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Erschienen in: Journal of Sol-Gel Science and Technology 2/2018

10.04.2018 | Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Sol–gel preparation of ZrC–ZrO2 composite microspheres using fructose as a carbon source

verfasst von: Xi Sun, Jingtao Ma, Xiaotong Chen, Ziqiang Li, Changsheng Deng, Bing Liu

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2018

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Abstract

ZrC–ZrO2 composite ceramic microspheres were prepared by internal gelation combined with carbothermic reduction using fructose as a chelating agent and carbon source. Fructose in the precursor solution formed complex with zirconium ions, which was conducive to the refining of the microstructure of the sintered composite. ZrC–ZrO2 composite with ZrC content as high as 60 wt% could be prepared.

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Literatur
1.
Zurück zum Zitat Stinton DP, Lackey WJ, Spence RD (1982) Production of spherical UO2-UC2 for nuclear fuel applications using thermochemical principles. J Am Ceram Soc 65(7):321–324CrossRef Stinton DP, Lackey WJ, Spence RD (1982) Production of spherical UO2-UC2 for nuclear fuel applications using thermochemical principles. J Am Ceram Soc 65(7):321–324CrossRef
2.
Zurück zum Zitat Stinton DP (1983) Mixed uranium dicarbide and uranium dioxide microspheres and process of make same U. S. Patent No. 4,367,184 Stinton DP (1983) Mixed uranium dicarbide and uranium dioxide microspheres and process of make same U. S. Patent No. 4,367,184
3.
Zurück zum Zitat Barnes CM, Richardson WC, Husser D, Ebner M (2008) Fabrication process and product quality improvements in advanced gas reactor UCO kernels. HTR2008: 58039 Barnes CM, Richardson WC, Husser D, Ebner M (2008) Fabrication process and product quality improvements in advanced gas reactor UCO kernels. HTR2008: 58039
4.
Zurück zum Zitat Couland M, Fourcaudot S, Abril RJ, Carretero AF, Somer J (2012) Novel production route of yttria-stabilized zirconia fuel kernels and pellets for nuclear fuel applications. J Am Ceram Soc 95(1):133–137CrossRef Couland M, Fourcaudot S, Abril RJ, Carretero AF, Somer J (2012) Novel production route of yttria-stabilized zirconia fuel kernels and pellets for nuclear fuel applications. J Am Ceram Soc 95(1):133–137CrossRef
5.
Zurück zum Zitat Hunt RD, Lindemer TB, Hu MZ, Del Cul GD, Collins JL (2007) Preparation of spherical, dense uranium fuel kernels with carbon. Radiochim Acta 95(40):225–232 Hunt RD, Lindemer TB, Hu MZ, Del Cul GD, Collins JL (2007) Preparation of spherical, dense uranium fuel kernels with carbon. Radiochim Acta 95(40):225–232
6.
Zurück zum Zitat Ma X, Huang X, Kang Z, Zhang G, Luo H (2015) One-pot syntheses and characterization ofzirconium carbide microspheres by carbon microencapsulation Ceram Int 41(5):6740–6746CrossRef Ma X, Huang X, Kang Z, Zhang G, Luo H (2015) One-pot syntheses and characterization ofzirconium carbide microspheres by carbon microencapsulation Ceram Int 41(5):6740–6746CrossRef
7.
Zurück zum Zitat Phillips JA, Nagley SG, Shaber EL (2012) Fabrication of uranium oxycarbide kernels and compactsfor HTR fuel Nucl Eng Des 251:261–281CrossRef Phillips JA, Nagley SG, Shaber EL (2012) Fabrication of uranium oxycarbide kernels and compactsfor HTR fuel Nucl Eng Des 251:261–281CrossRef
