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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 4/2014

01.04.2014 | Original Paper

Hybrid carbon nanotube—silica/ polyvinyl alcohol nanocomposites films: preparation and characterisation

verfasst von: Bessem Ben Doudou, Alexandre Vivet, Jun Chen, Abdelghani Laachachi, Thierry Falher, Christophe Poilâne

Erschienen in: Journal of Polymer Research | Ausgabe 4/2014

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Abstract

Composites of carbon nanotubes (CNT) in polymeric matrices have attracted considerable attention in the research and industrial communities due to their interesting and unique properties. However, the main intrinsic problem of CNT is their insolubility or very poor solubility in either water or organic solvents. Therefore, the dispersion of CNT has become the focus of many researches. In this study, a simple method based on a chemical process was developed in order to improve the dispersion of CNT. Our method consists in grafting carboxylic acid-functionalized carbon nanotubes (CNT-COOH) onto an amino-functionalized silica particles (SiO2-NH2) surface. Prior to assembly, CNT-COOH were prepared by using a mixture of concentrated nitric and sulfuric acids, while SiO2-NH2 were prepared by a silanization with 3-aminopropyltriethoxysilane (APTES). The hybrid carbon nanotube-silica (CNT/SiO2) was dispersed in polyvinyl alcohol (PVA) with 1, 3 and 5 wt% (by weight). Techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM) and differential scanning calorimetry (DSC) measurement have been employed to study the dispersion state in the polymer matrix. The results indicated a good and uniform dispersion of hybrid fillers. Indeed, it was shown that the silica particles play the role of dispersing agents. In addition, a decrease of the resistivity of the composite films was observed as the concentration of CNT-silica fillers in the PVA increases, reaching 3.4 × 103 Ω.m when the hybrid fillers concentration is equal to 5 %.
Vorheriger Artikel Graphting polyimide to MWCNT for enhancing dispersion and properties of MWCNT/polyetherimide nanocomposites
Nächster Artikel Preparation and behavior of “molecular compound” through covalent crosslinking between amino and sulfonic groups in single copolymers

