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The Influence of Soil Properties on the Water Pollution (Nitrate, Phosphate and COD) Following a Single Application of Sewage Sludge to 70 Contrasting Agricultural Soils

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Abstract

The aim was to study the influence of soil properties on the leaching of nitrate, phosphate and organic matter (OM) following the application of sewage sludge to contrasting soils. Seventy agricultural soils from different parts of Spain were amended with sewage sludge (50 t dry weight ha−1), and a controlled column study was developed. After 2, 4 and 6 months of incubation, distilled water, equivalent to an autumn rainfall event of 25 l m−2 in Mediterranean environments, was applied and leachates collected and analysed: pH, electrical conductivity (EC), chemical oxygen demand (COD), phosphate and nitrate. The mean values of pH in the leachates after 2, 4 and 6 months were similar and close to the neutrality. The highest concentrations for the rest of the parameters analysed were found after 2 months of incubation and diminished for 4 and 6 months, especially COD. Soil pH and texture were the most relevant soil properties controlling the leaching of the analysed parameters. The OM mineralization seemed to be enhanced at high values of soil pH, thus increasing the nitrate and reducing the COD leaching. However, phosphate levels were reduced at high values of soil pH. In addition, leaching was promoted in sandy soils. Other soil properties influenced phosphate leaching being the equivalent calcium carbonate soil content as the most relevant. Soil organic carbon was negatively related to the EC and nitrate concentration in the leachates but resulting in a weak contribution compared with soil pH and texture. Concerns about nitrate pollution have been confirmed.

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Acknowledgements

This work was supported by the Spanish Ministry of Environment (number of expedient: 021/2006/2-4.2). José M. Soriano gratefully acknowledges the Spanish Ministry of Science and Innovation for a research fellowship (AP2005-0320).

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  1. Department of Agrochemistry and Environment, University Miguel Hernández of Elche, Avenida de la Universidad S/N, 03202, Elche, Spain

    J. M. Soriano-Disla, I. Gómez & J. Navarro-Pedreño

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  1. J. M. Soriano-Disla
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  2. I. Gómez
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  3. J. Navarro-Pedreño
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Correspondence to J. M. Soriano-Disla.

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Soriano-Disla, J.M., Gómez, I. & Navarro-Pedreño, J. The Influence of Soil Properties on the Water Pollution (Nitrate, Phosphate and COD) Following a Single Application of Sewage Sludge to 70 Contrasting Agricultural Soils. Water Air Soil Pollut 223, 1783–1790 (2012). https://doi.org/10.1007/s11270-011-0983-6

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  • DOI: https://doi.org/10.1007/s11270-011-0983-6

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