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Functionalization of Cotton by RGO/TiO2 to Enhance Photodegradation of Rhodamine B Under Simulated Solar Irradiation

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Abstract

Reduced graphene oxide (RGO) and titanium dioxide (TiO2) nanoparticles were immobilized on cotton textile substrates to produce self-cleaning textiles. Varying number of layers of RGO and TiO2 nanoparticles were coated by a facile method, and their photocatalytic potential was evaluated by measuring the degradation rate of rhodamine B (Rh-B) in an aqueous solution in a photoreactor under simulated solar irradiation. X-ray diffraction (XRD) and zeta potential measurements of starting materials were studied as they are crucial for innovative methods of functionalization. The study confirms that it is possible to ensure a good adhesion of nanoparticles on textile samples without the use of a resin. The application of varying number of RGO and TiO2 coatings has influence on photocatalytic properties of functionalized cotton textile substrates. The energy band gap of the samples reduces from 3.25 to −3.20 eV with the number of RGO coatings. All five de-ethylated intermediates of Rh-B during the photocatalytic degradation were identified using a high-performance liquid chromatography–mass spectrometry method. The experimental results show that, in general, the higher the number of RGO coatings is, the higher the photocatalytic efficiency (η) of the functionalized substrate is (η=87% for three RGO coatings on TiO2).

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Acknowledgements

S. Landi Jr. expresses his gratitude to the Brazilian Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) for sporting his Doctoral Fellowship performed in Physics Centre at University of Minho. J. Molina wishes to thank the Spanish Ministerio de Ciencia e Innovación (contract CTM2011-23583) for the financial support. Moreover, the authors still want to thank the Portuguese Foundation for Science and Technology (FCT) for its contribution in financial support of this research work.

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Authors and Affiliations

  1. Center/Department of Physics, University of Minho, Campus of Azurém, 4800-058, Guimarães, Portugal

    S. Landi Jr, J. O. Carneiro, F. Fernandes, V. Teixeira & A. P. Samantilleke

  2. Instituto Federal Goiano, 75901-970, Rio Verde, Goiás, Brazil

    S. Landi Jr

  3. Chemistry Department, University of Minho, Gualtar Campus, 4710-057, Braga, Portugal

    P. Parpot

  4. Departamento de Ingeniería Textil y Papelera, EPS de Alcoy, Universitat Politècnica de València, Plaza Ferrándiz y Carbonell s/n, 03801, Alcoy, Spain

    J. Molina, F. Cases & J. Fernández

  5. Department of Textile, University of Minho, Campus of Azurém, 4800-058, Guimarães, Portugal

    J. G. Santos & G. M. B. Soares

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  1. S. Landi Jr
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  2. J. O. Carneiro
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  3. F. Fernandes
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  4. P. Parpot
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  5. J. Molina
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  7. J. Fernández
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  8. J. G. Santos
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  9. G. M. B. Soares
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  10. V. Teixeira
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  11. A. P. Samantilleke
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Correspondence to J. O. Carneiro or A. P. Samantilleke.

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Landi, S., Carneiro, J.O., Fernandes, F. et al. Functionalization of Cotton by RGO/TiO2 to Enhance Photodegradation of Rhodamine B Under Simulated Solar Irradiation. Water Air Soil Pollut 228, 335 (2017). https://doi.org/10.1007/s11270-017-3533-z

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  • DOI: https://doi.org/10.1007/s11270-017-3533-z

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