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A novel method of the synthesis of molybdovanadophosphoric heteropoly acid solutions

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Abstract

A novel eco-friendly method of the synthesis of aqueous solutions of the Keggintype Mo-V-P heteropoly acids H3+x PV x Mo12−x O40 (HPA-x) is proposed. At the first stage, V2O5 is dissolved in cooled H2O2 to form peroxyvanadic compounds, which spontaneously decompose to yield a H6V10O28 solution. The latter is stabilized by the addition of H3PO4 to yield a H9PV14O42 solution that is added to a boiling aqueous suspension of (H3PO4 + MoO3). This suspension is gradually evaporated producing the HPA-x solution. This safe and practically wasteless method holds much promise for the preparation of HPA-x solutions with x = 2–6.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    Viktor F. Odyakov & Elena G. Zhizhina

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  1. Viktor F. Odyakov
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  2. Elena G. Zhizhina
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Correspondence to Viktor F. Odyakov.

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Odyakov, V.F., Zhizhina, E.G. A novel method of the synthesis of molybdovanadophosphoric heteropoly acid solutions. React Kinet Catal Lett 95, 21–28 (2008). https://doi.org/10.1007/s11144-008-5374-7

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