Skip to main content
Log in

Pilot-Scale Aftertreatment Using Nonthermal Plasma Reduction of Adsorbed NOx in Marine Diesel-Engine Exhaust Gas

  • Original Paper
  • Published:
Plasma Chemistry and Plasma Processing Aims and scope Submit manuscript

Abstract

Regulations governing marine diesel engine NOx emissions have recently become more stringent. As it is difficult to fulfill these requirements by combustion improvements alone, effective aftertreatment technologies are needed to achieve efficient NOx reductions. In this study, we develop an effective NOx-reduction aftertreatment system for a marine diesel engine that employs combined nonthermal plasma (NTP) and adsorption. Compared with selective catalytic reduction, the proposed technology offers the advantages of not requiring a urea solution or harmful heavy-metal catalysts and low operating temperatures of less than 150 °C. The NOx reduction comprises repeated adsorption and desorption flow processes using NTP combined with NOx adsorbents made of MnOx–CuO. High concentrations of NOx are treated by NTP after NOx adsorption and desorption, and this aftertreatment system demonstrates excellent energy efficiencies of 161 g(NO2)/kWh, which fulfills the most recent International Maritime Organization emission NOx standards in the Tier II–III regulations for 2016 and requires only 4.3 % of the engine output power.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. Okubo M, Arita N, Kuroki T, Yamamoto T (2008) Total diesel emission control system using ozone injection and plasma desorption. Plasma Chem Plasma Process 28:173–187

    Article  CAS  Google Scholar 

  2. Kuroki T, Ishidate M, Okubo M, Yamamoto T (2010) Charge-to-mass ratio and dendrite structure of diesel particulate matter charged by corona discharge. Carbon 48:184–190

    Article  CAS  Google Scholar 

  3. Cooper BJ, Thoss JE (1989) Role of NO in diesel particulate emission control. SAE paper no. 89040

  4. Kato T, Ibaragi S, Matsuoka K, Imai K, Sato K (2010) Development of diesel particulate filter applying non-thermal plasma technology for onboard diesel generators. J Jpn Inst Marine Eng 45:962–967

    Google Scholar 

  5. Petzold A, Weingartner E, Hasselbach J, Lauer P, Kurok C, Fleischer F (2010) Physical properties, chemical composition, and cloud forming potential of particulate emissions from a marine diesel engine at various load conditions. Environ Sci Technol 44:3800–3805

    Article  CAS  Google Scholar 

  6. Petzold A, Lauer P, Fritsche U, Hasselbach J, Lichtenstern M, Schlager H, Fleischer F (2011) Operation of marine diesel engines on biogenic fuels: modification of emissions and resulting climate effects. Environ Sci Technol 45:10394–10400

    Article  CAS  Google Scholar 

  7. Kuwahara T, Yoshida K, Hanamoto K, Sato K, Kuroki T, Yamamoto T, Okubo M (2012) Continuous regeneration characteristics of ceramics particulate filter in marine diesel engine using nonthermal plasma-induced ozone injection. J Jpn Inst Marine Eng 47:379–384

    Google Scholar 

  8. Kuwahara T, Yoshida K, Hanamoto K, Sato K, Kuroki T, Yamamoto T, Okubo M (2012) Pilot-scale experiments of continuous regeneration of ceramic diesel particulate filter in marine diesel engine using nonthermal plasma-induced radicals. IEEE Trans Ind Appl 48:1649–1656

    Article  Google Scholar 

  9. Kang M, Park ED, Kim JM, Yie JE (2006) Cu–Mn mixed oxides for low temperature NO reduction with NH3. Catal Today 111:236–241

    Article  CAS  Google Scholar 

  10. Marbán G, Antuña R, Fuertes AB (2003) Low-temperature SCR of NOx with NH3 over activated carbon fiber composite-supported metal oxides. Appl Catal B 41:323–338

    Article  Google Scholar 

  11. Miessner H, Francke KP, Rudolph R, Hammer T (2002) NOx removal in excess oxygen by plasma-enhanced selective catalytic reduction. Catal Today 75:325–330

    Article  CAS  Google Scholar 

  12. Koebel M, Elsener M, Kleemann M (2000) Urea-SCR: a promising technique to reduce NOx emissions from automotive diesel engines. Catal Today 59:335–345

    Article  CAS  Google Scholar 

  13. Cha MS, Song YH, Lee JO, Kim SJ (2007) NOx and soot reduction using dielectric barrier discharge and NH3 selective catalytic reduction in diesel exhaust. Int J Plasma Environ Sci Technol 1:28–33

    Google Scholar 

  14. Imai H, Ogawa T, Sugimoto K, Kataoka M, Tanaka Y, Ono T (2005) Comparison of activities in selective catalytic reduction of NOx by C3H8 over Co/MFI, Fe/MFI, and H/MFI zeolite catalysts. Appl Catal B 55:259–265

    Article  CAS  Google Scholar 

  15. Rappé KG, Hoard JW, Aardahl CL, Park PW, Peden CHF (2004) Combination of low and high temperature catalytic materials to obtain broad temperature coverage for plasma-facilitated NOx reduction. Catal Today 89:143–150

