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Structural characteristics of organo-modified bentonites of different origin

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Abstract

Organobentonites were synthesized by treating Na-bentonites (Wyoming and Reşadiye) with cetylpyridinium chloride (CPC) using ion exchange method. The difference in the basal spacing by 0.65 Å and a higher mass loss by 13.32% of organobentonite (Wyoming) in the temperature range 200–550°C comparing with that of organobentonite (Reşadiye) were in conformity with the CEC values of organobentonites. The HOH stretching and bending peaks of bentonites became sharper following the treatment with the organo-cation. The intensity decrease of the Al–OH band for organobentonite (Reşadiye) and in particular, the significantly higher amount of m-cresol retained by the organobentonite of lower CEC than that by the organobentonite (Wyoming) indicate the influence of the CP cation on the adsorption process.

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References

  1. CG Olson ML Thompson MA Wilson et al. (1993) Phyllosilicates, Handbook of Soil Science CRC Press New York F80–124

    Google Scholar 

  2. TJ Pinnavia (1983) Science 220 365 Occurrence Handle10.1126/science.220.4595.365

    Article  Google Scholar 

  3. G Rytwo R Huterer-Harari S Dultz Y Gonen (2006) J. Therm. Anal. Cal. 84 225 Occurrence Handle10.1007/s10973-005-7187-5 Occurrence Handle1:CAS:528:DC%2BD28XjsVOnu70%3D

    Article  CAS  Google Scholar 

  4. WN Delgass GL Haller R Kellerman JH Lunsford et al. (1979) Spectroscopy in Heterogeneous Catalysis Academic Press New York 1

    Google Scholar 

  5. F Bergaya G Lagaly (2001) Appl. Clay Sci. 19 1 Occurrence Handle10.1016/S0169-1317(01)00063-1 Occurrence Handle1:CAS:528:DC%2BD3MXlvVCrur8%3D

    Article  CAS  Google Scholar 

  6. OR Pal AK Vanjara (2001) Sep. Purif. Technol. 24 167 Occurrence Handle10.1016/S1383-5866(00)00226-4 Occurrence Handle1:CAS:528:DC%2BD3MXmtFaqsbY%3D

    Article  CAS  Google Scholar 

  7. L Yuncong G Gupta (1994) Chemosphere 28 627 Occurrence Handle10.1016/0045-6535(94)90304-2

    Article  Google Scholar 

  8. J Barrault C Bouchoule K Echachoui N Frini-Srasra M Trabelsi F Bergaya (1998) Appl. Catal. B: Environ. 15 269 Occurrence Handle10.1016/S0926-3373(97)00054-4 Occurrence Handle1:CAS:528:DyaK2sXnvVeisb4%3D

    Article  CAS  Google Scholar 

  9. G Sheng SA Boyd (1998) Clays Clay Miner. 46 10 Occurrence Handle10.1346/CCMN.1998.0460102 Occurrence Handle1:CAS:528:DyaK1cXitFaltbs%3D

    Article  CAS  Google Scholar 

  10. AV Faridi S Guggenheim (1999) Clays Clay Miner. 47 338 Occurrence Handle10.1346/CCMN.1999.0470310

    Article  Google Scholar 

  11. A Gultek MG Icduygu T Seckin (2004) Mater. Sci. Eng. 107 166 Occurrence Handle10.1016/j.mseb.2003.11.001

    Article  Google Scholar 

  12. Y Sugahara S Satokawa K Yoshioka C Kato (1989) Clays Clay Miner. 37 143 Occurrence Handle10.1346/CCMN.1989.0370205 Occurrence Handle1:CAS:528:DyaL1MXhslKrs7c%3D

    Article  CAS  Google Scholar 

  13. H Favre G Lagaly (1991) Clay Miner. 26 19 Occurrence Handle10.1180/claymin.1991.026.1.03 Occurrence Handle1:CAS:528:DyaK3MXisFSit74%3D

    Article  CAS  Google Scholar 

  14. S Gitipour MT Bowers A Bodocsi (1997) J. Colloid Interface Sci. 196 191 Occurrence Handle10.1006/jcis.1997.5063 Occurrence Handle1:CAS:528:DyaK1cXhtVOgsrk%3D

    Article  CAS  Google Scholar 

  15. BS Krishna DSR Murty BSJ Prakash (2000) J. Colloid Interface Sci. 229 230 Occurrence Handle10.1006/jcis.2000.7015 Occurrence Handle1:CAS:528:DC%2BD3cXls1WqtLo%3D

    Article  CAS  Google Scholar 

  16. RS Juang SH Lin KH Tsao (2002) J. Colloid Interface Sci. 254 234 Occurrence Handle10.1006/jcis.2002.8629 Occurrence Handle1:CAS:528:DC%2BD38XotlWms7w%3D

    Article  CAS  Google Scholar 

  17. SY Lee WJ Cho KJ Kim JH Ahn M Lee (2005) J. Colloid Interface Sci. 284 667 Occurrence Handle10.1016/j.jcis.2004.10.070 Occurrence Handle1:CAS:528:DC%2BD2MXisVWktr8%3D

