Skip to main content
SpringerLink
Log in

Toluene hydrogenation over nickel-containing MCM-41 and Ti-MCM-41 materials

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

Nickel-containing MCM-41 and Ti-MCM-41 mesoporous materials with different amounts of nickel were prepared by one-pot, sol–gel synthesis. The properties of the nickel catalysts were studied by means of X-ray diffraction (XRD), N2 physisorption, UV-Vis spectroscopy and temperature programmed reduction (TPR) methods. The catalysts have been tested in the gas phase hydrogenation of toluene. The formation of various nickel species due to the different metal-support interaction was assumed for both of the supports. Strong metal–support interaction was supposed when Ti-MCM-41 was used as a support. It has been shown that the reducibility and the catalytic activity of the catalysts is strongly influenced by the host.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. A. Taguchi, F. Schüth, Micropor. Mesopor. Mater. 77, 1 (2005)

    Article  CAS  Google Scholar 

  2. Y. Park, T. Kang, J. Lee, P. Kim, H. Kim, J. Yi, Catal. Today 97, 195 (2004)

    Article  CAS  Google Scholar 

  3. V. Parvulescu, B.-L. Su, Catal. Today 69, 315 (2001)

    Article  CAS  Google Scholar 

  4. A. Stanislaus, B.H. Cooper, Catal. Rev. Sci. Eng. 36, 75 (1994)

    Article  CAS  Google Scholar 

  5. B.H. Cooper, B.B.L. Donnis, Appl. Catal., A: Gen. 137, 203 (1996)

    Article  CAS  Google Scholar 

  6. R. Wojcieszak, S. Monteverdi, J. Ghanbaja, M.M. Bettahar, J. Coll. Interf. Sci. 317, 166 (2008)

    Article  CAS  Google Scholar 

  7. R. Molina, G. Poncelet, J. Catal. 199, 162 (2001)

    Article  CAS  Google Scholar 

  8. A.G. Boudjahem, S. Monteverdi, M. Mercy, M.M. Betthar, J. Catal. 221, 325 (2004)

    Article  CAS  Google Scholar 

  9. T. Jiang, Q. Zhao, H. Yin, M. Li, J. Porous. Mater. 14, 457 (2007)

    Article  CAS  Google Scholar 

  10. A. Jasik, R. Wojcieszak, S. Monteverdi, M. Ziolek, M.M. Bettahar, J. Mol. Catal. 242, 81 (2005)

    Article  CAS  Google Scholar 

  11. R. Wojcieszak, S. Monteverdi, M. Mercy, I. Nowak, M. Ziolek, M.M. Bettahar, Appl. Catal. 268, 241 (2004)

    Article  CAS  Google Scholar 

  12. V. Mavrodinova, M. Popova, M. Linden, Ch. Minchev, J. Porous. Mater. 14, 213 (2007)

    Article  CAS  Google Scholar 

  13. A. Lewandovska, S. Monteverdi, M.M. Bettahar, M. Ziolek, J. Mol. Catal. 188, 85 (2002)

    Article  Google Scholar 

  14. D.J. Lensveld, J. Gerbrand Mesu, A. Jos van Dillen, D.J. Lensveld, K.P. de Jong, Micropor. Mesopor. Mater. 44–45, 401 (2001)

    Article  Google Scholar 

  15. E. Minor-Perez, R. Mendoza-Serna, J. Mendez-Vivar, R.C. Pless, D. Quintana-Zavala, R. Torres-Robles, J. Porous. Mater. 13, 13 (2006)

    Article  CAS  Google Scholar 

  16. Y.H. Choi, W.Y. Lee, Catal. Lett. 67, 155 (2000)

    Article  CAS  Google Scholar 

  17. T. Linssen, K. Cassiers, P. Cool, E.F. Vansant, Adv. Colloid Interface Sci. 103, 121 (2003)

    Article  CAS  Google Scholar 

  18. J.F. Bengoa, M.V. Cagnoli, N.G. Gallegos, A.M. Alvarez, L.V. Mogni, M.S. Moreno, S.G. Marchetti, Micropor. Mesopor. Mater. 84, 153 (2005)

    Article  CAS  Google Scholar 

  19. Y. Yang, S. Lim, G. Du, Y. Chen, D. Ciuparu, G.L. Haller, J. Phys. Chem. B 109, 13237 (2005)

    Article  CAS  Google Scholar 

  20. Y.S. Cho, J.C. Park, B. Lee, Y. Kim, J. Yi, Catal. Lett. 81, 1–2–1–89 (2002)

    Article  Google Scholar 

  21. K. Fang, W. Wei, J. Ren, Y. Sun, Catal. Lett. 93, 3–4–3–235 (2004)

    Article  Google Scholar 

  22. R.B. Biniwale, N. Kariya, M. Ichikawa, Catal. Lett. 105, 1–2–1–83 (2005)

    Article  Google Scholar 

  23. M. Grün, K.K. Unger, A. Matsumoto, K. Tsutsumi, Micropor. Mesopor. Mater. 27, 206 (1999)

    Article  Google Scholar 

  24. C. Galacho, M.M.L.R. Carrott, P.J.M. Carrott, Micropor. Mesopor. Mater. 100, 1–3–1–312 (2007)

    Article  Google Scholar 

  25. M.M.L.R. Carrott, C. Galacho, F.L. Conceicao, P.J.M. Carrott, Stud. Surf. Sci. Catal. 160, 567 (2007)

    Article  CAS  Google Scholar 

  26. X. Li, B. Li, H. Mao, A.T. Shah, J. Coll. Interf. Sci. 332, 444 (2009)

    Article  CAS  Google Scholar 

  27. A. Szegedi, M. Popova, V. Mavrodinova, M. Urban, I. Kiricsi, Ch. Minchev, Micropor. Mesopor. Mater. 99, 149 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Support of this work in the frame of the Hungarian-Bulgarian Inter-Academic Exchange Agreement is greatly acknowledged.

Author information

Authors and Affiliations

  1. Institute of Nanochemistry and Catalysis, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, 1025, Budapest, Hungary

    Ágnes Szegedi

  2. Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria

    Margarita Popova

Authors
  1. Ágnes Szegedi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Margarita Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ágnes Szegedi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Szegedi, Á., Popova, M. Toluene hydrogenation over nickel-containing MCM-41 and Ti-MCM-41 materials. J Porous Mater 17, 663–668 (2010). https://doi.org/10.1007/s10934-009-9336-x

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-009-9336-x

Keywords

Search

Navigation