganov, H.R. Fernandes, S. Agathopoulos, J.M.F. Ferreira, J. Porous. Mater. 13, 133 (2006)

    Article  CAS  Google Scholar 

  18. H. Hojaji, Mater. Res. Soc. Proc. 136, 185 (1989)

    Google Scholar 

  19. A.A. Ketov, in Proceedings of the International Symposium on Recycling and Reuse of Glass Cullet, ed. by R.K. Dhir et al. (Thomas Telford Books, Dundee, 2001), pp. 84–91

  20. E. Bernardo, F. Albertini, Ceram. Int. 32, 603 (2006). doi:10.1016/j.ceramint.2005.04.019

    Article  CAS  Google Scholar 

  21. Ducman V, Kovačević M (1997). Key Eng. Mater. 132–136:2264. doi:10.4028/www.scientific.net/KEM.132-136.2264

  22. L.J. Gibson, M.F. Ashby, Cellular solids, structure and properties (Cambridge University Press, Cambridge, 1999), pp. 175–231

    Google Scholar 

  23. E. Bernardo, P. Colombo, in Ceramic science and technology, ed. by R. Riedel, I.-W. Chen, vol. 1 (Wiley-VCH, Weinheim, 2008), pp. 407–442

  24. E. Bernardo, J. Eur. Ceram. Soc. 27, 2415 (2007). doi:10.1016/j.jeurceramsoc.2006.10.003

    Article  CAS  Google Scholar 

  25. W. Höland, G.G. Beall, Glass–ceramic technology (The American Ceramic Society, Westerville, 2002), pp. 110–119

    Google Scholar 

  26. http://webmineral.com/data/Bustamite.shtml, Accessed 17 March 2009

  27. S. Fotiadou, M.C. Limbachiya, A.N. Fried, J.J. Roberts, in Sustainable waste management and recycling of glass waste, ed. by M.C. Limbachiya, J. Roberts (Thomas Telford Ltd, London, 2004), pp. 305–312

    Google Scholar 

  28. M.J.M. Moons, K. Van Breugel, in Sustainable waste management and recycling of glass waste, ed. by M.C. Limbachiya, J. Roberts (Thomas Telford Ltd, London, 2004), pp. 197–204

    Google Scholar 

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Correspondence to Enrico Bernardo.

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Bernardo, E., Scarinci, G., Bertuzzi, P. et al. Recycling of waste glasses into partially crystallized glass foams. J Porous Mater 17, 359–365 (2010). https://doi.org/10.1007/s10934-009-9286-3

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  • DOI: https://doi.org/10.1007/s10934-009-9286-3

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