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Hydrothermal synthesis, crystal structure and magnetic property of oxalate-bridged iron 1D chain coordination polymer

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Abstract

A novel oxalate-bridged iron coordination polymer, Fe2(phen)2(C2O4)2 (1) has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TGA-DTA analysis, and single-crystal X-ray diffraction. Compound (1) crystallizes in the monoclinic system, space group P2(1), the final R is 0.0486. The tetradentate-chelating coordination mode of oxalate anion creates an infinite 1D iron (II) oxalate chain structure and from which a 2D network is constructed by π–π interactions of phen rings. The temperature-dependent magnetic susceptibility measurement indicates the existence of a weak antiferromagnetic coupling between FeII ions.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China

    Feng-Xia Ma, Fan-Xia Meng, Kun Liu, Hai-Jun Pang, Dong-Mei Shi & Ya-Guang Chen

  2. Basic Science Department, Jilin Agricultural Science and Technology College, Jilin, 13210, P. R. China

    Feng-Xia Ma

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  1. Feng-Xia Ma
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  2. Fan-Xia Meng
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  3. Kun Liu
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Correspondence to Ya-Guang Chen.

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Ma, FX., Meng, FX., Liu, K. et al. Hydrothermal synthesis, crystal structure and magnetic property of oxalate-bridged iron 1D chain coordination polymer. Transition Met Chem 32, 981–984 (2007). https://doi.org/10.1007/s11243-007-0264-9

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  • DOI: https://doi.org/10.1007/s11243-007-0264-9

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