Skip to main content
SpringerLink
Log in

On the mechanism of increasing ion conductivity in hybrid membranes

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Ion conductivity of hybrid membrane materials with incorporated nanoparticles of inorganic compounds and polyaniline was considered. A new theory of semielasticity of membrane pore walls was suggested in order to explain the phenomenon of increasing ion conductivity in such systems. It was assumed that in the low humidity region an additional contribution to the conductivity increase is made by the transfer over the incorporated nanoparticles surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Principles of Environmental Chemistry, J. Girard, Jones, and Bartlett Publ., Boston—Toronto—London—Singapore, 2005.

  2. European Commission. Eur20719 EN — Hydrogen Energy and Fuel Cells — A Vision of Our Future. Luxemburg: Office for Official Publications of the European Committees, 2003.

  3. B. N. Kuzyk, Rossiya i mir v XXI veke [Russia and World in the XXI Century], Institute of Economical Strategy, Moscow, 2005, 544 pp. (in Russian).

    Google Scholar 

  4. A. B. Yaroslavtsev, V. V. Nikonenko, Rossiiskie nanotekhnologii [Russian Nanotechnologies], 2009, 4, 44 (in Russian).

    Google Scholar 

  5. D. J. Jones, J. Roziere, Handbook of Fuel Cells — Fundamentals, Technology and Applications, Eds W. Vielstich, H. A. Gasteiger, A. Lamm, V.3, Fuel Cell Technology and Applications, John Wiley and Sons, Ltd, 2003, p. 447.

  6. A. B. Yaroslavtsev, Solid State Ionics, 2005, 176, 2935.

    Article  CAS  Google Scholar 

  7. B. A. Adams, E. L. Holmes, J. Chem. Soc., 1935, 54, 1.

    CAS  Google Scholar 

  8. A. B. Yaroslavtsev, Russ. J. Inorg. Chem., 2000, 45, 249s.

    Google Scholar 

  9. B. Bonnet, D. J. Jones, J. Roziere, L. Tchicaya, G. Alberti, M. Casciola, L. Massinelli, B. Bauer, A. Peraio, E. Ramunni, J. New Mater. Electrochem. Syst., 2000, 3, 87.

    CAS  Google Scholar 

  10. A. B. Yaroslavtsev, Usp. Khim., 2009, 78, 1094 [Russ. Chem. Rev. (Engl. Transl.), 2009, 78, 1013].

    Google Scholar 

  11. E. Yu. Safronova, I. A. Stenina, A. B. Yaroslavtsev, Zh. Neorg. Khim., 2010, 55, 16 [Russ. J. Inorg. Chem. (Engl. Transl.), 2010, 55, 13].

    Google Scholar 

  12. E. Yu. Voropaeva, I. A. Stenina, A. B. Yaroslavtsev, Zh. Neorg. Khim., 2008, 53, 1637 [Russ. J. Inorg. Chem. (Engl. Transl.), 2008, 53, 1677].

    CAS  Google Scholar 

  13. E. Yu. Voropaeva, I. A. Stenina, A. B. Yaroslavtsev, Zh. Neorg. Khim., 2008, 53, 1 [Russ. J. Inorg. Chem. (Engl. Transl.), 2008, 53, 1531].

    Google Scholar 

  14. S. A. Novikova, G. Yu. Yurkov, A. B. Yaroslavtsev, Mendeleev Commun., 2010, 20, 89.

    Article  CAS  Google Scholar 

  15. D. N. Muraviev, J. Macanas, M. Farre, M. Munoz, S. Alegret, Sensors and Actuators B, 2006, 118, 408.

    Article  Google Scholar 

  16. E. Yu. Safronova, A. B. Yaroslavtsev, Zh. Neorg. Khim., 2010, 55, 1587 [Russ. J. Inorg. Chem. (Engl. Transl.), 2010, 55, 1499].