8.
Zurück zum Zitat Hunt RD, Silva CM, Lindemer TB, Johnson JA, Collins JL (2014) Preparation of UC0.07-0.10N0.90-0.93spheres for TRISO coated fuel particles J Nucl Mater 448(1–3):399–403CrossRef Hunt RD, Silva CM, Lindemer TB, Johnson JA, Collins JL (2014) Preparation of UC0.07-0.10N0.90-0.93spheres for TRISO coated fuel particles J Nucl Mater 448(1–3):399–403CrossRef
9.
Zurück zum Zitat Hunt RD, Collins JL (2014) Recommended dispersing conditions for precursor solutions used in the preparation of uranium microspheres with carbon. Ann Nucl Energy 71:1–5CrossRef Hunt RD, Collins JL (2014) Recommended dispersing conditions for precursor solutions used in the preparation of uranium microspheres with carbon. Ann Nucl Energy 71:1–5CrossRef
10.
Zurück zum Zitat Silva CM, Lindemer TB, Voit SR, Hunt RD, Besmann TM, Terrani KA, Snead LL (2014) Characteristics of uranium carbonitride microparticles synthesized using different reaction conditions. J Nucl Mater 454(1-3):405–412CrossRef Silva CM, Lindemer TB, Voit SR, Hunt RD, Besmann TM, Terrani KA, Snead LL (2014) Characteristics of uranium carbonitride microparticles synthesized using different reaction conditions. J Nucl Mater 454(1-3):405–412CrossRef
11.
Zurück zum Zitat Gao Y, Ma JT, Zhao XY, Hao SC, Liu B, Deng CS (2016) The preparation of the ZrO2-ZrC ceramic microspheres by the internal gelation process with the sucrose as carbon source. Ceram Int 42(4):4715–4722CrossRef Gao Y, Ma JT, Zhao XY, Hao SC, Liu B, Deng CS (2016) The preparation of the ZrO2-ZrC ceramic microspheres by the internal gelation process with the sucrose as carbon source. Ceram Int 42(4):4715–4722CrossRef
12.
Zurück zum Zitat Jana S, Biswas PK (1997) Chemical behaviour of zirconium oxychloride octahydrate and acetic acid in precursor solution for zirconia film formation on glass. J Sol–Gel Sci Technol 9:227–237 Jana S, Biswas PK (1997) Chemical behaviour of zirconium oxychloride octahydrate and acetic acid in precursor solution for zirconia film formation on glass. J Sol–Gel Sci Technol 9:227–237
13.
Zurück zum Zitat Georgieva I, Danchova N, Gutzov S, Trendafilova N (2012) DFT modeling, UV–Vis and IR spectroscopic study of acetylacetone-modified zirconia sol–gel materials. J Mol Model 18:2409–2422CrossRef Georgieva I, Danchova N, Gutzov S, Trendafilova N (2012) DFT modeling, UV–Vis and IR spectroscopic study of acetylacetone-modified zirconia sol–gel materials. J Mol Model 18:2409–2422CrossRef
14.
Zurück zum Zitat Prasanth VG, Prasad G, Kiran T, Rathore RS, Pathak M, Sathiyanarayanan KI (2015) Synthesis, spectral characterization and crystal structure of a new precursor [(CH3COCHCOCH3)2Zr{C6H4(N=CHC6H4O)2}] for nano-zirconia: an investigation on the wettability of polyvinylidene fluoride–nano-zirconia composite material. J Sol–Gel Sci Technol 76:195–203CrossRef Prasanth VG, Prasad G, Kiran T, Rathore RS, Pathak M, Sathiyanarayanan KI (2015) Synthesis, spectral characterization and crystal structure of a new precursor [(CH3COCHCOCH3)2Zr{C6H4(N=CHC6H4O)2}] for nano-zirconia: an investigation on the wettability of polyvinylidene fluoride–nano-zirconia composite material. J Sol–Gel Sci Technol 76:195–203CrossRef
15.
