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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2019

01.05.2019 | ORIGINAL PAPER

Effect of Sulphur-chlorine bifunctional diol (SCBD) on antimicrobial, thermal and mechanical behavior of polyether block amide (PEBA) based breathable membranes

verfasst von: Bhausaheb B. Sole, Geetha Seshadri, Ajay Kumar Tyagi, Sunita Rattan

Erschienen in: Journal of Polymer Research | Ausgabe 5/2019

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Abstract

Polyether block amide (PEBA), a block copolymer is being blended with an organic compound 1-chloro-3-(2-hydroxyethylthio)propan-2-ol i.e. Sulphur-Chlorine Bifunctional Diol (SCBD) and membranes are obtained using solution casting method. Attempts have been made to impart antimicrobial properties to PEBA and investigate the effect of SCBD content on breathability, thermal stability and mechanical strength of the membranes. Fourier Transform Infrared – Attenuated Total Reflectance (FTIR-ATR), Scanning Electron Microscopy- Electron Dispersive X-Ray Spectroscopy (SEM-EDX), Atomic Force Microscopy (AFM), Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA) and Derivative Thermogravimetry (DTG) are used to characterize the membranes. Membranes are also tested for permeability towards two commercially important gases Helium (He) and Oxygen (O2). Small amount of SCBD (2.5%) is enough to impart antimicrobial property (upto 99.99% bacterial reduction) to the membranes without altering thermal stability and mechanical strength of the membrane. Membrane with higher SCBD content (10%) show degradation in thermal and mechanical behavior. 2.5% PEBA/SCBD membrane possess acceptable WVTR (1528 g/m2/day) and WVP (16.39 g.μm/m2.day.Pa) to be used for breathable applications including environmental (waste water treatment, Helium gas separation), biomedical (breathing mask, surgical gloves & gowns, bandages) etc.
Vorheriger Artikel Construction of highly stretchable silica/polyacrylamide nanocomposite hydrogels through hydrogen bond strategy
Nächster Artikel Self-assembly of linear-hyperbranched hybrid block polymers: crystallization-driven or solvent-driven?

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Fußnoten
1
Detailed synthesis and characterization of SCBD is being provided in supplementary information
 
