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Fluxes and Loading of Heavy Metals, Benzo[a]pyrene and Oil Products in Vilnius City

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Water, Air, & Soil Pollution: Focus

Abstract

The concentrations of heavy metals Pb, Cd, Cu, Zn and Hg, benzo[a]pyrene and oil products (C15–C28) in bulk (wet and dry) atmospheric deposition in Vilnius city in 2005–2006 were analysed. The highest flux to the ground surface of the city residential area, reaching 1,680 mg m−2 year−1, was determined for oil products, which in atmospheric bulk deposition was estimated to be mainly in the form of solid sediments. Among heavy metals, the highest flux was determined for Zn (113.5 mg m−2 year−1), while the lowest flux was determined for Hg (0.06 mg m−2 year−1). The flux of investigated pollutants ranges from a few times, or for some pollutants, up to one order of magnitude higher at the urban sampling site in comparison to residential or background sites. Some hundred tons of oil products, approximately 52 tons of zinc and a considerably lower amount of mercury, benzo[a]pyrene and cadmium deposit yearly to the ground and water surface of Vilnius city. Metallic constructions related to transport and buildings, automobile exhausts, spills of fuel and lubricants are suggested to be the factors which result in the accumulation of high amounts of heavy metals, oil products and other pollutants on the ground surface of the city.

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References

  • Berg, T., & Aas, W., (2000). Analytical intercomparison of heavy metals in precipitation 1999. EMEP/CCC-Report 8/2000, NILU, Norway.

  • Berg, T., Royset, O., & Steinnes, E. (1994). Trace elements in atmospheric precipitation at Norwegian background stations (1989–1990) measured by ICP-MS. Atmospheric Environment, 28(21), 1537–1549.

    Article  Google Scholar 

  • Čeburnis, D., Ruhling, A., & Kvietkus, K. (1997). Extended study of atmospheric heavy metal deposition in Lithuania based on moss analysis. Environmental Monitoring and Assessment, 47, 135–152.

    Article  Google Scholar 

  • Davis, A. P., Shokouhian, M., & Ni, S. B. (2001). Loading estimates of lead, copper, cadmium and zinc in urban runoff from specific sources. Chemosphere, 44(5), 997–1009.

    Article  CAS  Google Scholar 

  • Eriksson, E., Baun, A., Mikkelsen, P. S., & Ledin, A. (2005). Chemical hazard identification and assessment tool for evaluation of storm water priority pollutants. Water Science and Technology, 51, 47–55.

    CAS  Google Scholar 

  • Georgn, H. W., Perseke, C., & Rohbock, E. (1984). Deposition of acidic components and heavy metals in the Federal Republic of Germany for the period 1979–1981. Atmospheric Environment, 18, 581–589.

    Article  Google Scholar 

  • German, J., & Svensson, G. (2002). Metal content and particle size distribution of street sediments and street sweeping waste. Water Science and Technology, 46(6–7), 191–198.

    CAS  Google Scholar 

  • Heaton, R. W., Rahn, K. A., & Lowenthal, D. H. (1992). Regional apportionment of sulfate and trace elements in Rhode Island precipitation. Atmospheric Environment, 26A, 1529–1543.

    CAS  Google Scholar 

  • Kvietkus, K., Merkys, A., & Čeburnis, D. (1994). Heavy metals migration in hydrocycle. Atmospheric Physics, 16, 79–84.

    CAS  Google Scholar 

  • LAND 49-2002 (2002). Water quality. Infrared spectrophotometric method for determination of oil products. Lithuanian Environmental Ministry (in Lithuanian).

  • Makepeace, D. K., Smith, D. W., & Stanley, S. J. (1995). Urban storm water quality: summary of contaminated data. Crit. Rev. Environment Science and Technology, 25, 93–139.

    CAS  Google Scholar 

  • Milukaitė, A. (1998). Flux of benzo(a)pyrene to the ground surface and its distribution in the ecosystem. Water Air and Soil Pollution, 105, 471–480.

    Article  Google Scholar 

  • Munthe, J., Wanberg, I., Pirrone, N., Iverfeldt, A., Ferrara, R., Ebinghaus, R., et al. (2001). Intercomparison of methods for sampling and analysis of atmospheric mercury species. Atmospheric Environment, 35, 3007–3017.

    Article  CAS  Google Scholar 

  • Nriagu, J. O., & Pacyna, J. M. (1988). Quantitation assessment of worldwide contamination of air, water and soil by trace elements. Nature, 333, 134–139.

    Article  CAS  Google Scholar 

  • Šakalys, J., Kvietkus, K., & Valiulis, D. (2004). Variation tendencies of heavy metal concentration in the air and precipitation. Environmental and Chemical Physics, 26(2), 61–67.

    Google Scholar 

  • Sommar, J., Wänberg, I., Berg, T., Munte, J., Gårdfeldt, K., Richter, A., et al. (2004). Circumpolar transport and air–surface exchange of atmospheric mercury at Ny–Ålesund (79°N), Svalbard, spring 2002. Atmospheric Chemistry and Physics Discuss, 4, 1727–1771.

    Google Scholar 

  • Šopauskienė, D., Jasinevičienė, D., & Stapčinskaitė, S. (2001). The effect of changes in European anthropogenic emissions on the concentrations sulphur and nitrogen components in air and precipitations in Lithuania. Water, Air and Soil Pollution, 130, 517–522.

    Article  Google Scholar 

  • Urba, A., Kvietkus, K., Sakalys, J., Xiao, Z., & Lindqvist, O. (1995). A new sensitive and portable mercury analyzer Gardis-1A. Water, Air and Soil Pollution, 80, 1251–1260.

    Article  Google Scholar 

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Acknowledgements

Publication was prepared on the basis of data obtained during COST 636 activity. The project was supported by the Lithuanian State Science and Studies Foundation.

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Correspondence to A. Milukaite.

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Milukaite, A., Valiulis, D. & Šakalys, J. Fluxes and Loading of Heavy Metals, Benzo[a]pyrene and Oil Products in Vilnius City. Water Air Soil Pollut: Focus 8, 485–494 (2008). https://doi.org/10.1007/s11267-008-9181-y

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  • DOI: https://doi.org/10.1007/s11267-008-9181-y

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