Abstract
The study shows geochemical characterization of placer deposit in parts of coastal Odisha, India using Instrumental Neutron Activation Analysis (INAA). Twenty seven elements were estimated in ten heavy mineral beach sand samples. The characterisation was mostly based on the trace element, radioactive element and Rare Earth Element (REE) content of the bulk sand samples. The results indicate elevated concentration of thorium and the REE’s. The concentration of Scandium has been reported for the first time along this area. Positive correlation between thorium and REE was observed in beach placer samples collected from study area.
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13 November 2018
The original article was published without an acknowledgement section. The complete acknowledgement section is given below.
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Acknowledgements
The work has been funded by the Science and Engineering Research Board (SERB), DST, Govt. of India, under the Project Code: YSS/2015/000979. We acknowledge their financial assistance. We are also thankful to the technical personnel associated with this study, especially to the persons involved in the TRIGA Mark II research reactor operation at the Center for Research Reactor, AERE, Bangladesh Atomic Energy Commission, Bangladesh.
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Appendices
Appendix A: Elemental abundances in heavy mineral placers collected from the beach placers in Odisha, the values are expressed in µg/g
L-5 | ± | L-7 | ± | L-9 | ± | L-10 | ± | L-11 | ± | L-13 | ± | L-14 | ± | L-16 | ± | L-18 | ± | L-19 | ± | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Na | 416 | 4 | 321 | 3 | 336 | 3 | 312 | 3 | 318 | 3 | 325 | 4 | 172 | 2 | 233 | 3 | 538 | 7 | 476 | 6 |
Al | 4340 | 30 | 4180 | 30 | 4880 | 30 | 4880 | 30 | 5120 | 30 | 4180 | 30 | 4040 | 30 | 5450 | 40 | 5030 | 40 | 4710 | 40 |
K | 2330 | 50 | 1720 | 30 | 1770 | 40 | 1970 | 40 | 1680 | 40 | 1340 | 30 | 718 | 21 | 1030 | 30 | 2500 | 60 | 2080 | 50 |
Sc | 5.68 | 0.07 | 7.38 | 0.08 | 21 | 0.2 | 17.7 | 0.2 | 22.5 | 0.2 | 12.9 | 0.2 | 34 | 0.4 | 20.2 | 0.3 | 7.12 | 0.09 | 11.6 | 0.2 |
Ti | 633 | 34 | 1330 | 60 | 6260 | 270 | 3990 | 180 | 6420 | 280 | 1910 | 90 | 11,700 | 500 | 5480 | 240 | 1480 | 70 | 2210 | 100 |
V | 73 | 2 | 110 | 3 | 368 | 7 | 255 | 6 | 378 | 8 | 142 | 4 | 643 | 12 | 351 | 8 | 123 | 4 | 159 | 4 |
Cr | 46 | 1 | 62 | 1 | 151 | 2 | 135 | 2 | 151 | 3 | 76 | 2 | 222 | 4 | 152 | 3 | 74 | 1 | 84 | 3 |
Mn | 334 | 3 | 464 | 4 | 1451 | 9 | 1214 | 8 | 1544 | 10 | 851 | 6 | 2249 | 13 | 1418 | 9 | 420 | 4 | 800 | 6 |
Fe | 2020 | 40 | 2720 | 40 | 9240 | 130 | 7160 | 100 | 9830 | 140 | 4250 | 70 | 16,600 | 300 | 8200 | 140 | 2880 | 50 | 4160 | 90 |