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Literatur
1.
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef
2.
Godara A, Vaugien T (2009) Carbon nanotubes in polymer matrix composite structures. JEC Compos 48:64–68
3.
Thess A, Lee R, Nikolaev P, Dai HJ, Petit P, Robert J, Xu CH, Lee YH, Kim SG, Rinzler AG, Colbert DT, Scuseria GE, Tomanek D, Fischer JE, Smalley RE (1996) Crystalline ropes of metallic carbon nanotubes. Science 273:483–487CrossRef
4.
Sandler JKW, Kirk JE, Kinloch IA, Shaffer MSP, Windle AH (2003) Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites. Polymer 44:5893–5899CrossRef
5.
Ryan KP, Cadek M, Nicolosi V, Blond D, Ruether M, Armstrong G, Swan H, Fonseca A, Nagy JB, Maser WK, Blau WJ, Coleman JN (2007) Carbon nanotubes for reinforcement of plastics? A case study with poly(vinyl alcohol). Compos Sci Technol 67:1640–1649CrossRef
6.
Islam MF, Rojas E, Bergey DM, Johnson AT, Yodh AG (2003) High weight fraction surfactant solubilization of single-wall carbon nanotubes in water. Nano Lett 3:269–273CrossRef
7.
Xie XL, Mai YW, Zhou XP (2005) Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater Sci Eng R-Rep 49:89–112CrossRef
8.
Huang SM (2003) Growing carbon nanotubes on patterned submicron-size SiO2 spheres. Carbon 41:2347–2352CrossRef
9.
Agrawal S, Kumar A, Frederick MJ, Ramanath G (2005) Hybrid microstructures from aligned carbon nanotubes and silica particles. Small 1:823–826CrossRef
10.
Singh C, Shaffer MS, Windle AH (2003) Production of controlled architectures of aligned carbon nanotubes by an injection chemical vapour deposition method. Carbon 41:359–368CrossRef
11.
Zou H, Wu S, Shen J (2008) Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Chem Rev 108:3893–3957CrossRef
12.
Stojanovic D, Orlovic A, Markovic S, Radmilovic V, Uskokovic PS, Aleksic R (2009) Nanosilica/PMMA composites obtained by the modification of silica nanoparticles in a supercritical carbon dioxide-ethanol mixture. J Mater Sci 44:6223–6232CrossRef
13.
Motaung TE, Saladino ML, Luyt AS, Martino DFC (2012) The effect of silica nanoparticles on the morphology, mechanical properties and thermal degradation kinetics of polycarbonate. Compos Sci Technol 73:34–39CrossRef
14.
Chen YC, Lin HC, Lee YD (2003) The effects of filler content and size on the properties of PTFE/SiO2 composites. J Polym Res 10:247–258CrossRef
15.
Sharif A, Koolivand H, Khanbabaie G, Hemmati M, Aalaie J, Razzaghi Kashani M, Gheshlaghi A (2012) Improvement of CO2/CH4 separation characteristics of polyethersulfone by modifying with polydimethylsiloxane and nano-silica. J Polym Res 19:9916–9923CrossRef
16.
Laachachi A, Vivet A, Nouet G, Ben Doudou B, Poilâne C, Chen J, Bai JB, Ayachi M (2008) A chemical method to graft carbon nanotubes onto a carbon fiber. Mater Lett 62:394–397CrossRef
17.
Lin Y, Rao AM, Sadanadan B, Kenik EA, Sun YP (2002) Functionalizing multiple-walled carbon nanotubes with aminopolymers. J Phys Chem B 106:1294–1298CrossRef
18.
Jiang K, Eitan A, Schadler LS, Ajayan PM, Siegel RW, Grobert N, Mayne M, Reyes-Reyes M, Terrones H, Terrones M (2003) Selective attachment of gold nanoparticles to nitrogen-doped carbon nanotubes. Nano Lett 3:275–277CrossRef
19.
Liu J, Rinzler AG, Dai H, Hafner JH, Bradley RK, Boul PJ, Lu A, Iverson T, Shelimov K, Huffman CB, Rodriguez-Macias F, Shon YS, Lee TR, Colbert DT, Smalley RE (1998) Fullerene pipes. Science 280:1253–1256CrossRef
20.
Zhao W, Song C, Pehrsson PE (2002) Water-soluble and optically pH-sensitive single-walled carbon nanotubes from surface modification. J Am Chem Soc 124:12418–12419CrossRef
21.
Kovtyukhova NI, Mallouk TE, Pan L, Dickey EC (2003) Individual single-walled nanotubes and hydrogels made by oxidative exfoliation of carbon nanotube ropes. J Am Chem Soc 125:9761–9769CrossRef
22.
Peng H, Alemany LB, Margrave JL, Khabashesku VN (2003) Sidewall carboxylic acid functionalization of single-walled carbon nanotubes. J Am Chem Soc 125:15174–15182CrossRef
23.
Basiuk EV, Basiuk VA, Bañuelos JG, Saniger-Blesa JM, Pokrovskly BG (2002) Interaction of oxidized single-walled carbon nanotubes with vaporous aliphatic amines. J Phys Chem B 106:1588–1597CrossRef
24.
Huang W, Lin Y, Taylor S, Gallard J, Rao AM, Sun YP (2002) Sonication-assisted functionalization and solubilization of carbon nanotubes. Nano Lett 2:231–234CrossRef
25.
Xu Y, Gao C, Kong H, Yan D, Jin YZ, Watts PCP (2004) Growing multihydroxylhyperbranched polymers on the surfaces of carbon nanotubes by in situ ring-opening polymerization. Macromolecules A–H
26.
