Summary
The forms of vibrations and displacements of particles in amorphous structures have been investigated. The particles, moving on highly non-linear amplitude, are responsible for the creation of disordered structures of amorphous bodies. The non-linear oscillators, even if 'few' in concentration, are characterized by unpredictable trajectories in phase space. The non-linear oscillators are fully developed in the liquid state above the crossover temperature T cr and between T cr and T g their number decreases. Under T g they completely disappear. The interconnection between the linear oscillators in blocks plays the most important role in the characteristic time spectra in liquid state. Using the additive properties of elements polarizibilities, the number of acoustical units in individual blocks at T cr is estimated to be about 600 units. The diameter of blocks at T cr was estimated to be about 1.8 nm. Even if the non-linear high amplitude motions disappear at solidification, the remnants of structural irregularity remain and the disordered structure of glass is formed.
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Hlavőček, B., Šestők, J., Koudelka, L. et al. Forms of vibrations and structural changes in liquid state. J Therm Anal Calorim 80, 271–283 (2005). https://doi.org/10.1007/s10973-005-0647-0
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DOI: https://doi.org/10.1007/s10973-005-0647-0