    Article  Google Scholar 

  16. Hammer T, Kappes T, Baldauf M (2004) Plasma catalytic hybrid processes: gas discharge initiation and plasma activation of catalytic processes. Catal Today 89:5–14

    Article  CAS  Google Scholar 

  17. Chae JO (2003) Non-thermal plasma for diesel exhaust treatment. J Electrostat 57:251–262

    Article  CAS  Google Scholar 

  18. Tonkyn RG, Barlow SE, Hoard JW (2003) Reduction of NOx in synthetic diesel exhaust via two-step plasma-catalysis treatment. Appl Catal B 40:207–217

    Article  CAS  Google Scholar 

  19. McMillan SA, Broadbelt LJ, Snurr RQ (2003) Effect of local framework heterogeneity on NO adsorption in cobalt–ferrierite. J Catal 219:117–125

    Article  CAS  Google Scholar 

  20. Adelman BJ, Beutel T, Lei GD, Sachtler WMH (1995) Mechanistic cause of hydrocarbon specificity over Cu/ZSM-5 and Co/ZSM-5 catalysts in the selective catalytic reduction of NOx. J Catal 158:327–335

    Article  Google Scholar 

  21. McAdams R, Beech P, Shawcross JT (2008) Low temperature plasma assisted catalytic reduction of NOx in simulated marine diesel exhaust. Plasma Chem Plasma Process 28:159–171

    Article  CAS  Google Scholar 

  22. Hołub M, Kalisiak S, Borkowski T, Myśków J, Brandenburg R (2010) The influence of direct non-thermal plasma treatment on particulate matter (PM) and NOx in the exhaust of marine diesel engines. Pol J Environ Stud 19:1199–1211

    Google Scholar 

  23. Schmidt M, Basner R, Brandenburg R (2013) Hydrocarbon assisted NO oxidation with non-thermal plasma in simulated marine diesel exhaust gases. Plasma Chem Plasma Process 33:323–335

    Article  CAS  Google Scholar 

  24. Yoshida K, Kuroki T, Okubo M (2009) Diesel emission control system using combined process of nonthermal plasma and exhaust gas components’ recirculation. Thin Solid Films 518:987–992

    Article  CAS  Google Scholar 

  25. Kuwahara T, Yoshida K, Kannaka Y, Kuroki T, Okubo M (2011) Improvement of NOx reduction efficiency in diesel emission control using nonthermal plasma combined exhaust gas recirculation process. IEEE Trans Ind Appl 47:2359–2366

    Article  CAS  Google Scholar 

  26. Yoshida K, Okubo M, Yamamoto T (2007) Distinction between nonthermal plasma and thermal desorptions for NOx and CO2. Appl Phys Lett 90:131501

    Article  Google Scholar 

  27. Yoshida K, Okubo M, Kuroki T, Yamamoto T (2008) NOx aftertreatment using thermal desorption and nitrogen nonthermal plasma reduction. IEEE Trans Ind Appl 44:1403–1409

    Article  CAS  Google Scholar 

  28. Okubo M, Inoue M, Kuroki T, Yamamoto T (2005) NOx reduction aftertreatment system using nitrogen nonthermal plasma desorption. IEEE Trans Ind Appl 41:891–899

    Article  CAS  Google Scholar 

  29. Yamamoto T, Yang CL (1998) Plasma desorption and decomposition. In: Proceedings of IEEE-IAS Annual Meeting, Saint Louis MO, October 12–16, pp 1877–1883

  30. Okubo M, Tanioka G, Kuroki T, Yamamoto T (2002) NOx concentration using adsorption and nonthermal plasma desorption. IEEE Trans Ind Appl 38:1196–1203

    Article  CAS  Google Scholar 

  31. Okubo M, Yamamoto T, Kuroki T (2004) Exhaust gas cleaning method and system. Japanese patent pending no. 2003-361010, Oct 21, 2003, PCT Int Patent Pending, PCT/JP2004/1014737

Download references

Acknowledgments

This work was supported by the Regional R&D Resources Utilization Program in the Japan Science and Technology Agency (JST). It is also partly supported by Japan Society for the Promotion of Science (JSPS) KAKENHI Grant Number 24246145 and 249848. The authors would like to thank M. Nishimoto, T. Shinohara, M. Kawai (formerly graduate students at Osaka Prefecture University), S. Tagawa (formerly an undergraduate student at Osaka Prefecture University), S. Shimomura (engineering manager, Daihatsu Diesel MFG. Co. Ltd.), and S. Hosokawa (president, Masuda Research Inc.) for their contributions to the experiments.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Masaaki Okubo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuwahara, T., Yoshida, K., Kuroki, T. et al. Pilot-Scale Aftertreatment Using Nonthermal Plasma Reduction of Adsorbed NOx in Marine Diesel-Engine Exhaust Gas. Plasma Chem Plasma Process 34, 65–81 (2014). https://doi.org/10.1007/s11090-013-9486-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11090-013-9486-0

Keywords

Navigation