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Journal of Polymer Research

Erschienen in:

01.01.2018 | ORIGINAL PAPER

Influence of graphene on the non-isothermal crystallization kinetics of poly(vinyl alcohol)/starch composite

verfasst von: Osamah A. Bin-Dahman, Farrukh Shehzad, Mamdouh A. Al-Harthi

Erschienen in: Journal of Polymer Research | Ausgabe 1/2018

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Abstract

Non-isothermal crystallization behavior of poly(vinyl alcohol)/starch and poly(vinyl alcohol)/starch/graphene nanocomposites was studied using differential scanning calorimetry (DSC). Ozawa and Mo models were used to analyze the non-isothermal kinetics. The differential Friedman method was used to evaluate the effective activation energy (E _A) of the nanocomposites. The data fits the Mo Model well in the investigated temperature range. Graphene nucleates the crystallization of the composites by increasing the crystallization onset temperature along with the lowering of E _A. However, significant changes in the crystallization half-time were not observed, suggesting that the effect of graphene is more prominent at the nucleation stage.

Vorheriger Artikel A novel approach to analyze the rheological properties of hydrogels with network structure simulation

Nächster Artikel Structure, thermal conductive, dielectric and electrical insulating properties of UHMWPE/BN composites with a segregated structure

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Titel: Influence of graphene on the non-isothermal crystallization kinetics of poly(vinyl alcohol)/starch composite
verfasst von: Osamah A. Bin-Dahman
Farrukh Shehzad
Mamdouh A. Al-Harthi
Publikationsdatum: 01.01.2018
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 1/2018
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-017-1400-7

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