Abstract
Adsorption is an effective treatment process for removing phosphorus and thus controlling eutrophication. In this study, a clay composite material called Al–dolomite–montmorillonite (Al–DM) was prepared and characterized. Al–DM performed well with respect to phosphate removal, with its performance depending on the Al–DM loading, contact time, initial phosphorus concentration and initial solution pH. Adsorption mechanisms were investigated by conducting batch tests on phosphate adsorption using the Al–DM. The adsorption process fitted both the pseudo-second-order kinetics model and the intra-particle diffusion model. The Langmuir, Freundlich and BET models all adequately described the adsorption isotherm data. Thermodynamic studies showed that the adsorption process was endothermic and spontaneous in nature. Al–DM is an effective adsorbent for phosphate removal mainly due to its hierarchical porous structures as shown by characterization with SEM and EDS. Chemical changes occurring before and after adsorption in a water environment indicated that Al–DM had little negative effect on water quality.
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Lau, S.S.S., Lane, S.N.: Biological and chemical factors influencing shallow lake eutrophication: S long-term study. Sci. Total Environ. 288, 167–181 (2002)
Heisler, J., Glibert, P.M., Burkholder, J.M., Anderson, D.M., Cochlan, W., Dennison, W.C.: Eutrophication and harmful algal blooms: a scientific consensus. Harmful Algae 8, 3–13 (2008)
Tingxi, Z., Xiaorong, W., Xiangcan, J.: Variations of alkaline phosphatase activity and P fractions in sediments of a shallow Chinese eutrophic lake (Lake Taihu). Environ. Pollut. 150, 288–294 (2007)
Yeoman, S., Stephanson, T., Lester, J.N.: The removal of phosphorus during wastewater treatment: a review. Environ. Pollut. 49, 183–233 (1988)
Tchobanoglous, G.: Wastewater Engineering: Treatment, Disposal and Reuse. McGraw Hill, New York (1991)
De-Bashana, L.E., Bashan, Y.: Recent advances in removing phosphorus from wastewater and its future use as fertilizer (1997–2003). Water Res. 38, 4222–4246 (2004)
Sibrell, L.P., Montgomery, G.A., Ritenour, K.L., Tucker, T.W.: Removal of phosphorus from agriculture wastewater using adsorption media prepared from acid drainage sludge. Water Res. 43, 2240–2250 (2009)
Kostura, B., Kulveitova, H., Lesko, J.: Blast furnace slags as sorbent of phosphate from water solutions. Water Res. 39, 1795–1802 (2005)
Yang, Y., Zhao, Y.Q., Kearney, P.: Influence of ageing on the structure and phosphate adsorption capacity of dewatered alum sludge. Chem. Eng. J. 145, 276–284 (2008)
Chen, J., Kong, H., Wu, D., Chen, X., Zhang, D., Sun, Z.: Phosphate immobilization from aqueous solution by fly ashes in relation to their composition. J. Hazard. Mater. 139, 293–300 (2007)
Wu, D., Zhang, B., Li, C., Zhang, Z., Kong, H.: Simultaneous removal of ammonium and phosphate by zeolite synthesized from fly ash as influenced by salt treatment. J. Colloid Interface Sci. 304, 300–306 (2006)
Ferro-Garca, M.A., Carrasco-Marm, F., Rivera-Utrilla, J., Utrera-Hidalgo, E., Moreno-Castilla, C.: The use of activated carbon columns for the removal orthophosphate ions from aqueous solutions. Carbon 28, 91–95 (1990)
Oguz, E.: Removal of phosphate from aqueous solution with blast furnace slag. J. Hazard. Mater. 114, 131–137 (2004)
Xue, Y.J., Hou, H.B., Zhu, S.J.: Characteristics and mechanisms of phosphate adsorption onto basic oxygen furnace slag. J. Hazard. Mater. 162, 973–980 (2009)
Drizo, A., Forget, C., Chapuis, R.P., Comeau, Y.: Phosphorus removal by electric arc furnace steel slag and serpentinite. Water Res. 40, 1547–1554 (2006)
Gimsing, A.L., Szilas, C., Borggaard, O.K.: Sorption of glyphosate and phosphate by variable-charge tropical soils from Tanzania. Geoderma 138, 127–132 (2007)