Ben Doudou B, Chen J, Vivet A, Poilâne C (2012) Ab initio study of the size-dependent effect on the covalent functionalization of the single walled carbon nanotubes with hydroxyl, amine and carboxyl groups. J Nanosci Nanotechnol 12:8635–8639CrossRef
27.
Ben Doudou B, Chen J, Vivet A, Poilâne C, Nouet G, Ayachi M (2008) Ab initio study of interactions between covalently functionalized carbon nanotubes. World J Eng 5:581
28.
Zhu J, Kim JD, Peng HQ, Margrave JL, Khabashesku VN, Barrera EV (2003) Improving the dispersion and integration of single-walled carbon nanotubes in epoxy composites through functionalization. Nano Lett 3:1107–1113CrossRef
29.
Jang SR, Vittal R, Kim KJ (2004) Incorporation of functionalized single-wall carbon nanotubes in dye-sensitized TiO2 Solar cells. Langmuir 20:9807–9810CrossRef
30.
Rahman IA, Jafarzadeh M, Sipaut CS (2009) Synthesis of organo-functionalized nanosilica via a co-condensation modification using γ-aminopropyltriethoxysilane (APTES). Ceram Int 35:1883–1888CrossRef
31.
Vandenberg ET, Bertilsson L, Liedberg B, Uvdal K, Erlandsson R, Elwing H, Lundstrom I (1991) Structure of 3-aminopropyltriethoxisylane on silicon oxides. J Colloid Interface Sci 147:103–118CrossRef
32.
Hasan M, Das SK, Islam JMM, Abdul Gafur M, Hoque E, Khan MA (2013) Thermal properties of Carbon Nanotube (CNT) reinforced Polyvinyl Alcohol (PVA) composites. Int Lett Chem Phys Astron 12:59–66
33.
Penga Z, Konga LX, Lib SD (2005) Non-isothermal crystallisation kinetics of self-assembled polyvinylalcohol/silica nano-composite. Polymer 46:1949–1955CrossRef
34.
Probst O, Moore EM, Resasco DE, Grady BP (2004) Nucleation of polyvinyl alcohol crystallization by single-walled carbon nanotubes. Polymer 45:4437–4443CrossRef
35.
Zhanga J, Minea M, Zhua D, Matsuo M (2009) Electrical and dielectric behaviors and their origins in the three-dimensional polyvinyl alcohol/MWCNT composites with low percolation threshold. Carbon 47:1311–1320CrossRef
36.
Bin Y, Mine M, Koganemaru A, Jiang X, Matsuo M (2006) Morphology and mechanical and electrical properties of oriented PVA–VGCF and PVA–MWNT composites. Polymer 47:1308–1317CrossRef
37.
Zhang N, Xie J, Varadan VK (2006) Soluble functionalized carbon nanotube/poly(vinyl alcohol) nanocomposite as the electrode for glucose sensing. Smart Mater Struct 15:123–128CrossRef
38.
Martin CA, Sandler JKW, Shaffer MSP, Schwarz MK, Bauhofer W, Schulte K, Windle AH (2004) Formation of percolating networks in multi-wall carbon-nanotube epoxy composites. Compos Sci Technol 64:2309–2316CrossRef
39.
Ounaies Z, Parkb C, Wiseb KE, Siochic EJ, Harrisonc JS (2003) Electrical properties of single wall carbon nanotube reinforced polyimide composites. Compos Sci Technol 63:1637–1646CrossRef
40.
Bin Y, Kitanaka M, Zhu D, Matsuo M (2003) Development of highly oriented polyethylene filled with aligned carbon nanotubes by gelation/crystallization from solutions. Macromolecules 36:6213–6219CrossRef
41.
Seo MK, Park SJ (2004) Electrical resistivity and rheological behaviors of carbon nanotubes-filled polypropylene composites. Chem Phys Lett 395:44–48CrossRef
42.
Shaffer MSP, Windle AH (1999) Fabrication and characterization of carbon nanotube/poly(vinyl alcohol) composites. Adv Mater 11:937–941CrossRef
43.
Kilbride BE, Coleman JN, Fraysse J, Fournet P, Cadek M, Drury A, Hutzler S, Roth S, Blau WJ (2002) Experimental observation of scaling laws for alternating current and direct current conductivity in polymer-carbon nanotube composite thin films. J Appl Phys 92:4024–4030CrossRef
44.
Zhang W, Li W, Wang J, Qin C, Dai L (2010) Composites of polyvinyl alcohol and carbon nanotubes decorated with silver nanoparticles. Fibers Polym 11:1132–1136CrossRef
45.
Bai JB, Allaoui A (2003) Effect of the length and the aggregate size of MWNTs on the improvement efficiency of the mechanical and electrical properties of nanocomposites-experimental investigation. Compos Part A 34:689–694CrossRef
46.
Lee GW, Lee JI, Park M, Kim J (2005) Comparisons of thermal properties between inorganic filler and acid-treated multiwall nanotube/polymer composites. J Mater Sci 40:1259–1263CrossRef
Metadaten
Titel
Hybrid carbon nanotube—silica/ polyvinyl alcohol nanocomposites films: preparation and characterisation
verfasst von
Bessem Ben Doudou
Alexandre Vivet
Jun Chen
Abdelghani Laachachi
Thierry Falher
Christophe Poilâne
Publikationsdatum
01.04.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 4/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-014-0420-9

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