Co | 6.17 | 0.19 | 7.37 | 0.18 | 24.7 | 0.4 | 19.4 | 0.3 | 25 | 0.4 | 11.1 | 0.3 | 38.7 | 0.7 | 20.2 | 0.4 | 9.4 | 0.2 | 11.9 | 0.4 |
Zn | 47 | 3 | 53 | 3 | 209 | 8 | 152 | 6 | 177 | 7 | 84 | 4 | 299 | 12 | 169 | 7 | 89 | 4 | 80 | 6 |
Ga | 9.28 | 0.43 | 11.1 | 0.5 | 17.2 | 0.6 | 15.4 | 0.6 | 16.5 | 0.7 | 12.2 | 0.6 | 18 | 0.7 | 20.7 | 0.8 | 11.7 | 0.6 | 14.1 | 0.7 |
As | 3.1 | 0.14 | 1.84 | 0.1 | 6.71 | 0.2 | 7.32 | 0.23 | 8.36 | 0.25 | 2.21 | 0.12 | 4.29 | 0.17 | 3.32 | 0.16 | 4.64 | 0.19 | 7.13 | 0.25 |
Ba | 688 | 30 | 523 | 24 | 483 | 22 | 595 | 27 | 457 | 23 | 397 | 21 | 281 | 16 | 343 | 20 | 10,893 | 366 | 608 | 30 |
La | 35.7 | 0.8 | 110 | 2 | 502 | 7 | 501 | 7 | 383 | 6 | 123 | 2 | 1958 | 33 | 972 | 16 | 169 | 3 | 93 | 2 |
Ce | 73 | 1 | 240 | 4 | 1034 | 15 | 1088 | 16 | 859 | 13 | 260 | 5 | 4443 | 75 | 2002 | 34 | 375 | 6 | 189 | 4 |
Nd | 23.2 | 1 | 93 | 3 | 439 | 10 | 513 | 12 | 331 | 8 | 79 | 3 | 1923 | 46 | 1013 | 25 | 124 | 4 | 91 | 3 |
Sm | 4.86 | 0.07 | 15.1 | 0.2 | 68.7 | 0.7 | 69.3 | 0.7 | 51 | 0.5 | 16.7 | 0.2 | 256 | 3 | 125 | 2 | 24.1 | 0.3 | 13.3 | 0.2 |
Eu | 1.12 | 0.06 | 1.02 | 0.05 | 1.8 | 0.07 | 1.87 | 0.06 | 1.78 | 0.07 | 1.15 | 0.06 | 3.64 | 0.11 | 2.1 | 0.08 | 1.68 | 0.05 | 1.01 | 0.08 |
Tb | 0.411 | 0.025 | 0.808 | 0.031 | 3.36 | 0.08 | 3.21 | 0.07 | 2.65 | 0.07 | 1.16 | 0.04 | 10.1 | 0.2 | 4.66 | 0.12 | 1.26 | 0.04 | 0.963 | 0.061 |
Dy | 2.44 | 0.06 | 4.25 | 0.09 | 14.8 | 0.2 | 15.1 | 0.2 | 12.6 | 0.2 | 6.9 | 0.1 | 37.7 | 0.6 | 20.7 | 0.4 | 5.49 | 0.13 | 5.82 | 0.14 |
Yb | 1.48 | 0.06 | 2.89 | 0.08 | 7.51 | 0.16 | 6.57 | 0.13 | 6.88 | 0.16 | 4.8 | 0.13 | 14.7 | 0.3 | 7.31 | 0.18 | 2.24 | 0.06 | 4.72 | 0.2 |
Lu | 0.189 | 0.008 | 0.207 | 0.008 | 0.669 | 0.02 | 0.581 | 0.018 | 0.538 | 0.017 | 0.388 | 0.014 | 1.03 | 0.03 | 0.669 | 0.022 | 0.233 | 0.01 | 0.394 | 0.015 |
Hf | 8.7 | 0.2 | 13.5 | 0.3 | 55.3 | 0.9 | 55.3 | 0.9 | 36.9 | 0.6 | 21.5 | 0.4 | 138 | 2 | 60.1 | 1.1 | 24.9 | 0.5 | 18 | 0.5 |
Ta | 1.36 | 0.08 | 2.85 | 0.12 | 11.9 | 0.4 | 8.04 | 0.26 | 11.2 | 0.4 | 3.76 | 0.16 | 23.9 | 0.8 | 10 | 0.4 | 2.82 | 0.11 | 4.64 | 0.24 |
Th | 21.7 | 0.3 | 72.1 | 0.8 | 327 | 3 | 340 | 3 | 279 | 3 | 80.3 | 1.1 | 1430 | 19 | 634 | 8 | 103 | 1 | 67.8 | 1 |
U | 1.24 | 0.06 | 3.2 | 0.1 | 13.1 | 0.3 | 12.3 | 0.3 | 8.8 | 0.2 | 2.89 | 0.11 | 43.3 | 0.9 | 21.1 | 0.5 | 6.61 | 0.22 | 3.35 | 0.16 |
Appendix B: Elements with their resulting radionuclide (after interaction with thermal neutron), half-life, counting mood (Short1-S1, Short2-S2, Long1-L1, Long2-L2 and Long3-L3) and the respective gamma energy (in keV)
Elements | Radionuclide | Half-life | Counting mood | Gamma energy (keV) |
---|---|---|---|---|
Na | 24Na | 15.02 h | S2 | 1368.8, 2754 |
Al | 28Al | 2.25 month | S1 | 1778.8 |
