Skip to main content
Log in

Electrochemical Methods for the Evaluation of the Degradation of Structural Steels Intended for Long-Term Operation

  • Published:
Materials Science Aims and scope

The long-term operation of structural steels leads to changes in their state, which affects not only the mechanical or corrosion-mechanical properties of the metal but also its electrochemical characteristics. We study carbon, low-alloy, and stainless steels after their operation from 30 to more than 100 yr. On the one hand, we analyze some regularities of degradation of steels with regard for the conditions of mechanical loading and the action of corrosive media and, on the other hand, we study the electrochemical response to the changes in the state of steels. The obtained results are aimed at the diagnostics of degradation of the mechanical properties of steels with the use of the electrochemical approaches.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

References

  1. H. M. Nykyforchyn, K.-J. Kurzydlowski, and E. Lunarska, “Hydrogen degradation of steels in long-term service conditions” in: S. Shipilov (editor), Environment-Induced Cracking of Materials, Vol. 2: Prediction, Industrial Developments, and Evaluations, Elsevier, Amsterdam (2008), pp. 349–361.

  2. A. Ya. Krasovskii, I. V. Lokhman, and I. V. Orynyak, “Stress-corrosion failures of main pipelines,” Probl. Prochn., 44, No. 2, 23–43 (2012); English translation: Strength Mater., 44, No. 2, 129–143 (2012).

  3. E. I. Kryzhanivs’kyi, R. S. Hrabovs’kyi, and O. M. Mandryk, “Estimation of the serviceability of oil and gas pipelines after long-term operation according to the parameters of their defectiveness,” Fiz.-Khim. Mekh. Mater., 49, No. 1, 105–110 (2013); English translation: Mater. Sci., 49, No. 1, 117–123 (2013).

  4. O. H. Arhypov, V. А. Vorysenko, М. S. Khoma, and О. V. Lyubymova–Zinchenko, Degradation of Steels in Corrosive Media, Residual Life of Equipment, and Corrosion Monitoring [in Ukrainian], Dal’ East-Ukrainian National University, Lugans’k (2016).

  5. V. А. Voloshyn, О. І. Zvirko, and P. Ya. Sydor, “Influence of the compositions of neutral soil media on the corrosion cracking of pipe steel,” Fiz.-Khim. Mekh. Mater., 51, No. 4, 44–47 (2015); English translation: Mater. Sci., 50, No. 5, 671–675 (2015).

  6. O. T. Tsyrulnyk, Z. V. Slobodyan, O. I. Zvirko, M. I. Hredil,’ H. M. Nykyforchyn, and G. Gabetta, “Influence of the operation of Kh52 steel on corrosion processes in a model solution of gas condensate,” Fiz.-Khim. Mekh. Mater., 44, No. 5, 29–37 (2008); English translation: Mater. Sci., 44, No. 5, 619–629 (2008).

  7. V. A. Goltsov, “Fundamentals of hydrogen treatment of materials and its classification,” Int. J. Hydrogen Energy, No. 2-3, 119–124 (1997).

  8. H. M. Nykyforchyn, O. Z. Student, and A. D. Markov, “Abnormal behavior of high-temperature degradation of the weld metal of low-alloy steel welded joints,” Fiz.-Khim. Mekh. Mater., 43, No. 1, 73–79 (2007); English translation: Mater. Sci., 43, No. 1, 77–84 (2007).

  9. O. T. Tsyrul’nyk, “Application of the electrochemical methods in the diagnostics of the engineering state of structural materials,” Fiz.-Khim. Mekh. Mater., 49, No. 4, 103–110 (2013); English translation: Mater. Sci., 49, No. 4, 449–460 (2014).

  10. E. V. Kharchenko, L. K. Polishchuk, and O. I. Zvirko, “Estimation of the in-service degradation of steel shapes for the boom of a clamp-forming machine,” Fiz.-Khim. Mekh. Mater., 49, No. 4, 77–82 (2013); English translation: Mater. Sci., 49, No. 4, 501–507 (2014).

  11. V. Pustovoi, І. Reshchenko, and О. Zvirko, “Electrochemical method of monitoring of the in-service degradation of the mechanical properties of steels of gantry cranes,” Visn. TNTU, 77, No. 1, 79–87 (2015).

    Google Scholar 

  12. L. K. Polishchuk, H. V. Kharchenko, and О. І. Zvirko, “Corrosion-fatigue crack-growth resistance of steel of the boom of a clamp-forming machine,” Fiz.-Khim. Mekh. Mater., 51, No. 2, 77–82 (2015); English translation: Mater. Sci., 51, No. 2, 229–234 (2015).

  13. V. I. Pokhmurs’kyi and М. S. Khoma, Corrosion Fatigue of Metals and Alloys [in Ukrainian], Spolom, Lviv (2008).

  14. V. М. Pustovoi, І. О. Reshchenko, and О. І. Zvirko, “Influence of long-term cyclic deformation on the electrochemical behavior of steels of marine gantry cranes,” Fiz.-Khim. Mekh. Mater., 51, No. 1, 111–115 (2015); English translation: Mater. Sci., 51, No. 1, 125–130 (2015).

  15. T. Tsuru, Ya. Huang, Md. R. Ali, and A. Nishikata, “Hydrogen entry into steel during atmospheric corrosion process,” Corros. Sci., 47, No. 10, 2431–2440 (2005).

    Article  Google Scholar 

  16. H. M. Nykyforchyn, A. O. Kutnyi, O. Z. Student, H. V. Krechkovs’ka, O. I. Zvirko, and I. M. Kurnat, “Structure and properties of the steels of hyperboloid gridshell Shukhov’s towers after long-term operation,” Fiz.-Khim. Mekh. Mater., 49, No. 6, 70–78 (2013); English translation: Mater. Sci., 49, No. 6, 787–795 (2014).

  17. Yu. Tkachuk, P. Rozhahedy, R. Beleznai, and О. Student, “Static crack resistance of the blades of steam turbines,” Visn. TNTU, Special Issue, Part 1, 106–114 (2011).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to О. І. Zvirko.

Additional information

Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 52, No. 4, pp. 126–131, July–August, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zvirko, О.І. Electrochemical Methods for the Evaluation of the Degradation of Structural Steels Intended for Long-Term Operation. Mater Sci 52, 588–594 (2017). https://doi.org/10.1007/s11003-017-9994-9

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11003-017-9994-9

Keywords

Navigation