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Synthesis and catalytic activities in cyclohexane hydroxylation of metalloporphyrins supported on styrene-methylacrylic acid copolymer microspheres

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Abstract

Through a new synthetic strategy, metalloporphyrins (M = Fe(III), Mn(III) or Co(II)) were covalently immobilized on styrene-methylacrylic acid copolymer microspheres. These copolymer-immobilized metalloporphyrins were found to be more efficient catalysts than the analogous non-supported metalloporphyrins for cyclohexane hydroxylation in metalloporphyrin–O2–ascrobate mixtures. The catalytic activities of the immobilized catalysts follow the order Fe>Mn>Co.

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Acknowledgements

We are grateful to the supports of Guangzhou Municipality Science & Technology Bureau of China, the National Natural Science Foundation of China and National Key Foundation Research Development Project (973) Item of China (No. 2007 CB815306).

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Authors and Affiliations

  1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering & State Key Laboratory of Optoelectronic Material and Technologies, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Bo Fu, Han-Cheng Yu, Jin-Wang Huang, Ping Zhao & Liang-Nian Ji

  2. The Key Laboratory of Gene Engineering of Ministry of Education, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Liang-Nian Ji

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  1. Bo Fu
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  2. Han-Cheng Yu
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  3. Jin-Wang Huang
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  4. Ping Zhao
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  5. Liang-Nian Ji
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Correspondence to Jin-Wang Huang.

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Fu, B., Yu, HC., Huang, JW. et al. Synthesis and catalytic activities in cyclohexane hydroxylation of metalloporphyrins supported on styrene-methylacrylic acid copolymer microspheres. Transition Met Chem 33, 803–807 (2008). https://doi.org/10.1007/s11243-008-9114-7

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  • DOI: https://doi.org/10.1007/s11243-008-9114-7

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