    Article  CAS  Google Scholar 

  18. G Chen B Han H Yan (1998) J. Colloid Interface Sci. 201 158 Occurrence Handle10.1006/jcis.1998.5408 Occurrence Handle1:CAS:528:DyaK1cXjt1ekt74%3D

    Article  CAS  Google Scholar 

  19. A Alemdar O Atıcı N Gungor (2000) Mater. Lett. 43 57 Occurrence Handle10.1016/S0167-577X(99)00230-X Occurrence Handle1:CAS:528:DC%2BD3cXhslSqtb4%3D

    Article  CAS  Google Scholar 

  20. SG Starodoubtsev AA Ryabova AR Khokhlov G Allegra A Famulari SV Meille (2003) Langmuir 19 10739 Occurrence Handle10.1021/la0356248 Occurrence Handle1:CAS:528:DC%2BD3sXovVShsbw%3D

    Article  CAS  Google Scholar 

  21. Y Imai S Nishimura Y Inukai H Tateyama (2003) Clays Clay Miner. 51 162 Occurrence Handle10.1346/CCMN.2003.0510205 Occurrence Handle1:CAS:528:DC%2BD3sXjtlyiu7o%3D

    Article  CAS  Google Scholar 

  22. H Hongping D Zhe Z Jianxi Y Pen X Yunfei Y Dan FL Ray (2005) Clays Clay Miner. 53 287 Occurrence Handle10.1346/CCMN.2005.0530308

    Article  Google Scholar 

  23. SIDS Initial Assessment Report for SIAM16, Paris, France, 2003, 2-377.

  24. RK Taylor (1985) J. Chem.Technol. Biotechnol. 35 A 195

    Google Scholar 

  25. M Pospisil P Capkova D Merinska Z Malac J Simonik (2001) J. Colloid Interface Sci. 236 127 Occurrence Handle10.1006/jcis.2000.7360 Occurrence Handle1:CAS:528:DC%2BD3MXhslyisrs%3D

    Article  CAS  Google Scholar 

  26. RW Grimshaw et al. (1971) The Chemistry and Physics of Clays and Allied Ceramic Materials Ernest Benn Limited London Chapter XIV

    Google Scholar 

  27. AR Mermut G Lagaly (2001) Clays Clay Miner. 49 393 Occurrence Handle10.1346/CCMN.2001.0490506 Occurrence Handle1:CAS:528:DC%2BD3MXotFWht7g%3D

    Article  CAS  Google Scholar 

  28. S Yariv (2004) Appl. Clay Sci. 24 225 Occurrence Handle10.1016/j.clay.2003.04.002 Occurrence Handle1:CAS:528:DC%2BD2cXmtlKlsQ%3D%3D

    Article  CAS  Google Scholar 

  29. M Bora JN Ganguli DK Dutta (2000) Thermochim. Acta. 346 169 Occurrence Handle10.1016/S0040-6031(99)00410-4 Occurrence Handle1:CAS:528:DC%2BD3cXhslSku7k%3D

    Article  CAS  Google Scholar 

  30. Z Yermiyahu A Landau A Zaban I Labides S Yariv (2003) J. Therm. Anal. Cal. 72 431 Occurrence Handle10.1023/A:1024596726087 Occurrence Handle1:CAS:528:DC%2BD3sXltVWiu7c%3D

    Article  CAS  Google Scholar 

  31. A Tabak B Afsin (2001) Adsorp. Sci. Technol. 19 673 Occurrence Handle10.1260/0263617011494484

    Article  Google Scholar 

  32. J Madejova (2003) Vib. Spectrosc. 31 1 Occurrence Handle10.1016/S0924-2031(02)00065-6 Occurrence Handle1:CAS:528:DC%2BD38XpsFeisbw%3D

    Article  CAS  Google Scholar 

  33. A Tabak B Afsin SF Aygun H Icbudak (2005) J. Therm. Anal. Cal. 81 311 Occurrence Handle10.1007/s10973-005-0784-5 Occurrence Handle1:CAS:528:DC%2BD2MXnslyru7c%3D

    Article  CAS  Google Scholar 

  34. T Yamagishi R Takahashi D Nagatani G Konishi Y Nakamoto (2003) Soc. Polym. Sci. Jpn. 60 192 Occurrence Handle1:CAS:528:DC%2BD3sXjsF2it7Y%3D

    CAS  Google Scholar 

  35. KR Srinivasan HS Fogler (1990) Clays Clay Miner. 38 287 Occurrence Handle10.1346/CCMN.1990.0380307 Occurrence Handle1:CAS:528:DyaK3cXkt1yksbw%3D

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Rize University, Rize, Turkey, 53100

    A. Tabak

  2. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, Kurupelit, Samsun, Turkey, 55139

    B. Afsin, S. F. Aygun & E. Koksal

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  1. A. Tabak
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  2. B. Afsin
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  3. S. F. Aygun
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  4. E. Koksal
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Correspondence to A. Tabak.

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Tabak, A., Afsin, B., Aygun, S.F. et al. Structural characteristics of organo-modified bentonites of different origin. J Therm Anal Calorim 87, 377–382 (2007). https://doi.org/10.1007/s10973-006-7886-6

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