Zurück zum Zitat Li JJ, Jiao XL, Chen DR (2007) Preparation of Y-TZP ceramic fibers by electrolysis-sol-gel method. J Mater Sci 42:5562–5569CrossRef Li JJ, Jiao XL, Chen DR (2007) Preparation of Y-TZP ceramic fibers by electrolysis-sol-gel method. J Mater Sci 42:5562–5569CrossRef
16.
Zurück zum Zitat Suciu C, Hoffmann AC, Vik A, Goga F (2008) Effect of calcination conditions and precursor proportions on the properties of YSZ nanoparticles obtained by modified sol–gel route. Chem Eng J 138:608–615CrossRef Suciu C, Hoffmann AC, Vik A, Goga F (2008) Effect of calcination conditions and precursor proportions on the properties of YSZ nanoparticles obtained by modified sol–gel route. Chem Eng J 138:608–615CrossRef
17.
Zurück zum Zitat Bose S, Wu Y (2005) Synthesis of Al2O3–CeO2 mixed oxide nano-powders. J Am Ceram Soc 88:1999–2002CrossRef Bose S, Wu Y (2005) Synthesis of Al2O3–CeO2 mixed oxide nano-powders. J Am Ceram Soc 88:1999–2002CrossRef
18.
Zurück zum Zitat Gao Y, Ma JT, Zhao XY, Hao SC, Deng CS, Liu B (2015) An improved internal gelation process for preparing ZrO2 ceramic microspheres without cooling the precursor solution. J Am Ceram Soc 98(9):2732–2737CrossRef Gao Y, Ma JT, Zhao XY, Hao SC, Deng CS, Liu B (2015) An improved internal gelation process for preparing ZrO2 ceramic microspheres without cooling the precursor solution. J Am Ceram Soc 98(9):2732–2737CrossRef
19.
Zurück zum Zitat Couland M, Fourcaudot S, JovaniAbril R, Fernandez-Carretero A, Somers J (2012) Novel production route of yttria-stabilized zirconia fuel kernels and pellets for nuclear fuel applications. J Am Ceram Soc 95(1):133–137CrossRef Couland M, Fourcaudot S, JovaniAbril R, Fernandez-Carretero A, Somers J (2012) Novel production route of yttria-stabilized zirconia fuel kernels and pellets for nuclear fuel applications. J Am Ceram Soc 95(1):133–137CrossRef
20.
Zurück zum Zitat Hunt RD, Montgomerya FC, Collins JL (2010) Treatment techniques to prevent cracking of amorphous microspheres made by the internal gelation process. J Nucl Mater 405(2):160–164CrossRef Hunt RD, Montgomerya FC, Collins JL (2010) Treatment techniques to prevent cracking of amorphous microspheres made by the internal gelation process. J Nucl Mater 405(2):160–164CrossRef
21.
Zurück zum Zitat Chlistunoff J, Ziegler KJ, Lasdon L, Johnston KP (1999) Nitric/Nitrous acid equilibria in supercritical water. J Phys Chem A 103:1678–1688CrossRef Chlistunoff J, Ziegler KJ, Lasdon L, Johnston KP (1999) Nitric/Nitrous acid equilibria in supercritical water. J Phys Chem A 103:1678–1688CrossRef
22.
Zurück zum Zitat Sondhi A, Morandi C, Reidy RF, Scharf TW (2013) Theoretical and experimental investigations on the mechanism of carbothermal reduction of zirconia. Ceram Int 39:4489–4497CrossRef Sondhi A, Morandi C, Reidy RF, Scharf TW (2013) Theoretical and experimental investigations on the mechanism of carbothermal reduction of zirconia. Ceram Int 39:4489–4497CrossRef
23.
Zurück zum Zitat David J, Trolliard G, Gendre M, Maître A (2013) TEM study of the reaction mechanisms involved in the carbothermal reduction of zirconia. J Eur Ceram Soc 33:165–179CrossRef David J, Trolliard G, Gendre M, Maître A (2013) TEM study of the reaction mechanisms involved in the carbothermal reduction of zirconia. J Eur Ceram Soc 33:165–179CrossRef
24.
