Skip to main content
SpringerLink
Log in

Thermal analysis of some polynuclear coordination compounds as precursors of iron garnets (M3Fe5O12, M=Y3+ or Er3+)

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The thermal behaviour of four coordination compounds (NH4)6[Y3Fe5(C4O5H4)6(C4O5H3)6]·12H2O, (NH4)6[Y3Fe5(C6O7H10)6(C6O7H9)6]·8H2O, (NH4)6[Er3Fe5(C4O5H4)6(C4O5H3)6]·10H2O and (NH4)6[Er3Fe5(C4O6H4)6(C4O6H3)6]·22H2O has been studied to evaluate their suitability for garnet synthesis. The thermal decomposition and the phase composition of the resulted decomposition compounds are influenced by the nature of metallic cations (yttrium-iron or erbium-iron) and ligand anions (malate or gluconate).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. Carp and E. Segal, Rev. Roum. Chim., 39 (1994) 1123.

    CAS  Google Scholar 

  2. M. Brezeanu, L. Patron and M. Andruh, Polynuclear Coordination Compounds and their Application, Ed. Academiei 1986.

  3. I. Mindru, L. Patron and M. Brezeanu, Roum. Chem. Quart. Rev., 4 (1996) 167.

    CAS  Google Scholar 

  4. P. E. Rush, J. D. Oliver, G. D. Simpson and G. O. Carlisle, J. Inorg. Nucl. Chem., 37 (1975) 1393.

    Article  CAS  Google Scholar 

  5. S. Kirschner and A. Kiesling, J. Am. Chem. Soc., 20 (1960) 4174.

    Article  Google Scholar 

  6. N. Dennis Chasteen and R. Linn Belford, Inorg. Chem., 9 (1970) 169.

    Article  Google Scholar 

  7. I. Valiuna and K. P. Pribylor, Russ. J. Inorg. Chem., 36 (1991) 379.

    Google Scholar 

  8. B. S. Randhawa and K. J. Sweety, J. Therm. Anal. Cal., 65 (2001) 829.

    Article  CAS  Google Scholar 

  9. S. Sarmah and N. N. Dass, J. Thermal Anal., 54 (1988) 913.

    Google Scholar 

  10. N. Deb, J. Therm. Anal. Cal., 78 (2004) 237.

    Article  Google Scholar 

  11. N. N. Mallikarjuna, A. Lagashetty and A. Venkataraman, J. Therm. Anal. Cal., 74 (2003) 819.

    Article  CAS  Google Scholar 

  12. V. Logvinenko, L. Yudanova, N. Yudanov and G. Chekhova, J. Therm. Anal. Cal., 74 (2003) 395.

    Article  CAS  Google Scholar 

  13. D. G. Karraker, Inorg. Chem., 6 (1967) 1863.

    Article  CAS  Google Scholar 

  14. D. G. Karraker, Inorg. Chem., 7 (1967) 473.

    Article  Google Scholar 

  15. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Ed., J. Wiley & Sons, 1986.

  16. L. Patron, O. Carp, I. Mindru, G. Marinescu, N. Stanica and I. Balint, J. Serb. Chem. Soc., 70 (2005) 1049.

    Article  CAS  Google Scholar 

  17. P. Baraldi, Spectrochim. Acta, 38 (1982) 51.

    Article  Google Scholar 

  18. O. Carp, L. Patron, I. Mindru, G. Marinescu, L. Diamandescu and A. Banuta, J. Therm. Anal. Cal., 74 (2003) 789.

    Article  CAS  Google Scholar 

  19. O. Carp, L. Patron, E. Segal, R. Barjega and M. Brezeanu, J. Therm. Anal. Cal., 56 (1999) 513.

    Article  CAS  Google Scholar 

  20. I. Mindru, L. Patron, O. Carp, G. Marinescu, M. Pascu, G. Pascu and L. Diamandescu, Rev. Roum. Chim., 49 (2004) 235.

    CAS  Google Scholar 

  21. M. A. Mohamed, A. K. Galwey and S. Halawy, Thermochim. Acta, 323 (1998) 27.

    Article  CAS  Google Scholar 

  22. A. C. Tass, P. J. Majewski and F. Aldinger, J. Am. Ceram. Soc., 83 (2000) 2954.

    Article  Google Scholar 

  23. A. M. Hofmeister and K. R. Campbell, J. Appl. Phys., 72 (1992) 638.

    Article  CAS  Google Scholar 

  24. M. Ristic, I. Nowik, S. Popovic, I. Feluer and S. Music, Mater. Lett., 57 (2003) 2584.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. ‘Ilie Murgulescu’ Institute of Physical Chemistry, Spl. Independentei 202, sect.6, 060021, Bucharest, Romania

    Luminita Patron, Oana Carp, I. Mindru & G. Marinescu

  2. Solid State Chemistry, University of Augsburg, Universitätsstrasse 1, 86159, Augsburg, Germany

    J. Hanss & A. Reller

Authors
  1. Luminita Patron
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Oana Carp
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. Mindru
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Marinescu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. Hanss
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Reller
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Oana Carp.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Patron, L., Carp, O., Mindru, I. et al. Thermal analysis of some polynuclear coordination compounds as precursors of iron garnets (M3Fe5O12, M=Y3+ or Er3+). J Therm Anal Calorim 92, 307–312 (2008). https://doi.org/10.1007/s10973-007-8839-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-007-8839-4

Keywords

Search

Navigation