Skip to main content
SpringerLink
Log in

Preparation and characterization of nickel oxide nanoparticles via solid state thermal decomposition of dinuclear nickel(II) Schiff base complex [Ni2(Brsal-1,3-ph)2] as a new precursor

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The synthesis and characterization of nickel oxide nanoparticles via solid state thermal decomposition of a dinuclear nickel(II) complex, [Ni2(Brsal-1,3-ph)2] as a new precursor is reported. [Ni2(Brsal-1,3-ph)2] complex is characterized by elemental analyses and Fourier transform infrared (FT-IR) spectroscopy. Thermogravimetric analysis reveals its thermal stability and decomposition pattern. Solid state thermal decomposition of the complex at 450 °C for 3 h produces nickel oxide nanoparticles which are characterized by FT-IR spectroscopy, X-ray powder diffraction, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). SEM and TEM images demonstrate the square shape of the NiO nanoparticles of between 10 and 15 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. R. Xu, J. Wang, Q. Li, G. Sun, E. Wang, S. Li, J. Solid State Chem. 182, 3177–3182 (2009)

    Article  CAS  Google Scholar 

  2. A. El-Trass, H. Elshamy, I. El-Mehasseb, M. El-Kemary, Appl. Surf. Sci. 258, 2997–3001 (2012)

    Article  CAS  Google Scholar 

  3. A. Mehrani, A. Morsali, J. Inorg. Organomet. Polym. 21, 476–479 (2011)

    Article  CAS  Google Scholar 

  4. M. Salavati-Niasari, F. Davar, M. Mazaheri, Polyhedron 27, 3467–3471 (2008)

    Article  CAS  Google Scholar 

  5. S. Farhadi, J. Safabakhsh, J. Alloy Compd. 515, 180–185 (2012)

    Article  CAS  Google Scholar 

  6. W. Jia, E. Reitz, P. Shimpi, E.G. Rodriguez, P.X. Gao, Y. Lei, Mater. Res. Bull. 44, 1681–1686 (2009)

    Article  CAS  Google Scholar 

  7. G. Sharma, P. Jeevanandam, Appl. Surf. Sci. 258, 3679–3688 (2012)

    Article  CAS  Google Scholar 

  8. L. Wang, Y. Hao, Y. Zhao, Q. Lai, X. Xu, J. Solid State Chem. 183, 2576–2581 (2010)

    Article  CAS  Google Scholar 

  9. S. Farhadi, Z. Roostaei-Zaniyani, Polyhedron 30, 971–975 (2011)

    Article  CAS  Google Scholar 

  10. M. Salavati-Niasari, N. Mir, F. Davar, J. Alloy Compd. 493, 163–168 (2010)

    Article  CAS  Google Scholar 

  11. M. Ghosh, K. Biswas, A. Sundaresan, C.N.R. Rao, J. Mater. Chem. 16, 106–111 (2006)

    Article  CAS  Google Scholar 

  12. B.S. Kwak, B.H. Choi, M.J. Ji, S.M. Park, M. Kang, J. Ind. Eng. Chem. 18, 11–15 (2012)

    Article  CAS  Google Scholar 

  13. L.A. Saghatforoush, R. Mehdizadeh, F. Chalabian, Trans. Met. Chem. 35, 903–910 (2010)

    Article  CAS  Google Scholar 

  14. M. Alagiri, S. Ponnusamy, C. Muthamizhchelvan, J. Mater. Sci. 23, 728–732 (2012)

    CAS  Google Scholar 

  15. S.M. Meybodi, S.A. Hosseini, M. Rezaee, S.K. Sadrnezhaad, D. Mohammadyani, Ultrason. Sonochem. 19, 841–845 (2012)

    Article  Google Scholar 

  16. A. Allagui, R. Wuthrich, Electrochim. Acta 58, 12–18 (2011)

    Article  CAS  Google Scholar 

  17. N. Srivastava, P.C. Srivastava, Phys. E 42, 2225–2230 (2010)

    Article  CAS  Google Scholar 

  18. M. Salavati-Niasari, N. Mir, F. Davar, Polyhedron 28, 1111–1114 (2009)

    Article  CAS  Google Scholar 

  19. M. Salavati-Niasari, F. Mohandes, F. Davar, M. Mazaheri, M. Monemzadeh, N. Yavarinia, Inorg. Chim. Acta 362, 3691–3697 (2009)

    Article  CAS  Google Scholar 

  20. S. Farhadi, Z. Roostaei-Zaniyani, Polyhedron 30, 1244–1249 (2011)

    Article  CAS  Google Scholar 

  21. M. Salavati-Niasari, F. Davar, Z. Fereshteh, J. Alloy Compd. 494, 410–414 (2010)

    Article  CAS  Google Scholar 

  22. F. Davar, Z. Fereshteh, M. Salavati-Niasari, J. Alloy Compd. 476, 797–801 (2009)

    Article  CAS  Google Scholar 

  23. A. Khansari, M. Enhessari, M. Salavati-Niasari, J. Clust. Sci. 24, 289–297 (2013)

    Article  CAS  Google Scholar 

  24. A.D. Khalaji, J. Clust. Sci. 24, 185–189 (2013)

    Article  Google Scholar 

  25. A.D. Khalaji, J. Clust. Sci. 24, 209–215 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

A. D. Khalaji and M. Nikookar are grateful to the Council of Iran National Science Foundation and Golestan University for financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    Aliakbar Dehno Khalaji & Mahsa Nikookar

  2. Department of Chemistry, The University of Burdwan, Burdwan, West Bengal, India

    Debasis Das

Authors
  1. Aliakbar Dehno Khalaji
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mahsa Nikookar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Debasis Das
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Aliakbar Dehno Khalaji.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khalaji, A.D., Nikookar, M. & Das, D. Preparation and characterization of nickel oxide nanoparticles via solid state thermal decomposition of dinuclear nickel(II) Schiff base complex [Ni2(Brsal-1,3-ph)2] as a new precursor. Res Chem Intermed 41, 357–363 (2015). https://doi.org/10.1007/s11164-013-1197-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-013-1197-x

Keywords

Search

Navigation