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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2019

01.05.2019 | ORIGINAL PAPER

Poly[1,3,6,8-tetra(2-thiophenyl)pyrene] and poly[1,3,6,8-tetra(3-thiophenyl)pyrene] conjugated microporous polymers for reversible adsorbing and fluorescent sensing iodine

verfasst von: Tongmou Geng, Lanzhen Ma, Guofeng Chen, Can Zhang, Weiyong Zhang, Hongyu Xia, Hai Zhu

Erschienen in: Journal of Polymer Research | Ausgabe 5/2019

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Abstract

Two thiophene- and pyrene-based conjugated microporous polymers poly[1,3,6,8-tetra(2-thiophenyl)pyrene] and poly[1,3,6,8-tetra(3-thiophenyl)pyrene] (PTThP-2 and PTThP-3) were designed and prepared through a FeCl3 oxidative coupling polymerization. The PTThP-2 and PTThP-3 possess considerable BET surface area of over 370.8 m2 g−1 and 748.2 m2 g−1, large pore volume of 0.544 cm3 g−1 and 0.573 cm3 g−1, good stability, and display excellent guest uptake of 1.62 and 2.00 g g−1 in iodine vapour. Furthermore, incorporation of pyrene and thiophene moieties into these polymers can induce high fluorescence in the dispersions of tetrahydrofuran (THF), which make them sensing electron-deficient iodine via fluorescence quenching with the Ksv of 1.99 × 103 and 5.09 × 103 L mol−1, and the limit of detection of 7.54 × 10−8 and 2.95 × 10−8 mol L−1, respectively.
Vorheriger Artikel Transurethanization reaction as an alternative for melt modification of polyamide 6
Nächster Artikel The study on aging behaviors and critical stress of cross-linked high-density polyethylene during stress and photo-oxidative aging

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Metadaten
Titel
Poly[1,3,6,8-tetra(2-thiophenyl)pyrene] and poly[1,3,6,8-tetra(3-thiophenyl)pyrene] conjugated microporous polymers for reversible adsorbing and fluorescent sensing iodine
verfasst von
Tongmou Geng
Lanzhen Ma
Guofeng Chen
Can Zhang
Weiyong Zhang
Hongyu Xia
Hai Zhu
Publikationsdatum
01.05.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1766-9

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