Li, Y.Z., Liu, C.J., Luan, Z.K., Peng, X.J., Zhu, C.L., Chen, Z.Y., Zhang, Z.G., Fan, J.H., Jia, Z.P.: Phosphate removal from aqueous solutions using raw and activated red mud and fly ash. J. Hazard. Mater. 137, 374–383 (2006)
Moon, Y.H., Kim, J.G., Ahn, J.S., Lee, G.H., Moon, H.S.: Phosphate removal using sludge from fuller’s earth production. J. Hazard. Mater. 143, 41–48 (2007)
Karaca, S., Gürses, A., Ejder, M., Açıkyıldız, M.: Adsorptive removal of phosphate from aqueous solutions using raw and calcinated dolomite. J. Hazard. Mater. 128, 273–279 (2006)
Roques, H., Nufroho-Jeudy, L., Lebugle, A.: Phosphorus removal from wastewater by half-burned dolomite. Water Res. 25, 959–965 (1991)
Karaca, S., Gürses, A., Ejder, M., Açıkyıldız, M.: Kinetic modeling of liquid-phase adsorption of phosphate on dolomite. J. Colloid Interface Sci. 277, 257–263 (2004)
EPA: Water and Wastewater Monitoring Analysis Method, 4th edn, pp. 246–248. China Environmental Science, Beijing (2002)
Chen, N., Zhang, Z.Y., Feng, C.P., Li, M., Zhu, D.R., Chen, R.Z.: An excellent fluoride sorption behavior of ceramic adsorbent. J. Hazard. Mater. 183, 460–465 (2010)
Zhang, J.D., Shen, Z.M., Shan, W.P., Wang, W.H.: Adsorption behavior of phosphate on lanthanum(III)-coordinated diamino-functionalized 3D hybrid mesoporous silicates material. J. Hazard. Mater. 186, 76–83 (2011)
Ning, P., Bark, H.J., Li, B., Lu, X., Zhang, Y.: Phosphate removal from wastewater by model-La(III) zeolite adsorbents. J. Environ. Sci. 20, 670–674 (2008)
Li, K.Q., Li, Y., Zheng, Z.: Kinetics and mechanism studies of p-nitroaniline adsorption on activated carbon fibers prepared from cotton stalk by NH4H2PO4 activation and subsequent gasification with steam. J. Hazard. Mater. 178, 553–559 (2010)
Rodrigues, L.A., Pinto da Silva, M.L.C.: Thermodynamic and kinetic investigations of phosphate adsorption onto hydrous niobium oxide prepared by homogeneous solution method. Desalination 263, 29–35 (2010)
Zhang, J.D., Shen, Z.M., Shan, W.P., Chen, Z.Y., Mei, Z.J., Lei, Y.M., Wang, W.H.: Adsorption behavior of phosphate on lanthanum(III) doped mesoporous silicates material. J. Environ. Sci. (China) 22, 507–511 (2010)
Weber, W.J., Morris, J.C.: Proceedings of the International Conference on Water Pollution Symposium. Vol. 2, pp. 231–266. Pergamon, Oxford (1962)
Langmuir, I.: The constitution and fundamental properties of solids and liquids. J. Am. Chem. Soc. 38, 2221–2295 (1916)
Lyubchik, S.I., Lyubchik, A.I., Galushko, O.L., Tikhonova, L.P., Vital, J., Fonsca, I.M., Lyubchik, S.B.: Kinetics and thermodynamics of Cr(III) adsorption on the activated carbon from co-mingled wastes. Colloids Surf. A 242, 151–158 (2004)
Masue, Y., Loeppert, R.H., Kramer, T.A.: Arsenate-arsenite adsorption and desorption behavior on coprecipitated aluminum: iron hydroxides. Environ. Sci. Tech. 41, 837–842 (2007)
World Health Organization: Guidelines for drinking-water quality, vol. 1, 3rd edn. World Health Organization, Geneva (2004)
Xue, Y.J., Hou, H.B., Zhu, S.J.: Characteristics and mechanisms of phosphate adsorption onto basic oxygen furnace slag. J. Hazard. Mater. 162, 973–980 (2009)
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The authors thank the Fundamental Research Funds for the Central Universities, Water Pollution Control and Treatment Key Projects (2009ZX07 102-002-01), and National Natural Science Foundation (No. 31140082) for financial support of this work.
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Gao, Y., Chen, N., Hu, W. et al. Phosphate Removal from Aqueous Solution by an Effective Clay Composite Material. J Solution Chem 42, 691–704 (2013). https://doi.org/10.1007/s10953-013-9985-x
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DOI: https://doi.org/10.1007/s10953-013-9985-x