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Use of a recyclable poly(N-vinyl carbazole) palladium(II) complex catalyst: Heck cross-coupling reaction under phosphine-free and aerobic conditions

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Abstract

A novel pathway for cross-coupling reaction of terminal alkenes with aryl halides (Heck cross-coupling) has been described using a new phosphine-free poly(N-vinyl carbazole) anchored palladium(II) complex as catalyst in aerobic conditions. The catalyst was found to be highly active for the couplings of a variety of substituted and non-substituted aryl halides with terminal alkenes and to smoothly afford the corresponding desired products in good to excellent yields. The catalyst can be reused at least six times without noticeable decrease in catalytic activity.

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Acknowledgments

We acknowledge the Department of Science and Technology (DST), Council of Scientific and Industrial Research (CSIR) and the University Grant Commission (UGC), New Delhi, India for funding. One of the authors, K.T., is thankful to the University Grants Commission (Eastern Region), India, for financial support. We also thank the DST and UGC, New Delhi, India for providing instrumental support under the FIST and SAP program.

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Authors and Affiliations

  1. Department of Chemistry, University of Kalyani, Kalyani, Nadia, 741235, West Bengal, India

    Manirul Islam, Paramita Mondal & Anupam Singha Roy

  2. Department of Chemistry, B.S. College, S-24 P.G.S., Tangrakhali, 743329, West Bengal, India

    Kazi Tuhina

Authors
  1. Manirul Islam
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  2. Paramita Mondal
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  3. Anupam Singha Roy
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  4. Kazi Tuhina
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Correspondence to Manirul Islam.

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Islam, M., Mondal, P., Roy, A.S. et al. Use of a recyclable poly(N-vinyl carbazole) palladium(II) complex catalyst: Heck cross-coupling reaction under phosphine-free and aerobic conditions. Transition Met Chem 35, 491–499 (2010). https://doi.org/10.1007/s11243-010-9354-1

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  • DOI: https://doi.org/10.1007/s11243-010-9354-1

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