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Synthesis, characterization and self-assembly of amphiphilic block copolymer poly(4-vinyl benzene chloride)-b-poly(N-vinylpyrrolidone) in aqueous solution

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Abstract

The synthesis, characterization and self-assembly of a novel amphiphilic block copolymer containing a poly(N-vinylpyrrolidone) as a segment of hydrophilic and poly(4-vinyl benzene chloride) (PVBC) arms are reported. The copolymer was characterized by FT-IR spectroscopy 1H NMR. The composition and the molecular weights of the block copolymers were established using gel permeation chromatography and 1H NMR. The water-soluble fraction of poly(N-vinyl-2-pyrrolidone) (PVP)/PVBC block copolymers formed micelles which were investigated at 25 °C in water at 5 mg/ml concentration using a tensiometer. The morphology of micelles in aqueous solution was determined by the AFM, SANS, and SAXS methods.

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Acknowledgments

This work was performed in the laboratory of Chemical Physical Macromolecular, University of Oran, Algeria. The co-authors would like to thank CNRS of Marseille and Grenoble for helping with NMR and GPC measurements and Mullhose and Grenoble for helping with AFM and DRX (SAXS) measurements.

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Authors and Affiliations

  1. Laboratory of Macromolecular Chemical-Physical, Department of Chemistry, University of Oran, El Menaouar B.P 1524, 31000, Oran, Algeria

    Nardjesse Nemiche, Fatima Zohra Sebba & Seghier Ould Kada

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  1. Nardjesse Nemiche
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  2. Fatima Zohra Sebba
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  3. Seghier Ould Kada
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Correspondence to Nardjesse Nemiche.

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Nemiche, N., Sebba, F.Z. & Kada, S.O. Synthesis, characterization and self-assembly of amphiphilic block copolymer poly(4-vinyl benzene chloride)-b-poly(N-vinylpyrrolidone) in aqueous solution. Res Chem Intermed 40, 3127–3134 (2014). https://doi.org/10.1007/s11164-013-1158-4

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  • DOI: https://doi.org/10.1007/s11164-013-1158-4

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