2
Value of S is 35.7 mmHg (4760 Pa) at 32 °C and 49.7 mmHg (6626 Pa) at 38 °C
 
Literatur
1.
Brewer SA (2011) Recent patents on. Material Science 4:1–14
2.
3.
4.
Sridhar S, Suryamurali R, Smitha B, Aminabhavi TM (2007) Colloids and Surfaces A: Physicochemical and Engineering Aspects. Colloids Surf A Physicochem Eng Asp 297:267–274CrossRef
5.
Liu L, Chakma A, Feng X (2005) CO2/N2 separation by poly(ether block amide) thin film hollow Fiber composite membranes. Ind Eng Chem Res 44:6874–6882CrossRef
6.
Kim JH, Lee YM (2001) Gas permeation properties of poly(amide-6-b-ethylene oxide)–silica hybrid membranes. J Membr Sci 193:209–225CrossRef
7.
Friess K, Hynek V, Sipek M, Kujawski WM, Vopicka O, Zgazar M, Kujawski MW (2011) Permeation and sorption properties of poly(ether-block-amide) membranes filled by two types of zeolites. Sep Purif Technol 80:418–427CrossRef
8.
Akhtar FH, Kumar M, Peinemann KV (2017) Pebax®1657/graphene oxide composite membranes for improved water vapor separation. J Membr Sci 525:187–194CrossRef
9.
10.
11.
12.
Peng L, Gang X, Dicky P, Li QX, Koon-Gee N, En-Tang K (2018) pH-sensitive Zwitterionic polymer as an antimicrobial agent with effective bacterial targeting. ACS Biomater Sci Eng 4(1):40–46CrossRef
13.
Dastjerdi R, Montazer M (2010) A review on the application of inorganic nano-structured materials in the modification of textiles: focus on anti-microbial properties. Colloids Surf B: Biointerfaces 79:5–18CrossRef
14.
Nisola GM, Park JS, Beltran AB, Chung WJ (2012) Silver nanoparticles in a polyether-block-polyamide copolymer towards antimicrobial and antifouling membranes. RSC Adv 2:2439–2448CrossRef
15.
16.
Weld JT, Gunther A (1947) The antibacterial properties of sulfur. J Exp Med 85:531–542CrossRef
17.
Rufford TE, Chan KI, Huang SH, May EF (2014) A review of conventional and emerging process Technologies for the Recovery of helium from natural gas. Adsorpt Sci Technol 32:49–72CrossRef
18.
Perelshtein AG, Perkas N, Guibert G, Mikhailov S, Gedanken A (2008) Sonochemical coating of silver nanoparticles on textile fabrics (nylon, polyester and cotton) and their antibacterial activity. Nanotechnology 19:245705–245711CrossRef
19.
Wiyong K, Vichuta L, Suvimol S, Uracha R (2009) Antibacterial effect of apatite-coated titanium dioxide for textiles applications. Nanomedicine 5:240–249CrossRef
20.
Jafar H, Russell JC, Elena PI (2013) Antibacterial surfaces: the quest for a new generation of biomaterials. Trends Biotechnol 31:295–304CrossRef
21.
El-Refaie KE, Imam Abdel-Hay F, Ahmed A. Yehia M (2006) Biologically active polymers: VII. Synthesis and antimicrobial activity of some crosslinked copolymers with quaternary ammonium and phosphonium groups. Polymers 66: 419–429
22.
Guangli L, Jiarui S (2000) A study of pyridinium-type functional polymers. IV. Behavioral features of the antibacterial activity of insoluble pyridinium-type polymers. J Appl Polym Sci 78:676–684CrossRef
23.
Maribel P, Gustavo V, Roberto O, Maria MCO, Keiko S (2003) Effect of chitosan and temperature on spore germination of Aspergillus Niger. Macromol Biosci 3:582–586CrossRef
24.
Goldberg S, Doyle RJ, Rosenberg M (1990) Mechanism of enhancement of microbial cell hydrophobicity by cationic polymers. J Bacteriol 172:5650–5654CrossRef
25.
Reijerkerk SR, Knoef MH, Nijmeijer K, Wessling M (2010) Poly(ethylene glycol) and poly(dimethyl siloxane): combining their advantages into efficient CO2 gas separation membranes. J Membr Sci 352:126–135CrossRef
26.
Rabieea H, Soltanieh MS, Mousavia A, Ghadimi (2014) Improvement in CO2/H2 separation by fabrication of poly(ether-b-amide6)/glycerol triacetate gel membranes. J Membr Sci 469:43–58CrossRef
27.
Jha GS, Chhabra P, Suri G, Tyagi M, Arora P, Seshadri G, Khandal RK (2009) Study on designing sulfur containing bifunctional building block with improved refractive index. E- J Chem 6(2):399–411CrossRef
28.
