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Topics in Catalysis
Erschienen in: Topics in Catalysis 12-14/2017

10.04.2017 | Original Paper

Gliding Arc Plasma Synthesis of MnO2 Nanorods for the Plasma-Catalytic Bleaching of Azoïc Amaranth Red Dye

verfasst von: F. W. Boyom Tatchemo, S. Nzali, G. Kamgang Youbi, A. Tiya Djowe, D. Kuete Saa, E. Acayanka, S. Laminsi, E. M. Gaigneaux

Erschienen in: Topics in Catalysis | Ausgabe 12-14/2017

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Abstract

Manganese (IV) oxide (MnO2) nanoparticles were synthesized, via a plasma-chemical route by using a gliding arc discharge at atmospheric pressure. α-MnO2 nanorods were obtained from the chemical reduction of KMnO4. The synthesis yield was 96.8% after 4.5 min of exposure of the solution to the plasma. Further increase of the exposure time induced a decrease of MnO2 yield because of its reductive transformation into Mn2+ ions. Particles were characterized by X-ray powder diffraction, scanning electron microscopy, Fourier Transform Infrared spectroscopy, and nitrogen physisorption. The plasma-catalytic properties of the synthesized material were tested in the bleaching of amaranth red (AR). AR bleaching efficiencies of 17 and 44% were respectively obtained when the plasma and plasma-catalyst processes were applied for 30 min with initial pH 10. The influence of the initial pH, and catalyst concentration were investigated: the AR bleaching efficiency increased linearly with the catalyst concentration and increased markedly when the pH of the solution decreased.
Vorheriger Artikel Thermal Evolution of the Structure and Activity of Rh Overlayer Catalysts Prepared by Pulsed Arc-Plasma Deposition
Nächster Artikel Effect of Persulfate on the Degradation of Acid Orange 7 (AO7) by Dielectric Barrier Discharge Plasma

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Metadaten
Titel
Gliding Arc Plasma Synthesis of MnO2 Nanorods for the Plasma-Catalytic Bleaching of Azoïc Amaranth Red Dye
verfasst von
F. W. Boyom Tatchemo
S. Nzali
G. Kamgang Youbi
A. Tiya Djowe
D. Kuete Saa
E. Acayanka
S. Laminsi
E. M. Gaigneaux
Publikationsdatum
10.04.2017
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 12-14/2017
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0761-9

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