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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2018

01.05.2018 | ORIGINAL PAPER

Excellent corrosion protection performance of epoxy composite coatings filled with silane functionalized silicon nitride

verfasst von: Yongxing Zhang, Min Zhao, Jiaoxia Zhang, Qian Shao, Jianfeng Li, Hang Li, Bo Lin, Meiyan Yu, Shougang Chen, Zhanhu Guo

Erschienen in: Journal of Polymer Research | Ausgabe 5/2018

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Abstract

Silicon nitride was firstly used as anticorrosive pigment in organic coatings. An effective strategy by combining inorganic fillers and organosilanes was used to enhance the dispersibility of silicon nitride in epoxy resin. The formed nanocomposites were applied to protect Q235 carbon steel from corrosion. The anticorrosive performance of modified silicon nitride with silane (KH-570) was investigated by electrochemical impedance spectroscopy (EIS), water absorption and pull-off adhesion methods. With the increase of immersion time, the corrosion resistance as well as adhesion strength of epoxy resin coating and unmodified silicon nitride coating decreased significantly. However, for the modified silicon nitride coating, the corrosion resistance and adhesion strength still maintained 5.7×1010 Ω cm2 and 7.6 MPa after 2400-h and 1200-h immersion, respectively. The excellent corrosion resistance performance could be attributed to the chemical interactions between KH-570 functional groups and silicon nitride powders, which mainly came from the easy formation of Si-O-Si bonds. Furthermore, the modified silicon nitride coating formed a strong barrier to corrosive electrolyte due to the hydrophobic of modified silicon nitride powder and increased bonds.
Vorheriger Artikel Facile fabrication of hollow polyaniline spheres and its application in supercapacitor

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Metadaten
Titel
Excellent corrosion protection performance of epoxy composite coatings filled with silane functionalized silicon nitride
verfasst von
Yongxing Zhang
Min Zhao
Jiaoxia Zhang
Qian Shao
Jianfeng Li
Hang Li
Bo Lin
Meiyan Yu
Shougang Chen
Zhanhu Guo
Publikationsdatum
01.05.2018
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2018
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-018-1518-2

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