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Topics in Catalysis
Erschienen in: Topics in Catalysis 12-14/2017

10.04.2017 | Original Paper

Hybrid Plasma-Catalytic Oxidation of VOCs with NiMn/Montmorillonite: Plasma and Catalyst Considerations

verfasst von: Amin Mohammad Gholipour, Nader Rahemi, Somaiyeh Allahyari, Eslam Ghareshabani

Erschienen in: Topics in Catalysis | Ausgabe 12-14/2017

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Abstract

Bifunctional nanocatalyst of NiMn over alkali activated montmorillonite was prepared with different Mn contents. The prepared catalysts were examined in hybrid plasma-catalytic system for oxidation of volatile organic compounds. The prepared catalysts were characterized by XRD, FESEM, BET, FTIR and EDX analyses. FESEM pictures showed complete and uniform coverage of montmorillonite with metal oxide particles in nano scale. Increasing Mn content from 0 to 9 wt% decreased the BET surface area from 31 to 18 m2 g−1. FTIR spectra illustrated just peaks of montmorillonite and Ni or Mn related peaks were not observed even at high concentrations of Mn. The highest VOC abatement was related to NiMn/montmorillonite with 6 wt% of Mn. This catalyst in hybrid plasma-catalytic oxidation could remove 92% of benzene from polluted air with initial benzene concentration of 1000 ppm in plasma voltage of 20 kV and 9.8 kHz of frequency. While using plasma without catalyst could just remove 74% of benzene in similar conditions. NiMn/montmorillonite nanocatalyst with 6 wt% of Mn was tested at different plasma voltages (10–30 kV) and the highest VOC removal was observed at a voltage of 20 kV. Among 1–9 min residence time, the longest residence time of 9 min had supreme abatement of benzene. Study on mixture of benzene, toluene and xylene in plasma-catalytic system illustrated the highest removal for xylene and the lowest removal for benzene in plasma environment of 20 kV and 9.8 kHz.
Vorheriger Artikel Cold Plasma for Synthesizing High Performance Bimetallic PdCu catalysts: Effect of Reduction Sequence and Pd/Cu Atomic Ratios
Nächster Artikel Plasma Catalytic Removal of p-Xylene from Air Stream Using γ-Al2O3 Supported Manganese Catalyst

