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Steam Oxidation Resistance of Slurry Aluminum and Aluminum/Silicon Coatings on Steel for Ultrasupercritical Steam Turbines

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Abstract

Aluminum and aluminum/silicon coatings were deposited on ferritic–martensitic P92 and austenitic IN-800HT steels in a single-step process from an environmentally friendly slurry. A B2-FeAl phase formed on both the Al and the Al/Si coatings formed on P92. On IN-800HT, both Al and Al/Si grew a B2-(Fe,Ni)Al matrix. An additional ζ2-(Fe,Ni)3Al10 phase was also detected in the Al/Si coatings. The behavior of these coatings was then studied in steam at 650 °C and 1 bar for 2000 h. The uncoated P92 displayed a significant mass gain compared to the coated ones. The coatings also reduced the mass gains of the uncoated IN-800HT but to a lesser extent than in P92. The reduction in kinetics of the coated specimens was attributed to the major formation of a protective α-Al2O3 oxide.

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References

  1. T.-U. Kern, M. Staubli and B. Scarlin, ISIJ International 42, 1515 (2002).

    Article  Google Scholar 

  2. J. M. Beér, Progress in Energy and Combustion Science 33, 107 (2007).

    Article  Google Scholar 

  3. J. C. Vaillant, B. Vandenberghe, B. Hahn, H. Heuser and C. Jochum, International Journal of Pressure Vessels and Piping 85, 38 (2008).

    Article  Google Scholar 

  4. G. R. Holcomb, M. Ziomek-Moroz, DOE/NETL-IR-2006-116 (DOE, Washington, DC, 2006).

  5. B. Wang, Z. Liu, S. Cheng, C. Liu and J. Wang, Journal of iron and steel research 21, 765 (2014).

    Article  Google Scholar 

  6. V. T. Ha and W. S. Jun, Materials Science & Engineering A 558, 103 (2012).

    Article  Google Scholar 

  7. J. Gan, J. I. Cole, T. R. Allen, S. Shutthanandan and S. Thevuthasan, Journal of Nuclear Materials 351, 223 (2006).

    Article  Google Scholar 

  8. L. Y. Xu, P. Zhu, H. Y. Jing, S. X. Zhong and Y. D. Han, Engineering Failure Analysis 31, 375 (2013).

    Article  Google Scholar 

  9. E. J. Opila, N. S. Jacobson, D. L. Myers and E. H. Copland, JOM 58, 22 (2006).

    Article  Google Scholar 

  10. A. Aguero, R. Muelas, A. Pastor and S. Osgerby, Surface and Coatings Technology 200, 1219 (2005).

    Article  Google Scholar 

  11. F. Pedraza, M. Proy, C. Boulesteix, P. Krukovskyi and M. Metel, Materials and Corrosion (2016). doi:10.10002/maco.201508758.

    Google Scholar 

  12. A. Aguero, R. Muelas, M. Guitierrez, R. Van Vulpen, S. Osgerby and J. P. Banks, Surface and Coatings Technology 201, 6253 (2007).

    Article  Google Scholar 

  13. S. Dryepondt and B. A. Pint, Surface & Coatings Technology 205, 1195 (2010).

    Article  Google Scholar 

  14. X. Montero, M. C. Galetz and M. Schütze, Oxidation of Metals 80, 635 (2013).

    Article  Google Scholar 

  15. F. J. Perez, M. P. Hierro, J. A. Trilleros, M. C. Carpintero, L. Sanchez and F. J. Bolivar, Materials Chemistry and Physics 97, 50 (2006).

    Article  Google Scholar 

  16. J. M. Brossard, M. P. Hierro, J. A. Trilleros, M. C. Carpintero, L. Sanchez, F. J. Bolivar and F. J. Perez, Surface and Coatings Technology 201, 5743 (2007).

