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Journal of Nanoparticle Research

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01.11.2013 | Research Paper

Adsorption behavior and mechanism of methyl blue on zinc oxide nanoparticles

verfasst von: Fan Zhang, Jing Lan, Ye Yang, Tiefeng Wei, Ruiqin Tan, Weijie Song

Erschienen in: Journal of Nanoparticle Research | Ausgabe 11/2013

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Abstract

The adsorption behavior and mechanism of methyl blue (MB) on zinc oxide (ZnO) nanoparticles were investigated in this work. The adsorption capacity of MB on the ZnO nanoparticles reached 10.70 ± 0.80 mmol/g, which was the highest among today’s adsorbents for removing MB. The adsorption process was independent of pH and temperature in the experimental range. The adsorption kinetics was elucidated by the pseudo-second-order model and exhibited 2-stage intra-particle diffusion model. The adsorption isotherm fitted well with the Temkin model. The calculated parameter from Temkin model indicated the adsorption process was spontaneous with a uniform distribution of binding energies. The mechanism studies by XPS analysis confirmed that ionic bonding between Zn²⁺ in Zn(OH)⁺ and sulfonic groups of MB was the major interaction between MB and ZnO nanoparticles. The adsorption for MB by ZnO nanoparticles was selective. This work indicates that ZnO nanoparticles are promising adsorbents for removal of MB from waste water.

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Titel: Adsorption behavior and mechanism of methyl blue on zinc oxide nanoparticles
verfasst von: Fan Zhang
Jing Lan
Ye Yang
Tiefeng Wei
Ruiqin Tan
Weijie Song
Publikationsdatum: 01.11.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 11/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-2034-2

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