Skip to main content
Log in

Thermal properties of poly(lactic acid)/organo-montmorillonite nanocomposites

  • Regular Papers
  • Organics/Polymers
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Poly(lactic acid)/organo-montmorillonite nanocomposites were prepared by melt intercalation technique. Maleic anhydride-grafted ethylene propylene rubber (EPMgMA) was added into the PLA/OMMT in order to improve the compatibility and toughness of the nanocomposites. The samples were prepared by single screw extrusion followed by compression molding. The effect of OMMT and EPMgMA on the thermal properties of PLA was studied. The thermal properties of the PLA/OMMT nanocomposites have been investigated by using differential scanning calorimeter (DSC) and thermo-gravimetry analyzer (TG). The melting temperature (T m), glass transition temperature (T g), crystallization temperature (T c), degree of crystallinity (χc), and thermal stability of the PLA/OMMT nanocomposites have been studied. It was found that the thermal properties of PLA were greatly influenced by the addition of OMMT and EPMgMA.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T. M. Wu and C. Y. Wu, Polym. Degrad. Stab., 91 (2006) 2198.

    Article  CAS  Google Scholar 

  2. M. A. Paul, M. Alexandre, P. Degée, C. Henrist, A. Rulmont and P. Dubois, Polymer, 44 (2003) 443.

    Article  CAS  Google Scholar 

  3. H. J. Choi, J. W. Kim and M. S. Jhon, Polymer Clay Nanocomposites. ‘Encyclopedia of Chemical Processing’, S. Lee, Ed., Taylor and Francis Group, UK 2006, p. 2301.

    Google Scholar 

  4. L. A. Utracki, Clay-containing Polymeric Nanocomposites, Rapra Teachnology Ltd., UK 2004, p. 1.

    Google Scholar 

  5. S. Sinha Ray and M. Bousmina, Progr. Mater. Sci., 50 (2005) 962.

    Article  CAS  Google Scholar 

  6. J. L. Feijoo, L. Cabedo, E. Gimenez, J. M. Lagaron and J. J. Saura, J. Mater. Sci., 40 (2005) 1785.

    Article  CAS  Google Scholar 

  7. C. Peter, L. Baron, Z. Wang and T. J. Pinnavaia, Appl. Clay Sci., 15 (1999) 11.

    Article  Google Scholar 

  8. Z. Q. Shen, G. P. Simon and Y. B. Cheng, Polymer, 45 (2002) 4251.

    Article  Google Scholar 

  9. M. Okamoto, Biodegradable Polymer/Layered Silicate Nanocomposites: A Review. ‘Chapter 8 — Handbook of Biodegradable Polymeric Materials and their Applications’, S. Mallapragada and B. Narasimhan, Eds, American Scientific Publishers, USA 2005, p. 1.

    Google Scholar 

  10. C. Thellen, C. Orroth, D. Froio, D. Ziegler, J. Lucciarini, R. Farrell, N. A. D’souza and J. A. Ratto, Polymer, 46 (2005). 11716.

    Article  CAS  Google Scholar 

  11. L. Petersson and K. Oksman, Compos. Sci. Technol., 66 (2006) 2187.

    Article  CAS  Google Scholar 

  12. J. H. Chang, Y. U. An, D. Cho and E. P. Giannelis, Polymer, 44 (2003) 3715.

    Article  CAS  Google Scholar 

  13. T. H. Lee, F. Y. C. Boey and K. A. Khor, Compos. Sci. Technol., 53 (1995) 259.

    Article  CAS  Google Scholar 

  14. H. Wang, X. Z. Sun and P. Seib, J. Appl. Polym. Sci., 82 (2001) 1761.

    Article  CAS  Google Scholar 

  15. O. Martin and L. Avérous, Polymer, 42 (2001) 6209.

    Article  CAS  Google Scholar 

  16. M. L. Di Lorenzo, Eur. Polym. J., 41 (2005) 569.

    Article  Google Scholar 

  17. G. H. Yew, A. M. Mohd Yusof, Z. A. Mohd Ishak and U. S. Ishiaku, Polym. Degrad. Stab., 90 (2005) 488.

    Article  CAS  Google Scholar 

  18. J. Scheirs, Compositional and Failure Analysis of Polymers: A Practical Approach, John Wiley and Sons, New York 2000, p. 1.

    Google Scholar 

  19. J. H. Lee, T. G. Park, S. H. Park, D. S. Lee, Y. K. Lee, S. C. Yoon and J. D. Nam, Biomaterial, 24 (2003) 2773.

    Article  CAS  Google Scholar 

  20. M. Day, A. Victoria Nawaby and X. Liao, J. Therm. Anal. Cal., 86 (2006) 623.

    Article  CAS  Google Scholar 

  21. D. Lewitus, S. McCarthy, A. Ophir and S. Kenig, J. Polym. Environ., 14 (2006) 171.

    Article  CAS  Google Scholar 

  22. N. R. Choudhury, T. K. Chaki and A. K. Bhowmick, Thermochim. Acta, 176 (1991) 149.

    Article  CAS  Google Scholar 

  23. S. Sinha Ray and M. Okamoto, Progr. Polym. Sci., 28 (2003) 1539.

    Article  Google Scholar 

  24. D. Wu, L. Wu, L. F. Wu and M. Zhang, Polym. Degrad. Stab., 91 (2006) 1.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to W. S. Chow.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chow, W.S., Lok, S.K. Thermal properties of poly(lactic acid)/organo-montmorillonite nanocomposites. J Therm Anal Calorim 95, 627–632 (2009). https://doi.org/10.1007/s10973-007-8975-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-007-8975-x

Keywords

Navigation