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Journal of Sol-Gel Science and Technology

Erschienen in:

01.06.2014 | Original Paper

Multifunctional superhydrophobic/oleophobic and flame-retardant cellulose fibres with improved ice-releasing properties and passive antibacterial activity prepared via the sol–gel method

verfasst von: Jelena Vasiljević, Brigita Tomšič, Ivan Jerman, Boris Orel, Gregor Jakša, Janez Kovač, Barbara Simončič

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2014

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Abstract

In this research, a two-component sol–gel inorganic–organic hybrid coating was prepared on a cotton fibre surface. An equimolar sol mixture of the precursors 1H,1H,2H,2H-perfluorooctyltriethoxysilane (SiF) and P,P-diphenyl-N-(3-(trimethoxysilyl)propyl) phosphinic amide (SiP) was applied to cotton fabric samples using the pad-dry-cure method. The surfaces of the untreated and coated cotton fibres were characterised using scanning electron microscopy, Fourier transform-infrared spectroscopy, X-ray photoelectron spectroscopy, and time-of-flight-secondary ion mass spectrometry. The functional properties of the coated cotton fabric samples were investigated using static contact angle measurements with water and n-hexadecane, the ice-releasing test, antibacterial testing against Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli, thermogravimetric analysis in an air atmosphere, and vertical flammability tests. The results reveal the formation of a nanocomposite two-component inorganic–organic hybrid polymer network that is homogenously distributed over the cotton fibre surface. The presence of the SiP component in the two-component inorganic–organic hybrid coating did not hinder the functional properties imparted by the presence of the SiF component and vice versa, illustrating their compatibility. The cooperative action of the SiF and SiP components in the two-component coating provided the cotton fabric with exceptional multifunctionality, including simultaneous superhydrophobicity and high oleophobicity, passive antibacterial activity, and improved thermo-oxidative stability.

Vorheriger Artikel Sol–gel derived nano zinc oxide for the reduction of zinc oxide level in natural rubber compounds

Nächster Artikel Microwave sintering of nickel ferrite nanoparticles processed via sol–gel method

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Titel: Multifunctional superhydrophobic/oleophobic and flame-retardant cellulose fibres with improved ice-releasing properties and passive antibacterial activity prepared via the sol–gel method
verfasst von: Jelena Vasiljević
Brigita Tomšič
Ivan Jerman
Boris Orel
Gregor Jakša
Janez Kovač
Barbara Simončič
Publikationsdatum: 01.06.2014
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 3/2014
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-014-3294-8

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