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Literatur
1.
Jones AP (1999) Indoor air quality and health. Atmos Environ 33(28):4535–4564CrossRef
2.
Kim H-H, Ogata A, Futamura S (2006) Effect of different catalysts on the decomposition of VOCs using flow-type plasma-driven catalysis. IEEE Trans Plasma Sci 34(3):984–995CrossRef
3.
Roland U, Holzer F, Kopinke FD (2005) Combination of non-thermal plasma and heterogeneous catalysis for oxidation of volatile organic compounds: part 2. Ozone decomposition and deactivation of γ-Al2O3. Appl Catal B 58(3–4):217–226CrossRef
4.
Chen HL et al (2009) Removal of volatile organic compounds by single-stage and two-stage plasma catalysis systems: a review of the performance enhancement mechanisms, current status, and suitable applications. Environ Sci Technol 43(7):2216–2227CrossRef
5.
Huang H, Ye D, Guan X (2008) The simultaneous catalytic removal of VOCs and O3 in a post-plasma. Catal Today 139(1–2):43–48CrossRef
6.
Van Durme J et al (2007) Efficient toluene abatement in indoor air by a plasma catalytic hybrid system. Appl Catal B 74(1–2):161–169CrossRef
7.
Magureanu M et al (2011) In situ study of ozone and hybrid plasma Ag–Al catalysts for the oxidation of toluene: evidence of the nature of the active sites. Appl Catal B 104(1–2):84–90CrossRef
8.
Holzer F, Kopinke FD, Roland U (2005) Influence of ferroelectric materials and catalysts on the performance of non-thermal plasma (NTP) for the removal of air pollutants. Plasma Chem Plasma Process 25(6):595–611CrossRef
9.
Futamura S, Yamamoto T (1997) Byproduct identification and mechanism determination in plasma chemical decomposition of trichloroethylene. IEEE Trans Ind Appl 33(2):447–453CrossRef
10.
Magureanu M et al (2007) Improved performance of non-thermal plasma reactor during decomposition of trichloroethylene: optimization of the reactor geometry and introduction of catalytic electrode. Appl Catal B 74(3–4):270–277CrossRef
11.
Delagrange S, Pinard L, Tatibouët J-M (2006) Combination of a non-thermal plasma and a catalyst for toluene removal from air: manganese based oxide catalysts. Appl Catal B 68(3–4):92–98CrossRef
12.
Futamura S et al (2004) Synergistic effect of silent discharge plasma and catalysts on benzene decomposition. Catal Today 89(1–2):89–95CrossRef
13.
Magureanu M et al (2007) Plasma-assisted catalysis total oxidation of trichloroethylene over gold nano-particles embedded in SBA-15 catalysts. Appl Catal B 76(3–4):275–281CrossRef
14.
Subrahmanyam C et al (2006) Catalytic abatement of volatile organic compounds assisted by non-thermal plasma: part 1. A novel dielectric barrier discharge reactor containing catalytic electrode. Appl Catal B 65(1–2):150–156CrossRef
15.
Li Y et al (2014) Post plasma-catalysis for VOCs degradation over different phase structure MnO2 catalysts. Chem Eng J 241:251–258CrossRef
16.
Wang W et al (2015) Removal of gas phase low-concentration toluene over Mn, Ag and Ce modified HZSM-5 catalysts by periodical operation of adsorption and non-thermal plasma regeneration. J Hazard Mater 292:70–78CrossRef
17.
Guo Y-F et al (2006) Toluene decomposition using a wire-plate dielectric barrier discharge reactor with manganese oxide catalyst in situ. J Mol Catal A 245(1–2):93–100CrossRef
18.
Solsona B et al (2011) Promoting the activity and selectivity of high surface area Ni–Ce–O mixed oxides by gold deposition for VOC catalytic combustion. Chem Eng J 175:271–278CrossRef
19.
Heracleous E et al (2005) Investigation of Ni-based alumina-supported catalysts for the oxidative dehydrogenation of ethane to ethylene: structural characterization and reactivity studies. J Catal 231(1):159–171CrossRef
20.
Dhandapani B, Oyama ST (1997) Gas phase ozone decomposition catalysts. Appl Catal B 11(2):129–166CrossRef
21.
Harling AM et al (2009) The role of ozone in the plasma-catalytic destruction of environmental pollutants. Appl Catal B 90(1–2):157–161CrossRef
22.
Hosseini SA et al (2012) Nanocrystalline AMn2O4 (A = Co, Ni, Cu) spinels for remediation of volatile organic compounds—synthesis, characterization and catalytic performance. Ceram Int 38(2):1655–1661CrossRef
23.
Morales MR, Barbero BP, Cadús LE (2007) Combustion of volatile organic compounds on manganese iron or nickel mixed oxide catalysts. Appl Catal B 74(1–2):1–10CrossRef
24.
Tang W et al (2015) Limited nanospace for growth of Ni–Mn composite oxide nanocrystals with enhanced catalytic activity for deep oxidation of benzene. Catal Today 258:148–155CrossRef
25.
Li D, Li C, Suzuki K (2013) Catalytic oxidation of VOCs over Al- and Fe-pillared montmorillonite. Appl Clay Sci 77–78:56–60CrossRef
26.
Morozov G et al (2014) Sorption of volatile organic compounds and their mixtures on montmorillonite at different humidity. Colloids Surf A 454:159–171CrossRef
27.
Nogueira, F.G.E. et al (2009) Reactive adsorption of methylene blue on montmorillonite via an ESI-MS study. Appl Clay Sci 43(2):190–195CrossRef
28.
Qu F, Zhu L, Yang K (2009) Adsorption behaviors of volatile organic compounds (VOCs) on porous clay heterostructures (PCH). J Hazard Mater 170(1):7–12CrossRef