Zurück zum Zitat Gendre M, Maître A, Trolliard G (2011) Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties. J Eur Ceram Soc 31(13):2377–2385CrossRef Gendre M, Maître A, Trolliard G (2011) Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties. J Eur Ceram Soc 31(13):2377–2385CrossRef
25.
Zurück zum Zitat Morant C, Sanz JM, Galán L, Soriano L, Rueda F (1989) An XPS study of the interaction of oxygen with zirconium. Surf Sci 218:331–345CrossRef Morant C, Sanz JM, Galán L, Soriano L, Rueda F (1989) An XPS study of the interaction of oxygen with zirconium. Surf Sci 218:331–345CrossRef
26.
Zurück zum Zitat Matsuoka M, Isotani S, Sucasaire W, Kuratani N, Ogata K (2008) X-ray photoelectron spectroscopy analysis of zirconium nitride-like films prepared on Si (100) substrates by ion beam assisted deposition. Surf Coat Technol 202:3129–3135CrossRef Matsuoka M, Isotani S, Sucasaire W, Kuratani N, Ogata K (2008) X-ray photoelectron spectroscopy analysis of zirconium nitride-like films prepared on Si (100) substrates by ion beam assisted deposition. Surf Coat Technol 202:3129–3135CrossRef
27.
Zurück zum Zitat Chu AM, Qin ML, Rafi-ud-din, Zhang L, Lu HF, Jia BR, Qu XH (2013) Carbothermal synthesis of ZrC powders using a combustion synthesis precursor. Int J Refract Met Hard Mater 36:204–210CrossRef Chu AM, Qin ML, Rafi-ud-din, Zhang L, Lu HF, Jia BR, Qu XH (2013) Carbothermal synthesis of ZrC powders using a combustion synthesis precursor. Int J Refract Met Hard Mater 36:204–210CrossRef
28.
Zurück zum Zitat Steiner SA, Baumann TF, Bayer BC (2009) Nanoscale zirconia as a nonmetallic catalyst for graphitization of carbon and growth of single and multiwall carbon nanotubes. J Am Chem Soc 131:12144–12154CrossRef Steiner SA, Baumann TF, Bayer BC (2009) Nanoscale zirconia as a nonmetallic catalyst for graphitization of carbon and growth of single and multiwall carbon nanotubes. J Am Chem Soc 131:12144–12154CrossRef
29.
Zurück zum Zitat Won YS, Kim YS, Varanasi VG, Kryliouka O, Andersona TJ, Sirimanne CT, McElwee-White L (2007) Growth of ZrC thin films by aerosol-assisted MOCVD. J Cryst Growth 304:324–332CrossRef Won YS, Kim YS, Varanasi VG, Kryliouka O, Andersona TJ, Sirimanne CT, McElwee-White L (2007) Growth of ZrC thin films by aerosol-assisted MOCVD. J Cryst Growth 304:324–332CrossRef
30.
Zurück zum Zitat Zhao HS, Liu B, Zhang KH, Tang CH (2012) Microstructure analysis of zirconium carbide layer on pyrocarbon-coated particles prepared by zirconium chloride vapor method. Nucl Eng Des 251:443–448CrossRef Zhao HS, Liu B, Zhang KH, Tang CH (2012) Microstructure analysis of zirconium carbide layer on pyrocarbon-coated particles prepared by zirconium chloride vapor method. Nucl Eng Des 251:443–448CrossRef
31.
Zurück zum Zitat Gao Y, Ma JT, Zhao XY, Hao SC, Liu B, Deng CS (2016) The fabrication of ZrO2-ZrC microspheres by internal gelation and carbothermal reduction process. J Am Ceram Soc 99(4):1184–1191CrossRef Gao Y, Ma JT, Zhao XY, Hao SC, Liu B, Deng CS (2016) The fabrication of ZrO2-ZrC microspheres by internal gelation and carbothermal reduction process. J Am Ceram Soc 99(4):1184–1191CrossRef
Metadaten
Titel
Sol–gel preparation of ZrC–ZrO2 composite microspheres using fructose as a carbon source
verfasst von
Xi Sun
Jingtao Ma
Xiaotong Chen
Ziqiang Li
Changsheng Deng
Bing Liu
Publikationsdatum
10.04.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4653-7

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