Liua Z, Xua Z, Wana L, Wub J, Ulbrichtc M (2005) Surface modification of polypropylene microfiltration membranes by the immobilization of poly(N-vinyl-2-pyrrolidone): a facile plasma approach. J Membr Sci 249:21–31CrossRef
29.
Sridhar S, Kalyani S, Ravikumar YVL, Muralikrishna TSVN (2010) Performance of composite membranes of poly(ether–block–amide) for dehydration of ethylene glycol and ethanol. Sep Sci Technol 45:322–330CrossRef
30.
Kumbharkar SC, Kharul UK (2009) N-substitution of polybenzimidazoles: synthesis and evaluation of physical properties. Eur Polym J 45:3363–3371CrossRef
31.
Stern SA, Gareis PJ, Sinclair TF, Mohr PH (1963) Performance of a versatile variable-volume permeability cell. Comparison of gas permeability measurements by the variable-volume and variable-pressure methods. J Appl Polym Sci 7:2035–2051CrossRef
32.
Kim JH, Lee YM (2001) Gas permeation properties of poly(amide-6-b-ethylene oxide)–silica hybrid membranes. J Membr Sci 193:209–225CrossRef
33.
Wang S, Liu Y, Huang S, Wu H, Li Y, Tian Z, Jiang Z (2014) Pebax-PEG-MWCNT hybrid membranes with enhanced CO2 capture properties. J Membr Sci 460:62–70CrossRef
34.
Peyravi M, Ardestani MA, Babaluo AA, Aghjeh MKR, Pishghadam SR, Jannatdoust E (2010) Synthesis and characterization of nanostructured- segmented block copolyetheramide based on nylon 6 and Polyethyleneoxide. Chin J Polym Sci 28:597–605CrossRef
35.
Zhao D, Ren J, Wang Y, Qiu Y, Li H, Hua K, Li X, Ji J, Deng M (2016) High CO2 separation performance of Pebax®/CNTs/GTA mixed matrix membranes. J Membr Sci 521:104–113CrossRef
36.
Pavia D L, Lampman GM, Kriz G S (2001) In introduction to spectroscopy, 3rd edition ; Thomson Learning, Chapter 2, p 70
37.
Ghadimi A, Amirilargani M, Mohammadi T, Kasiri N, Sadatnia B (2014) Preparation of alloyed poly (ether block amide)/poly (ethylene glycol diacrylate) membranes for separation of CO2/H2 (syngas application). J Membr Sci 458:14–26CrossRef
38.
Shichao F, Jizhong R, Kaisheng H, Hui L, Xiaoling R, Deng M (2013) Poly(amide-12-b-ethylene oxide)/polyethylene glycol blend membranes for carbon dioxide separation. Sep Purif Technol 116:25–34CrossRef
39.
Car A, Stropnik C, Yave W, Peinemann KV (2008) PEG modified poly(amide-b-ethylene oxide) membranes for CO2 separation. J Membr Sci 307:88–95CrossRef
40.
Khosravi T, Omidkhah M (2015) Preparation of CO2-philic polymeric membranes by blending poly(ether-b-amide-6) and PEG/PPG-containing copolymer. RSC Adv 5:12849–12859CrossRef
41.
Feng S, Ren J, Li Z, Li H, Hua K, Li X, Deng M (2013) Poly(amide-12-b-ethylene oxide)/glycerol triacetate blend membranes for CO2 separation. Int J Greenh Gas Con 19:41–48 CrossRef
42.
Rosenthal RA, Schlitzen RL, McNamee LS, Dassanayake LN, Amass P (1992) Antimicrobial activity of organic chlorine releasing compounds. Cont Lens Anterior Eye 15:81–84
43.
McDonnell G, Russell AD (1999) Antiseptics and disinfectants: activity, action, and resistance. Clin Microbiol Rev 12:147–179CrossRef
44.
Kim J, Pitts B, Stewart PS, Camper A, Yoon J (2008) Comparison of the antimicrobial effects of chlorine, silver ion, and tobramycin on biofilm. Antimicrob Agents Chemother 52(4):1446–1453CrossRef
45.
Weld JT, Gunther A (1947) The antibacterial properties of sulfur. J Exp Med 85(5):531–542CrossRef
46.
Yanyali SA, Cetin H, Talu H, Vahaboglu (2001) Effect of sulfur hexafluoride gas on antibacterial activity of antibiotics in vitro against agents causing endophthalmitis. Ophthalmologica 215(6):439–443CrossRef
47.
Konaklieva MI, Plotkin BJ (2010) In Frontiers in anti-infective drug discovery, Benthum e book: vol. 1 chapter 10, pp 269–278CrossRef
Metadaten
Titel
Effect of Sulphur-chlorine bifunctional diol (SCBD) on antimicrobial, thermal and mechanical behavior of polyether block amide (PEBA) based breathable membranes
verfasst von
Bhausaheb B. Sole
Geetha Seshadri
Ajay Kumar Tyagi
Sunita Rattan
Publikationsdatum
01.05.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1780-y

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