K | 42K | 12.36 h | S2 | 1524.6 |
Sc | 46Sc | 83.83 days | L3 | 889.2, 1120.5 |
Ti | 51Ti | 5.76 month | S1 | 320.1 |
V | 52V | 3.76 month | S1 | 1434.2 |
Cr | 51Cr | 27.7 days | L3 | 320.1 |
Mn | 56Mn | 2.58 month | S2 | 846.6, 1810.7, 2113.2 |
Fe | 59Fe | 44.50 days | L3 | 1099.2, 1291.6 |
Co | 60Co | 5.27 years | L3 | 1173.2, 1332.5 |
Zn | 65Zn | 244.1 days | L3 | 1115.5 |
Ga | 72Ga | 14.1 h | L1 | 629.9, 834 |
As | 76As | 26.30 h | L1 | 559.1 |
Ba | 131Ba | 11.8 days | L2 | 123.8, 216, 373.2, 496.3 |
La | 140La | 1.68 days | L1 | 328.8, 487, 815.8, 1596.2 |
Ce | 141Ce | 32.51 days | L3 | 145.5 |
Nd | 147Nd | 10.99 days | L2 | 91.1, 531 |
Sm | 153Sm | 1.94 days | L1 | 103.2 |
Eu | 152Eu | 13.33 years | L3 | 121.8, 1408 |
Tb | 160Tb | 72.30 days | L3 | 298.6, 879.4, 1177.9 |
Dy | 165Dy | 2.33 h | S2 | 94.7 |
Yb | 169Yb | 32.02 days | L3 | 177 |
175Yb | 4.19 days | L1 | 282.5, 396.3 | |
Lu | 177Lu | 6.71 days | L2 | 208.4 |
Hf | 181Hf | 42.39 days | L3 | 132.9, 482 |
Ta | 182Ta | 115 days | L3 | 1189, 1221.4 |
Th | 233Pa | 27 days | L3 | 311.9 |
U | 239Np | 2.35 days | L1 | 106.1, 228.2, 277 |
Appendix C: Elemental abundances in replicate measurements (n = 3) of IAEA-SL-1 along with their literature values [27]. Individual uncertainties are due to their counting statistics and the neutron flux corrections obtained from monitor foils
SL-1(1) | ± | SL-1(2) | ± | SL-1(3) | ± | Average | SD | RSD (%) | Certificate | Min. | Max. | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Mass (g) | 0.04,003 | 0.0614 | 0.07083 | |||||||||
Na (%) | 0.173 | 0.002 | 0.171 | 0.002 | 0.169 | 0.002 | 0.171 | 0.002 | 1.2 | 0.172 | 0.16 | 0.184 |
Al (%) | 10 | 0.06 | 9.9 | 0.06 | 9.96 | 0.06 | 9.95 | 0.05 | 0.5 | 8.9 | ||
K (%) | 1.41 | 0.04 | 1.44 | 0.04 | 1.37 | 0.03 | 1.41 | 0.04 | 2.7 | 1.5 | ||
Sc (µg/g) | 16 | 0.2 | 14.9 | 0.2 | 15.6 | 0.3 | 15.5 | 0.6 | 3.6 | 17.3 | 16.2 | 18.4 |
Ti (%) | 0.417 | 0.026 | 0.514 | 0.029 | 0.515 | 0.028 | 0.482 | 0.057 | 11.7 | 0.517 | 0.48 | 0.554 |
V (µg/g) | 152 | 5 | 165 | 5 | 164 | 5 | 160 | 7 | 4.5 | 170 | 155 | 185 |
Cr (µg/g) | 104 | 2 | 98 | 2 | 101 | 2 | 101 | 3 | 2.9 | 104 | 95 | 113 |
Mn (µg/g) | 3431 | 18 | 3498 | 20 | 3433 | 18 | 3454 | 38 | 1.1 | 3460 | 3300 | 3620 |
Fe (%) | 6.5 | 0.09 | 6.2 | 0.1 | 6.38 | 0.12 | 6.36 | 0.15 | 2.4 | 6.74 | 6.57 | 6.91 |
Co (µg/g) | 19.2 | 0.3 | 16.9 | 0.3 | 17.9 | 0.3 | 18 | 1.2 | 6.5 | 19.8 | 18.3 | 21.3 |
Zn (µg/g) | 215 | 8 | 197 | 7 | 206 | 8 | 206 | 9 | 4.3 | 223 | 213 | 233 |
Ga (µg/g) | 21 | 1 | 24 | 1 | 23 | 2 | 23 | 1 | 5.1 | 24 | ||
As (µg/g) | 28.5 | 0.7 | 28 | 0.7 | 32.1 | 0.9 | 29.5 | 2.2 | 7.5 | 27.5 | 24.6 | 30.4 |
Ba (µg/g) | 593 | 27 | 610 | 27 | 571 | 28 | 591 | 20 | 3.3 | 639 | 586 | 692 |
La (µg/g) | 49 | 1 | 47 | 1 | 49 | 1 | 48 | 1 | 2.6 | 52.6 | 49.5 | 55.7 |
