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High activity Fe-MIL-101 solid acid catalyst for acetalization of aldehydes with methanol and enamination of β-dicarbonyl compounds

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Abstract

Catalytic activity Fe-MIL-101 as a reusable solid acid catalyst for acetalization of aldehydes with methanol and enamination of β-dicarbonyl compounds was explored. The recovered Fe-MIL-101 could be reused over ten cycles without any loss of activity. The novel solid acid catalyst has great potential for green chemical application.

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Acknowledgments

The work was supported by the Co-building Special Project of Beijing Municipal Education and the National High Technology Research and Development Program of China (No. 2013AA031702). We also thank the Fundamental Research Funds for the Central Universities (FRF-TP-14-061A1) for financial support.

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Authors and Affiliations

  1. Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing, 100083, People’s Republic of China

    Li Tan

  2. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, People’s Republic of China

    Ming Yang, Jia Tang, Qianqian Ma & Nannan Zheng

Authors
  1. Ming Yang
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  2. Jia Tang
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  3. Qianqian Ma
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  4. Nannan Zheng
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  5. Li Tan
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Correspondence to Li Tan.

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Yang, M., Tang, J., Ma, Q. et al. High activity Fe-MIL-101 solid acid catalyst for acetalization of aldehydes with methanol and enamination of β-dicarbonyl compounds. J Porous Mater 22, 1345–1350 (2015). https://doi.org/10.1007/s10934-015-0011-0

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  • DOI: https://doi.org/10.1007/s10934-015-0011-0

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