29.
Ryu C-Y, Yeo S-D (2010) Vapor phase adsorption of trichloroethane using organically modified montmorillonite. J Ind Eng Chem 16(3):441–447CrossRef
30.
Zuo S et al (2012) Adsorption/desorption and catalytic oxidation of VOCs on montmorillonite and pillared clays. Catal Commun 22:1–5CrossRef
31.
Huang Q, Zuo S, Zhou R (2010) Catalytic performance of pillared interlayered clays (PILCs) supported CrCe catalysts for deep oxidation of nitrogen-containing VOCs. Appl Catal B 95(3–4):327–334CrossRef
32.
Oliveira, LCA et al (2008) Catalytic oxidation of aromatic VOCs with Cr or Pd-impregnated Al-pillared bentonite: byproduct formation and deactivation studies. Appl Clay Sci 39(3–4):218–222CrossRef
33.
Harling AM et al (2007) Temperature dependence of plasma-catalysis using a nonthermal, atmospheric pressure packed bed; the destruction of benzene and toluene. J Phys Chem C 111(13):5090–5095CrossRef
34.
Kim H-H, Ogata A, Futamura S (2008) Erratum to “Oxygen partial pressure-dependent behavior of various catalysts for the total oxidation of VOCs using cycled system of adsorption and oxygen plasma”. [Appl Catal B 79(4):356–367]. Appl Catal B 2016 185:378
35.
Zatta L, Ramos LP, Wypych F (2013) Acid-activated montmorillonites as heterogeneous catalysts for the esterification of lauric acid acid with methanol. Appl Clay Sci 80–81:236–244CrossRef
36.
Zhao H et al (2013) Catalytic dehydration of glycerol to acrolein over sulfuric acid-activated montmorillonite catalysts. Appl Clay Sci 74:154–162CrossRef
37.
Delhez, R., de Keijser TH, Mittemeijer EJ (1982) Determination of crystallite size and lattice distortions through X-ray diffraction line profile analysis. Fresenius’ Zeitschrift für anal Chem 312(1):1–16CrossRef
38.
Moreno-Piraján JC, Garcia-Cuello VS, Giraldo L (2010) Synthesis of HMOR and HZSM-5 and their behaviour in the catalytic conversion of methanol to propylene (MTP). J Thermodyn Catal 1:101. doi:10.​4172/​2157-7544.​1000101
39.
Allahyari S, Haghighi M, Ebadi A (2014) Direct conversion of syngas to DME as a green fuel in a high pressure microreactor: influence of slurry solid content on characteristics and reactivity of washcoated CuO–ZnO–Al2O3/HZSM-5 nanocatalyst. Chem Eng Process 86:53–63CrossRef
40.
Allahyari S et al (2014) Ultrasound assisted co-precipitation of nanostructured CuO–ZnO–Al2O3 over HZSM-5: Effect of precursor and irradiation power on nanocatalyst properties and catalytic performance for direct syngas to DME. Ultrason Sonochem 21(2):663–673CrossRef
41.
Allahyari S et al (2014) Effect of irradiation power and time on ultrasound assisted co-precipitation of nanostructured CuO–ZnO–Al2O3over HZSM-5 used for direct conversion of syngas to DME as a green fuel. Energy Convers Manag 83:212–222CrossRef
42.
Allahyari S et al (2014) Direct synthesis of dimethyl ether as a green fuel from syngas over nanostructured CuO–ZnO–Al2O3/HZSM-5 catalyst: Influence of irradiation time on nanocatalyst properties and catalytic performance. J Power Sour 272:929–939CrossRef
43.
Rahemi N et al (2014) Syngas production from reforming of greenhouse gases CH4/CO2 over Ni–Cu/Al2O3 nanocatalyst: Impregnated vs. plasma-treated catalyst. Energy Convers Manag 84:50–59CrossRef
44.
Rahemi N et al (2013) Synthesis and physicochemical characterizations of Ni/Al2O3–ZrO2 nanocatalyst prepared via impregnation method and treated with non-thermal plasma for CO2 reforming of CH4. J Ind Eng Chem 19(5):1566–1576CrossRef
45.
Rahemi N et al (2013) Non-thermal plasma assisted synthesis and physicochemical characterizations of Co and Cu doped Ni/Al2O3 nanocatalysts used for dry reforming of methane. Int J Hydrogen Energy 38(36):16048–16061CrossRef
46.
Nejad DM, Rahemi N, Allahyari S (2017) Effect of tungsten loading on the physiochemical properties of nanocatalysts of Ni–Mo–W/carbon nanotubes for the hydrodesulfurization of thiophene. React Kinet Mech Catal 120(1):279–294
47.
Karatum O, Deshusses MA (2016) A comparative study of dilute VOCs treatment in a non-thermal plasma reactor. Chem Eng J 294:308–315CrossRef
48.
Trinh QH, Lee SB, Mok YS (2015) Removal of ethylene from air stream by adsorption and plasma-catalytic oxidation using silver-based bimetallic catalysts supported on zeolite. J Hazard Mater 285:525–534CrossRef
49.
Bahri M et al (2016) Impact of design parameters on the performance of non-thermal plasma air purification system. Chem Eng J 302:204–212CrossRef
50.
Sivachandiran L et al (2013) Isopropanol saturated TiO2 surface regeneration by non-thermal plasma: influence of air relative humidity. Chem Eng J 214:17–26CrossRef
Metadaten
Titel
Hybrid Plasma-Catalytic Oxidation of VOCs with NiMn/Montmorillonite: Plasma and Catalyst Considerations
verfasst von
Amin Mohammad Gholipour
Nader Rahemi
Somaiyeh Allahyari
Eslam Ghareshabani
Publikationsdatum
10.04.2017
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 12-14/2017
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0758-4

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