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DTA and FTIR of 70TeO2–(25 − x)MnO2–xV2O5–5Fe2O3 tellurite glass systems

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Abstract

A series of quaternary tellurite glasses in the form of 70TeO2–(25 − x)MnO2–xV2O5–Fe2O3 where (0 ≤ x ≤ 25 mol%) have been prepared by the conventional melt quenching technique. Differential thermal analysis (DTA) curves of these glasses have been investigated in the temperature range 300–1093 K and at different heating rates a = (2.5, 5, 10, 20 and 40 K min−1). The glass transition temperature (T g), the crystallization temperature (T P), the glass stability (∆T) and the activation energy for crystallization have been measured. The glass transition temperature has been analyzed according to the average cross-link density, and the average stretching force constant is present in the glass. FTIR investigations showed that the absorption bands of different modes of vibration in the manganese tellurite network were shifted toward higher wave number.

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Acknowledgements

The experimental facilities from University of Al-Azhar University, Jeddah University, Menofia University, Port Said University, King Khalid University are gratefully acknowledged.

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Authors and Affiliations

  1. Physics Department, Faculty of Science, Al-Azhar University, P.O. 71452, Assiut, Egypt

    K. A. Aly, Y. B. Saddeek & A. M. Abd Elnaeim

  2. Physics Department, Faculty of Science and Arts Khulais, Jeddah University, Jeddah, Saudi Arabia

    K. A. Aly

  3. Physics Department, Faculty of Science, Menofia University, Shibin El Kom, Egypt

    R. El-Mallawany

  4. Department of Physics, Faculty of Science, Port Said University, Port Said, Egypt

    A. Dahshan

  5. Physics Department, Faculty of Girls, King Khalid University, Abha, Saudi Arabia

    A. Dahshan

Authors
  1. K. A. Aly
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  2. R. El-Mallawany
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  3. Y. B. Saddeek
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  4. A. Dahshan
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  5. A. M. Abd Elnaeim
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Correspondence to Y. B. Saddeek.

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Aly, K.A., El-Mallawany, R., Saddeek, Y.B. et al. DTA and FTIR of 70TeO2–(25 − x)MnO2–xV2O5–5Fe2O3 tellurite glass systems. J Therm Anal Calorim 131, 1857–1865 (2018). https://doi.org/10.1007/s10973-017-6499-6

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  • DOI: https://doi.org/10.1007/s10973-017-6499-6

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