    Google Scholar 

  17. I. A. Stenina, A. A. Ilína, I. Yu. Pinus, V. G. Sergeev, A. B. Yaroslavtsev, Izv. Akad. Nauk, Ser. Khim., 2008, 2219 [Russ. Chem. Bull., Int. Ed., 2008, 57, 2261].

    Google Scholar 

  18. A. B. Yaroslavtsev, V. V. Nikonenko, V. I. Zabolotskii, Usp. Khim., 2003, 72, 438 [Russ. Chem. Rev. (Engl. Transl.), 2003, 72, 393].

    Google Scholar 

  19. K. A. Mauritz, R. B. Moor, Chem. Rev., 2004, 104, 4535.

    Article  CAS  Google Scholar 

  20. T. D. Gierke, G. E. Munn, F. C. Wilson, J. Polym. Sci., Polym. Phys., 1981, 19, 1687.

    CAS  Google Scholar 

  21. W. Y. Hsu, T. D. Gierke, J. Membr. Sci., 1983, 13, 307.

    Article  CAS  Google Scholar 

  22. C. C. Liang, J. Electrochem. Soc., 1973, 120, 1289.

    Article  CAS  Google Scholar 

  23. J. Maier, J. Phys. Chem. Solids, 1985, 46, 309.

    Article  CAS  Google Scholar 

  24. J. Maier, Solid State Chem., 1995, 23, 171.

    Article  CAS  Google Scholar 

  25. K.-D. Kreuer, S. J. Paddison, E. Spohr, M. Schuster, Chem. Rev., 2004, 104, 4637.

    Article  CAS  Google Scholar 

  26. A. B. Yaroslavtsev, I. A. Stenina, E. Yu. Voropaeva, A. A. Ilyina, Polymers Adv. Techn., 2009, 20, 566.

    Article  CAS  Google Scholar 

  27. E. Yu. Voropaeva, E. A. Sanginov, V. I. Volkov, A. S. Pavlov, A. S. Shalimov, I. A. Stenina, A. B. Yaroslavtsev, Zh. Neorg. Khim., 2008, 53, 1643 [Russ. J. Inorg. Chem. (Engl. Transl.), 2008, 53, 1536].

    CAS  Google Scholar 

  28. H. E. Roman, A. Bunde, W. Dieterich, Phys. Rev. B., 1986, 34, 3439.

    Article  Google Scholar 

  29. A. Bunde, Solid State Ionics, 1995, 75, 147.

    Article  CAS  Google Scholar 

  30. T. A. Kravchenko, M. Yu. Chaika, E. V. Bulavina, A. V. Glotov, A. B. Yaroslavtsev, Dokl. Akad. Nauk, Khim., 2010, 433, 55 [Dokl. Chem. (Engl. Transl.), 2010, 433, 111].

    Google Scholar 

  31. V. Yu. Kotov, A. B. Yaroslavtsev, Izv. Akad. Nauk, Ser. Khim., 2002, 515 [Russ. Chem. Bull., Int. Ed., 2002, 51, 555].

  32. V. I. Volkov, E. V. Volkov, S. V. Timofeev, E. A. Sanginov, A. A. Pavlov, E. Yu. Safronova, I. A. Stenina, A. B. Yaroslavtsev, Zh. Neorg. Khim., 2010, 55, 355 [Russ. J. Inorg. Chem. (Engl. Transl.), 2010, 55, 315].

    Google Scholar 

  33. D. L. Gorbatchev, A. B. Yaroslavtsev, J. Mol. Struct., 1997, 416, 63.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. Yu. Safronova, A. A. Lysova, S. A. Novikova & A. B. Yaroslavtsev

Authors
  1. E. Yu. Safronova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Lysova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Novikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. B. Yaroslavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 21—28, January, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Safronova, E.Y., Lysova, A.A., Novikova, S.A. et al. On the mechanism of increasing ion conductivity in hybrid membranes. Russ Chem Bull 60, 20–27 (2011). https://doi.org/10.1007/s11172-011-0003-4

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-011-0003-4

Key words

Search

Navigation