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Problems and prospects of solid contact ion-selective electrodes with ionophore-based membranes

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Russian Chemical Bulletin Aims and scope

Abstract

The problems of stability and reproducibility of potentials of solid contact ion-selective electrodes with ionophore-based membranes were considered from the viewpoint of the existence of a sequence of equilibria providing the coupling of the ionic conductivity in the membrane and the electronic conductivity in the substrate. The both historical approaches to the stabilization of potentials of solid contact electrodes and the contemporary approaches based on the use of conducting polymers were briefly characterized. The role of water uptake by the membrane from the solution is also discussed.

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  1. Department of Chemistry, Saint Petersburg State University, 26 Universitetsky prosp., Staryi Petergof, 198504, Saint Petersburg, Russian Federation

    N. M. Ivanova, M. B. Levin & K. N. Mikhelson

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  1. N. M. Ivanova
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  2. M. B. Levin
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  3. K. N. Mikhelson
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Correspondence to K. N. Mikhelson.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0920–0930, May, 2012.

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Ivanova, N.M., Levin, M.B. & Mikhelson, K.N. Problems and prospects of solid contact ion-selective electrodes with ionophore-based membranes. Russ Chem Bull 61, 926–936 (2012). https://doi.org/10.1007/s11172-012-0136-0

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