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Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 10/2011

01.10.2011 | Research Paper

Evolution of the zinc compound nanostructures in zinc acetate single-source solution

verfasst von: Ying Wang, Yinhua Li, Zhengzhi Zhou, Xihong Zu, Yulin Deng

Erschienen in: Journal of Nanoparticle Research | Ausgabe 10/2011

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Abstract

A series of nanostructured zinc compounds with different nanostructures such as nanobelts, flake-like, flower-like, and twinning crystals was synthesized using zinc acetate (Zn(Ac)2) as a single-source. The evolution of the zinc compounds from layered basic zinc acetate (LBZA) to bilayered basic zinc acetate (BLBZA) and twinned ZnO nano/microcrystal was studied. The low-angle X-ray diffraction spectra indicate the layered spacing is 1.34 and 2.1 nm for LBZA and BLBZA, respectively. The Fourier transform infrared (FTIR) spectra results confirmed that the bonding force of acetate anion with zinc cations decreases with the phase transformation from Zn(Ac)2 to BLBZA, and finally to LBZA. The OH− groups gradually replaced the acetate groups coordinated to the matrix zinc cation, and the acetate groups were released completely. Finally, the Zn(OH)2 and ZnO were formed at high temperature. The conversion process from Zn(Ac)2 to ZnO with release of acetate anions can be described as Zn(Ac)2 → BLBZA → LBZA → Zn(OH)2 → ZnO.
Vorheriger Artikel Synthesis and characterization of polyhedral and quasi-sphere non-polyhedral Pt nanoparticles: effects of their various surface morphologies and sizes on electrocatalytic activity for fuel cell applications
Nächster Artikel Correlation between structural and giant magnetoresistance properties of Fe–Ag nanogranular films

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Metadaten
Titel
Evolution of the zinc compound nanostructures in zinc acetate single-source solution
verfasst von
Ying Wang
Yinhua Li
Zhengzhi Zhou
Xihong Zu
Yulin Deng
Publikationsdatum
01.10.2011
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 10/2011
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-011-0504-y

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