Ce (µg/g) | 106 | 2 | 99 | 2 | 105 | 2 | 103 | 4 | 3.6 | 117 | 100 | 134 |
Nd (µg/g) | 42 | 2 | 48 | 2 | 47 | 2 | 46 | 3 | 6.6 | 43.8 | 41 | 46.6 |
Sm (µg/g) | 9 | 0.1 | 8.2 | 0.1 | 9.1 | 0.2 | 8.7 | 0.5 | 5.8 | 9.25 | 8.74 | 9.76 |
Eu (µg/g) | 1.79 | 0.02 | 1.59 | 0.02 | 1.71 | 0.03 | 1.7 | 0.1 | 5.8 | 1.6 | ||
Tb (µg/g) | 1.05 | 0.03 | 0.93 | 0.03 | 1.03 | 0.03 | 1 | 0.06 | 6.3 | 1.4 | ||
Dy (µg/g) | 6.8 | 0.1 | 6.6 | 0.2 | 7.9 | 0.2 | 7.1 | 0.7 | 9.7 | 7.46 | 5.34 | 9.58 |
Yb (µg/g) | 3 | 0.1 | 2.7 | 0.1 | 3.1 | 0.1 | 3 | 0.2 | 7.7 | 3.42 | 2.78 | 4.06 |
Lu (µg/g) | 0.47 | 0.02 | 0.64 | 0.03 | 0.79 | 0.04 | 0.64 | 0.16 | 25.1 | 0.54 | ||
Hf (µg/g) | 4.03 | 0.09 | 3.86 | 0.09 | 4.06 | 0.1 | 3.98 | 0.1 | 2.6 | 4.16 | 3.58 | 4.74 |
Ta (µg/g) | 1.07 | 0.05 | 0.84 | 0.04 | 1.13 | 0.05 | 1.02 | 0.15 | 14.9 | 1.6 | ||
Th (µg/g) | 12.9 | 0.2 | 11.7 | 0.2 | 12.8 | 0.2 | 12.4 | 0.7 | 5.5 | 14 | 13 | 15 |
U (µg/g) | 3.4 | 0.1 | 3.6 | 0.1 | 4.3 | 0.3 | 3.8 | 0.4 | 11.5 | 4.02 | 3.7 | 4.34 |
Both NIST-1633b (coal-fly-ash) and IAEA-Soil-7 were used as standard. For the quantification of Sc, V, Cr, Co, Ga, As, Ba, La, Nd, Sm, Eu, Tb, Dy, Hf, Yb, Ta, Th and U, NIST-1633b was used as standard while the rest of the elements were quantified by using IAEA-Soil-7 as the standard. Data reliability was checked by the repeated analysis (n = 3) of IAEA-SL-1 (lake sediment) with different sample mass (40.03 to 70.83 mg). Accuracy has been checked by comparing our analytical values (mean value) to those of certificate values. All the elemental abundances of our study are consistent with those of certificate value within 10%, except those for Al, Ce, Tb, Yb, Lu, Ta and Th. In the IAEA-SL-1 certificate (provided by IAEA), Tb, Yb, Lu and Ta are indicated as ‘information value’ rather than the ‘recommended value’. But considering the analytical uncertainty (standard deviation, 1σ) our elemental data for IAEA-SL-1 are consistent with those of certificate value. In “Appendix C”, reproducibility (precision) is presented by the relative standard deviations (RSDs). Analytical reproducibility for Na, Al, K, Sc, V, Cr, Mn, Fe, Zn, Ba, La, Ce and Hf are within 5.0% and for Co, Ga, As, Nd, Sm, Eu, Tb, Dy, Yb and Th are less than 10.0% but more than 5.0% whereas, the reproducibility for Ti, Lu, Ta and U are more than 10.0%.
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Khan, R., Ghosal, S., Sengupta, D. et al. Studies on heavy mineral placers from eastern coast of Odisha, India by instrumental neutron activation analysis. J Radioanal Nucl Chem 319, 471–484 (2019). https://doi.org/10.1007/s10967-018-6250-1
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DOI: https://doi.org/10.1007/s10967-018-6250-1