    Article  Google Scholar 

  17. S. Poupard, J. F. Martinez and F. Pedraza, Surface and Coatings Technology 202, 3100 (2008).

    Article  Google Scholar 

  18. ASM Handbook, Alloy Phase Diagrams Vol. 3 (ASM International, Materials Park, Ohio, 1992).

  19. L. Eleno, K. Frisk and A. Schneider, Intermetallics 14, 1276 (2006 ).

    Article  Google Scholar 

  20. A. Aguero, V. Gonzalez, M. Guttierrez, R. Knödler, R. Muelas and S. Straub, Materials and Corrosion 62, 561 (2011).

    Article  Google Scholar 

  21. A. Aguero, M. Hernandez and A. Santaballa, Oxidation of Metals (2012). doi:10.1007/s11085-012-9351-1.

    Google Scholar 

  22. P. Berthod, S. Michon, S. Mathieu, R. Podor, C. Rapin and P. Steinmetz, Materials Science Forum 461–464, 1117 (2004).

    Article  Google Scholar 

  23. T. Sourmail, Materials Science and Technology 17, 1 (2001).

    Article  Google Scholar 

  24. W. E. White and I. Le May, Metallography 5, 333 (1972).

    Article  Google Scholar 

  25. F. J. Pérez, F. Pedraza, M. P. Hierro, J. Balmain and G. Bonnet, Oxidation of Metals 58, 563 (2002).

    Article  Google Scholar 

  26. B. Pieraggi, Oxidation of Metals 27, 177 (1987).

    Article  Google Scholar 

  27. S. Guo, Z. B. Wang and K. Lu, Journal of Materials Science & Technology 31, 1268 (2015).

    Article  Google Scholar 

  28. M. W. Brumm and H. J. Grabke, Corrosion Science 33, 1677 (1992).

    Article  Google Scholar 

  29. W. J. Quadakkers, P. J. Ennis, J. Zurek and M. Michalik, Materials at High Temperature 22, 47 (2005).

    Google Scholar 

  30. J. L. Marulanda, S. I. Castaneda and F. J. Pérez, Oxidation of Metals 84, 429 (2015).

    Article  Google Scholar 

  31. H. Abe, S. M. Hong and Y. Watanabe, Nuclear Engineering and Design 280, 652 (2014).

    Article  Google Scholar 

  32. N. S. Quan and D. J. Young, Oxidation of Metals 25, 107 (1986).

    Article  Google Scholar 

  33. W. J. Quadakkers and J. Zurek, Shreir’s Corrosion 1, 407 (2010).

    Article  Google Scholar 

  34. X. Montero, M. C. Galetz and M. Schütze, Surface and Coatings Technology 236, 465 (2013).

    Article  Google Scholar 

  35. B. Bouchaud, J. Balmain, D. Barrer, T. Delannoye and F. Pedraza, Corrosion Science 68, 176 (2013).

    Article  Google Scholar 

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Acknowledgements

The authors gratefully acknowledge European Union for the funding of FP7 project “POEMA: Production of Coatings for New Efficient and Clean Coal Power Plant Materials” (Grant Agreement No. 310436).

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Authors and Affiliations

  1. Laboratoire des Sciences de l’Ingénieur pour l’Environnement (LaSIE, UMR-CNRS 7356), Université de La Rochelle, Avenue Michel Crépeau, 17042, La Rochelle Cedex 1, France

    Claire Boulesteix, Fernando Pedraza & Manuel Proy

  2. Grupo de Ingeniería de Superficies y Materiales Nanoestructurados, Faculdad de Ciencias Químicas, Universidad Complutense de Madrid, 28040, Madrid, Spain

    Isabel Lasanta, Teresa de Miguel, Andrea Illana & Francisco Javier Pérez

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  1. Claire Boulesteix
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  2. Fernando Pedraza
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  3. Manuel Proy
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  4. Isabel Lasanta
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  5. Teresa de Miguel
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  6. Andrea Illana
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  7. Francisco Javier Pérez
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Correspondence to Claire Boulesteix.

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Boulesteix, C., Pedraza, F., Proy, M. et al. Steam Oxidation Resistance of Slurry Aluminum and Aluminum/Silicon Coatings on Steel for Ultrasupercritical Steam Turbines. Oxid Met 87, 469–479 (2017). https://doi.org/10.1007/s11085-017-9726-4

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  • DOI: https://doi.org/10.1007/s11085-017-9726-4

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